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Experimental and modeling studies of Eu(III) sorption on TiO2
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Zhijuon Guo
Veröffentlicht/Copyright:
25. September 2009
Abstract
Eu(III) sorption on TiO2 (anatase) was investigated as functions of pH, ionic strength and Eu(III) concentration by using a batch experimental method. It was found that Eu(III) sorption on anatase is strongly pH-dependent, but insensitive to ionic strength. A constant capacitance model with three inner-sphere surface complexes, ≡SOEu2+, ≡SOEuOH+ and ≡SOEu(OH)3-, was used to interpret Eu(III) sorption on anatase in the absence and presence of carbonate (pCO2=10-3.58 atm).
Published Online: 2009-09-25
Published in Print: 2009-06
© by Oldenbourg Wissenschaftsverlag, München, Germany
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Schlagwörter für diesen Artikel
Sorption;
Eu(III);
TiO2;
Surface complexation;
Modeling
Artikel in diesem Heft
- Influence of pH and metal ion loading on the Cm(III) humate complexation: a time resolved laser fluorescence spectroscopy study
- Radiotracer study of thorium complexation with humic acid at pH 2–11 using free-liquid electrophoresis
- Experimental and modeling studies of Eu(III) sorption on TiO2
- Extraction of uranium(VI) with diamides of dipicolinic acid from nitric acid solutions
- Extraction behavior of short-lived isotopes of Mo/W using α-benzoinoxime: A model system for the study of seaborgium
- Production of 95gTc via95Ru decay
- A novel 188W/188Re electrochemical generator with potential for medical applications
- Influence of dose rate on the radiolytic stability of a BTBP solvent for actinide(III)/lanthanide(III) separation
- Study of some Ayurvedic Indian medicinal plants for the essential trace elemental contents by instrumental neutron activation analysis and atomic absorption spectroscopy techniques
- Epithermal neutrons activation analysis, radiochemical and radiometric investigations of evaporitic deposits of Slanic-Prahova (Romania) salt mine