Startseite Experimental insights into the adsorption of newly synthesized Gemini ethoxylated surfactant on C-steel in different acidic media accompanied by DFT and MCs studies
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Experimental insights into the adsorption of newly synthesized Gemini ethoxylated surfactant on C-steel in different acidic media accompanied by DFT and MCs studies

  • Nasser M. El Basiony EMAIL logo , Elsayed A. Elsharaky , Dong-Hwan Kim EMAIL logo und Aziza S. El-Tabei
Veröffentlicht/Copyright: 29. Mai 2023
Zeitschrift für Physikalische Chemie
Aus der Zeitschrift Zeitschrift für Physikalische Chemie Band 237 Heft 6

Abstract

Bis ethoxylated cationic surfactant (BOECS) is synthesized. The prepared surfactant’s structure configuration was verified through a variety of spectral and physicochemical techniques, including FT-IR, MS,1HNMR, and surface activity evaluations. BOECS applications as a C-steel corrosion inhibitor in 1.0 N HCl and 1.0 N H2SO4 and sulfate reducing bacteria (SRB) mitigations have been investigated thoroughly. Physical properties of the BOECS indicate its potential adsorption affinity at the air/water interface. The electrical conductivity determines the CMC value in accordance with the surface tension value. Electrochemical kinetic parameters indicate the BOECS is sorted as a mixed-type inhibitor and has an inhibition efficacy of 91.22 % and 81.26% for HCl and H2SO4, respectively. Active centers of BOECS structure enhance its adsorption at the electrolyte/C-steel. Calculated adsorption energy change (∆Gads) and theoretical adsorption energy (Eads) values suggest strong and spontaneous BOECS adsorption. The cytotoxic performance of the synthesized BOECS exhibited a potent inhibitory potential against the SRB. The outcomes of this research exhibit that the BOECS can lower SRB growth from 106 to 102 cell/mL.

Keywords: adsorption energy; C-steel corrosion; electrochemical techniques; HCl; SRB; surfactants
Corresponding authors: Nasser M. El Basiony, Egyptian Petroleum Research Institute (EPRI), Nasr City 11727, Cairo, Egypt; and School of Chemical Engineering, Sungkyunkwan University, Suwon 16419, Republic of Korea, E-mail: ; and Dong-Hwan Kim, School of Chemical Engineering, Sungkyunkwan University, Suwon 16419, Republic of Korea, E-mail:
Nasser M. El Basiony and A. S. El-Tabei contributed equally to this article.

Funding source: National Research Foundation of Korea (NRF)

Award Identifier / Grant number: 2022H1D3A2A02060789

Acknowledgment

The authors are grateful to the Egyptian petroleum research institute, and the School of Chemical Engineering, Sungkyunkwan University for their support.

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT and Ministry of Education) (2022H1D3A2A02060789).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Supplementary Material

This article contains supplementary material (https://doi.org/10.1515/zpch-2022-0138).

Received: 2022-09-27
Accepted: 2023-05-03
Published Online: 2023-05-29
Published in Print: 2023-06-27

© 2023 Walter de Gruyter GmbH, Berlin/Boston

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  1. Frontmatter
  2. Original Papers
  3. UV spectroscopy: A novel method for determination of degree of substitution of phthaloyl group as amine protector in chitosan
  4. One step biogenic sugarcane bagasse mediated synthesis of gold nanoparticles and their catalytic applications in removing environmental pollutants
  5. Photocatalytic degradation of atrazine and abamectin using Chenopodium album leaves extract mediated copper oxide nanoparticles
  6. Theoretical and experimental insights into the C-steel aqueous corrosion inhibition at elevated temperatures in 1.0 M HCl via multi-carbonyl Gemini cationic surfactants
  7. Hysteresis in three-dimensional multi-layer molecularly thin-film lubrication
  8. Temperature dependent volumetric, viscometric and conductance studies of barium chloride in aqueous solution of citric acid: an insight into molecular interactions
  9. Experimental insights into the adsorption of newly synthesized Gemini ethoxylated surfactant on C-steel in different acidic media accompanied by DFT and MCs studies
https://doi.org/10.1515/zpch-2022-0138
Schlagwörter für diesen Artikel
adsorption energy; C-steel corrosion; electrochemical techniques; HCl; SRB; surfactants

Artikel in diesem Heft

  1. Frontmatter
  2. Original Papers
  3. UV spectroscopy: A novel method for determination of degree of substitution of phthaloyl group as amine protector in chitosan
  4. One step biogenic sugarcane bagasse mediated synthesis of gold nanoparticles and their catalytic applications in removing environmental pollutants
  5. Photocatalytic degradation of atrazine and abamectin using Chenopodium album leaves extract mediated copper oxide nanoparticles
  6. Theoretical and experimental insights into the C-steel aqueous corrosion inhibition at elevated temperatures in 1.0 M HCl via multi-carbonyl Gemini cationic surfactants
  7. Hysteresis in three-dimensional multi-layer molecularly thin-film lubrication
  8. Temperature dependent volumetric, viscometric and conductance studies of barium chloride in aqueous solution of citric acid: an insight into molecular interactions
  9. Experimental insights into the adsorption of newly synthesized Gemini ethoxylated surfactant on C-steel in different acidic media accompanied by DFT and MCs studies
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