A comparison between the chemical behaviour of lead-gold and lead-bismuth eutectics towards 316L stainless steel
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S. Heinitz
, D. Schumann, J. Neuhausen
, S. Köchli , K. Thomsen , E. Platacis , O. Lielausis , I. Bucenieks , A. Zik , A. Romančuks , K. Kravalis , L. Buligins und A. Türler
Summary
Lead-gold eutectic (LGE) has been recently proposed as an alternative target material for high power spallation sources. In order to compare the corrosive properties of LGE to the better-studied eutectic of lead-bismuth (LBE), an isothermal twin-loop made of SS 316L was built and operated at the Institute of Physics of the University of Latvia. We have measured the concentration of steel alloying elements dissolved in both alloys at the end of two test campaigns via ICP-OES. In case of LGE, a pronounced concentration increase of Fe, Ni, Mn and Cr is found in the liquid metal, which is significantly higher compared to LBE. Similar results were obtained during complementary investigations on material samples exposed to both alloys in this twin-loop at 400 ◦C and 450 ◦C. These findings indicate that in contact with LGE, SS 316L steel suffers from substantial chemical attack. Detailed investigations using structure materials other than SS 316L have to be undertaken before qualifying LGE as a serious alternative to LBE.
© 2013 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München
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- Purification of selenium from thorium, uranium, radium, actinium and potassium impurities for low background measurements
- Analysis of long-lived radionuclides produced by proton irradiation in lead targets – γ -measurements
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Artikel in diesem Heft
- Inhalt
- Cross-sections of 45Sc(n, 2n)44m,gSc reaction from the reaction threshold to 20 MeV
- Fast neutron spectrum unfolding of a TRIGA Mark II reactor and measurement of spectrum-averaged cross sections: integral tests of differential cross sections of neutron threshold reactions
- Determination of 234U and 238U in seawater samples by alpha spectrometry after concentration of U(VI) onto hydrotalcite and co-precipitation with LaF3
- Substitution of IO3 −, IO4−, SeO3 2−, and SeO42− for CO32− in Na4[UO2(CO3)3]
- Structure and spectroscopy of uranyl salicylaldiminate complexes
- A comparison between the chemical behaviour of lead-gold and lead-bismuth eutectics towards 316L stainless steel
- Effect of temperature on the solubility and solid phase stability of zirconium hydroxide
- Purification of selenium from thorium, uranium, radium, actinium and potassium impurities for low background measurements
- Analysis of long-lived radionuclides produced by proton irradiation in lead targets – γ -measurements
- Feasibility studies for production of 89Sr in the Fast Breeder Test Reactor (FBTR)
- Synthesis of I-131 labelled iodine species relevant during severe nuclear accidents in light water reactors