Startseite Naturwissenschaften Insights into the corrosion resistance of a novel quinoline derivative on Q235 steel in acidizing medium under hydrodynamic condition: experimental and surface study
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Insights into the corrosion resistance of a novel quinoline derivative on Q235 steel in acidizing medium under hydrodynamic condition: experimental and surface study

  • Ambrish Singh EMAIL logo , Kashif R. Ansari EMAIL logo , Ismat H. Ali , Muhammad Younas , Abdullah K. Alanazi und Yuanhua Lin EMAIL logo
Veröffentlicht/Copyright: 13. Februar 2024
Zeitschrift für Physikalische Chemie
Aus der Zeitschrift Zeitschrift für Physikalische Chemie Band 238 Heft 8

Abstract

The study concentrated on the fabrication of an environmentally friendly inhibitor, namely ethyl 4-(4-methoxyphenyl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carboxylate derivative of quinoline (MQC), in a single step, and assessed its inhibiting property in highly acidic fluid (15 % HCl) for protecting Q235 steel at 1500 rpm rotation speed. Weight reduction, Potentiodynamic polarization, and electrochemical impedance spectroscopy were utilized in the study to investigate the inhibiting impact of MQC. The estimated findings corroborated the inhibiting data of 93.54 and 98.38 % at 308 K with 100 mg/L/only MQC and MQC + KI/75 mg/L + 0.5 mM, respectively, and the impact of temperature upon the inhibitory capability possessed little impact at larger dose quantities. According to the electrochemical outcomes, the MQC is a mixed-type corrosion inhibitor. The findings of the SEM, EDX, and AFM examinations demonstrated that the MQC established a barrier over the surface of Q235 steel by adsorption, changing the hydrophilic and hydrophobic attributes of the Q235 steel surface. An additional XPS assessment demonstrated MQC molecule adsorption on the Q235 steel surface. Density functional theory (DFT) and molecular dynamic simulations (MD) calculations were further performed to justify the experimental results.

Keywords: corrosion inhibitor; quinoline derivative; SEM; EDX; Q235 steel
Corresponding authors: Ambrish Singh, Department of Chemistry, Nagaland University, Lumami, Zunheboto, 798627, Nagaland, India, E-mail: ; and Kashif R. Ansari and Yuanhua Lin, School of New Energy and Materials, Southwest Petroleum University, Chengdu, 610500, Sichuan, China; and State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu, 610500, Sichuan, China, E-mail: (K.R. Ansari), (Y. Lin)

Acknowledgments

The authors extend their appreciation to the Deanship of Scientific Research at King Khalid University for funding this work through a research group program under grant number R.G.P. 2/271/44.

  1. Research ethics: Not applicable.

  2. Author contributions: The authors have accepted responsibility for the entire content of this manuscript and approved its submission.

  3. Competing interests: The authors states no conflict of interest.

  4. Research funding: The Research was funded by grant number R.G.P. 2/271/44.

  5. Data availability: The raw data can be obtained on request from the corresponding author.

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Supplementary Material

This article contains supplementary material (https://doi.org/10.1515/zpch-2023-0377).

Received: 2023-10-05
Accepted: 2024-01-18
Published Online: 2024-02-13
Published in Print: 2024-08-27

© 2024 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. Review Article
  3. Biomedical and agricultural applications of gold nanoparticles (AuNPs): a comprehensive review
  4. Original Papers
  5. Growth and physiochemical properties of semi organic ammonium pentaborate dihydrate single crystal
  6. A comparative investigation on the surface and physicochemical properties of organobimetallic thiocyanate complexes of Cadmium, Zinc, Mercury and Manganese
  7. Insights into the corrosion resistance of a novel quinoline derivative on Q235 steel in acidizing medium under hydrodynamic condition: experimental and surface study
  8. Geometrical factor, bond order analysis, vibrational energies, electronic properties (gas and solvent phases), topological and molecular docking analysis on Ipriflavone-osteoporosis diseases
  9. Exploration of facile hydrothermally produced pure nickel oxide nanostructures as an effective electrode material for the enhanced supercapacitor applications
  10. Correlation between surface morphology and photocatalytic performance of electrochemically anodized SnO2 nanoparticles
  11. Quantum mechanical treatment for potential antiphlogistic effects from the leaf extract of Ocimum basilicum citriodorum using gas chromatography-mass spectrometry (GCMS)
  12. Homology modeling and molecular docking study of metabotropic glutamate receptor 5 variant F: an attempt to develop drugs for treating CNS diseases
https://doi.org/10.1515/zpch-2023-0377
Schlagwörter für diesen Artikel
corrosion inhibitor; quinoline derivative; SEM; EDX; Q235 steel

Artikel in diesem Heft

  1. Frontmatter
  2. Review Article
  3. Biomedical and agricultural applications of gold nanoparticles (AuNPs): a comprehensive review
  4. Original Papers
  5. Growth and physiochemical properties of semi organic ammonium pentaborate dihydrate single crystal
  6. A comparative investigation on the surface and physicochemical properties of organobimetallic thiocyanate complexes of Cadmium, Zinc, Mercury and Manganese
  7. Insights into the corrosion resistance of a novel quinoline derivative on Q235 steel in acidizing medium under hydrodynamic condition: experimental and surface study
  8. Geometrical factor, bond order analysis, vibrational energies, electronic properties (gas and solvent phases), topological and molecular docking analysis on Ipriflavone-osteoporosis diseases
  9. Exploration of facile hydrothermally produced pure nickel oxide nanostructures as an effective electrode material for the enhanced supercapacitor applications
  10. Correlation between surface morphology and photocatalytic performance of electrochemically anodized SnO2 nanoparticles
  11. Quantum mechanical treatment for potential antiphlogistic effects from the leaf extract of Ocimum basilicum citriodorum using gas chromatography-mass spectrometry (GCMS)
  12. Homology modeling and molecular docking study of metabotropic glutamate receptor 5 variant F: an attempt to develop drugs for treating CNS diseases
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