Investigation of humic acid complexation behavior with uranyl ions using modified synthetic and natural humic acids
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S. Pompe
We investigated the influence of phenolic OH groups on the complexation behavior of humic acid (HA) with UO22+ ions at pH 4. Starting from synthetic HA type M1, natural HA Aldrich, and natural HA Kranichsee, we synthesized modified HAs with blocked phenolic OH groups by derivatization with diazomethane. The partial blocking of phenolic OH groups was confirmed by a radiometric method which quantitatively determined the functional groups and by FTIR spectroscopy. The complexation behavior of the chemically modified and unmodified HAs with UO22+ ions was investigated by time-resolved laser-induced fluorescence spectroscopy. The experimental data were evaluated with the metal ion charge neutralization model. We determined comparable complexation constants for all HAs. Two modified HAs (type M1 and Aldrich) had significantly lower loading capacities for UO22+ ions (10.5 ± 0.9% and 9.7 ± 1.6%, respectively) than the corresponding unmodified HAs 18.0 ± 2.0% and 17.5 ± 1.6%, respectively). This indicates that the blocking of the phenolic OH groups changes the complexation behavior of HAs.
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Artikel in diesem Heft
- Preface: Migration Conference 1999
- The influence of near field hydrogen on actinide solubilities and spent fuel leaching
- Experimental determination and chemical modelling of radiolytic processes at the spent fuel/water interface
- Thermodynamic data for the solubility of tin(IV) in aqueous cementitious environments
- Leaching behaviour of UO2 containing α-emitting actinides
- Dehydration of synthetic autunite hydrates
- Aqueous dissolution kinetics of pyrochlore, zirconolite and brannerite at 25, 50, and 75 °C
- Complex formation of Np(V) with humic acid and polyacrylic acid
- Investigation of humic acid complexation behavior with uranyl ions using modified synthetic and natural humic acids
- Solution coordination chemistry of uranium in the binary UO22+-SO42- and the ternary UO22+-SO42--OH- system
- The speciation of Tc(IV) in chloride solutions
- The hydrolysis of uranium(VI) in sulfate media
- Complex formation of Eu(III) with polyacrylic acid
- Determination of Co(II) and Ni(II)-humate stability constants at high ionic strength NaCl solutions
- Analysis of Th(IV)-humate by XPS
- EXAFS structural analysis of aqueous uranium(VI) complexes with lignin degradation products
- Thermodynamic modeling of metal-ligand interactions in high ionic strength NaCl solutions: the Co2+-oxalate system
- Mixed Ca2+/UO22+/CO32- complex formation at different ionic strengths
- Humic colloid-borne Np migration: influence of the oxidation state
- Reduction of Pu(V) by humic acid
- Colloid-borne uranium and other heavy metals in the water of a mine drainage gallery
- Application of LIBD to the determination of the solubility product of thorium(IV)-colloids
- The Rossendorf Beam Line ROBL – a dedicated experimental station for XAFS measurements of actinides and other radionuclides
- Extended X-ray absorption fine structure and time differential perturbed angular correlation study of hafnium(IV) sorbed onto amorphous silica
- Speciation analysis on europium(III) using laser-induced breakdown spectroscopy
- The migration behavior of Np(V) in sandy soil and granite media in the presence of humic substances
- Uranium(VI) and neptunium(V) transport through fractured, hydrothermally altered concrete
- Experimental study and modeling of uranium (VI) transport through ferrous olivine rock columns
- Aqueous Pu(IV) sorption on brucite
- Surface spectroscopic studies of Cs+, and Ba2+ sorption on chlorite-illite mixed clay
- Approaches to modelling uranium(VI) adsorption on natural mineral assemblages
- Evaluation of radioactive nickel distribution coefficient by analyzing background stable nickel
- Application of electrokinetic data to test the adsorption models
- Sorption equilibrium and kinetics of NpO2+ on dispersed particles of Na-montmorillonite
- Sorption of Am(III) and Eu(III) onto γ-alumina: experiment and modelling
- Effects of humic acid on the sorption of Am(III) and Cm(III) on kaolinite
- Uranium(VI) sorption onto phyllite and selected minerals in the presence of humic acid
- The partitioning of uranium and neptunium onto hydrothermally altered concrete
- Alteration products of uraninite from the Colorado Plateau
- Fracture-filling minerals as uranium sinks and sources, a natural analogue study at Palmottu, Finland
- Spectroscopic properties of uranium(VI) minerals studied by time-resolved laser-induced fluorescence spectroscopy (TRLFS)
- Fracture smectite as a long-term sink for natural radionuclides – indications from unusual U-series disequilibria
- The potential of subterranean microbes in facilitating actinide migration at the Grimsel Test Site and Waste Isolation Pilot Plant
- Application of gel electrophoretic techniques to the investigation of actinide-humic interactions in soils
- Applications of NAA, PIXE and XPS for the quantification and characterization of the humic substances/iodine association
- Quantitative assessment of radiocaesium bioavailability in forest soils
- Actinide partitioning to an acidic, sandy lake sediment
- Adsorption of Cs and U(VI) on soils of the Australian arid zone
- Natural and artificial radionuclides in forest and bog soils: Tracers for migration processes and soil development
- Distribution of natural radionuclides during the processing of phosphate rock from Itataia-Brazil for production of phosphoric acid and uranium concentrate
- An electrostatic approach for the prediction of actinide complexation constants with inorganic ligands-application to carbonate complexes
- Determination and uncertainties of radioelement solubility limits to be used by SKB in the SR 97’ performance assessment exercise
Artikel in diesem Heft
- Preface: Migration Conference 1999
- The influence of near field hydrogen on actinide solubilities and spent fuel leaching
- Experimental determination and chemical modelling of radiolytic processes at the spent fuel/water interface
- Thermodynamic data for the solubility of tin(IV) in aqueous cementitious environments
- Leaching behaviour of UO2 containing α-emitting actinides
- Dehydration of synthetic autunite hydrates
- Aqueous dissolution kinetics of pyrochlore, zirconolite and brannerite at 25, 50, and 75 °C
- Complex formation of Np(V) with humic acid and polyacrylic acid
- Investigation of humic acid complexation behavior with uranyl ions using modified synthetic and natural humic acids
- Solution coordination chemistry of uranium in the binary UO22+-SO42- and the ternary UO22+-SO42--OH- system
- The speciation of Tc(IV) in chloride solutions
- The hydrolysis of uranium(VI) in sulfate media
- Complex formation of Eu(III) with polyacrylic acid
- Determination of Co(II) and Ni(II)-humate stability constants at high ionic strength NaCl solutions
- Analysis of Th(IV)-humate by XPS
- EXAFS structural analysis of aqueous uranium(VI) complexes with lignin degradation products
- Thermodynamic modeling of metal-ligand interactions in high ionic strength NaCl solutions: the Co2+-oxalate system
- Mixed Ca2+/UO22+/CO32- complex formation at different ionic strengths
- Humic colloid-borne Np migration: influence of the oxidation state
- Reduction of Pu(V) by humic acid
- Colloid-borne uranium and other heavy metals in the water of a mine drainage gallery
- Application of LIBD to the determination of the solubility product of thorium(IV)-colloids
- The Rossendorf Beam Line ROBL – a dedicated experimental station for XAFS measurements of actinides and other radionuclides
- Extended X-ray absorption fine structure and time differential perturbed angular correlation study of hafnium(IV) sorbed onto amorphous silica
- Speciation analysis on europium(III) using laser-induced breakdown spectroscopy
- The migration behavior of Np(V) in sandy soil and granite media in the presence of humic substances
- Uranium(VI) and neptunium(V) transport through fractured, hydrothermally altered concrete
- Experimental study and modeling of uranium (VI) transport through ferrous olivine rock columns
- Aqueous Pu(IV) sorption on brucite
- Surface spectroscopic studies of Cs+, and Ba2+ sorption on chlorite-illite mixed clay
- Approaches to modelling uranium(VI) adsorption on natural mineral assemblages
- Evaluation of radioactive nickel distribution coefficient by analyzing background stable nickel
- Application of electrokinetic data to test the adsorption models
- Sorption equilibrium and kinetics of NpO2+ on dispersed particles of Na-montmorillonite
- Sorption of Am(III) and Eu(III) onto γ-alumina: experiment and modelling
- Effects of humic acid on the sorption of Am(III) and Cm(III) on kaolinite
- Uranium(VI) sorption onto phyllite and selected minerals in the presence of humic acid
- The partitioning of uranium and neptunium onto hydrothermally altered concrete
- Alteration products of uraninite from the Colorado Plateau
- Fracture-filling minerals as uranium sinks and sources, a natural analogue study at Palmottu, Finland
- Spectroscopic properties of uranium(VI) minerals studied by time-resolved laser-induced fluorescence spectroscopy (TRLFS)
- Fracture smectite as a long-term sink for natural radionuclides – indications from unusual U-series disequilibria
- The potential of subterranean microbes in facilitating actinide migration at the Grimsel Test Site and Waste Isolation Pilot Plant
- Application of gel electrophoretic techniques to the investigation of actinide-humic interactions in soils
- Applications of NAA, PIXE and XPS for the quantification and characterization of the humic substances/iodine association
- Quantitative assessment of radiocaesium bioavailability in forest soils
- Actinide partitioning to an acidic, sandy lake sediment
- Adsorption of Cs and U(VI) on soils of the Australian arid zone
- Natural and artificial radionuclides in forest and bog soils: Tracers for migration processes and soil development
- Distribution of natural radionuclides during the processing of phosphate rock from Itataia-Brazil for production of phosphoric acid and uranium concentrate
- An electrostatic approach for the prediction of actinide complexation constants with inorganic ligands-application to carbonate complexes
- Determination and uncertainties of radioelement solubility limits to be used by SKB in the SR 97’ performance assessment exercise