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Observations on Spur Reactions in the Liquid Phase γ-Radiolysis
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Ralph N. Schindler
Published/Copyright:
December 1, 1963
Summary
Propane and butane formation is observed in the liquid phase γ-radiolysis of mixtures of methyl with ethyl halide; butane and ethane formation occurs when mixtures of methyl with n-propyl iodide are irradiated. The G-values for these products are not affected by ≦ 10-2 moles/1 DPPH. These observations and the dependence of G (recombination products) on the composition of the mixtures strongly suggest that these hydrocarbons are formed by diffusion-controlled recombination in spurs.
Published Online: 1963-12-1
Published in Print: 1963-12-1
© 2013 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München
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Articles in the same Issue
- Preparation of 18F in a Nuclear Reactor
- Rapid Solvent Extraction Methods for Fission Product Separation and Analysis
- Half-Life Determination of 220Rn
- The Gas Phase Radiolysis of Ethyl Chloride
- Radiolysis of Ethyl Iodide in the Liquid Phase
- Observations on Spur Reactions in the Liquid Phase γ-Radiolysis
- The Szilard-Chalmers Effect in Cyclohexane-Iodide Mixtures
- The Effect of γ-Pre-Irradiation on Recoil Phenomena in Crystals
- Retention and Annealing Reactions in Dichromates
- Some Observations on the Szilard-Chalmers Process in Dichromates
- A Survey of Photoneutron Sources
- Radiochemical Separation of Thallium by Amalgam Exchange
- Kurze Mitteilungen
- Fast Separation of Antimony from Irradiated Enriched Tellurium
- Beitrag zur strahlenchemisch-thermischen Zersetzung von Kohlenwasserstoffen
