Home Physical Sciences Highly photosensitized Mg4 Si6O15 (OH)2·6H2O@guar gum nanofibers for the removal of methylene blue under solar light irradiation
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Highly photosensitized Mg4 Si6O15 (OH)2·6H2O@guar gum nanofibers for the removal of methylene blue under solar light irradiation

  • Sadia Ata , Saba Naz , Ismat Bibi EMAIL logo , Ijaz-ul Mohsin , Atif Islam , Azra Mehmood , Foziah F. Al-Fawzan , Siham A. Alissa and Munawar Iqbal EMAIL logo
Published/Copyright: August 13, 2021

Abstract

In the present investigation, photosensitized nanofibers (NFs) based on guar gum (GG)/poly(vinyl alcohol) (PVA)/Mg4Si6O15(OH)2·6H2O (SP) (modified by 1, 4-diamminobutane [DAB]) was fabricated by electrospinning approach and same was used for the degradation of dye under solar light irradiation. For electrospinning of NFs, the acceleration voltage, nozzle flow rate and collector distance levels of 19,000 KV, 0.5 mL/h and 3 cm were optimum conditions along with 7% (w/v) blend of GG/PVA (1.4:5.6 wt/wt) and 0.01 g modified Mg4Si6O15(OH)2·6H2O. The exfoliation, intercalation and clay organophilization in GG/PVA/Mg4Si6O15(OH)2·6H2O (GG/PVA/SP) NFs were examined by FTIR analysis. The photocatalytic activity (PCA) of NF was studied under the solar light irradiation for methylene blue (MB) dye degradation. The photosensitized GG/PVA/SP2 (G3) showed promising PCA under visible light and G3 furnished higher degradation of MB dye (99.1%) within 10 min of irradiation. Results revealed that GG/PVA/SP based NFs are highly active under solar light, which can be applied for the treatment of wastewater.


Corresponding authors: Ismat Bibi, Institute of Chemistry, The Islamia University of Bahawalpur, Bahawalpur, Pakistan, E-mail: ; and Munawar Iqbal, Department of Chemistry, Division of Science and Technology, University of Education, Lahore, Pakistan, E-mail:

Funding source: Princess Nourah bint Abdulrahman University

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This research was funded by the Deanship of Scientific Research at Princess Nourah bint Abdulrahman University through the Fast-track Research Funding Program.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2020-12-13
Accepted: 2021-07-28
Published Online: 2021-08-13
Published in Print: 2022-02-23

© 2021 Walter de Gruyter GmbH, Berlin/Boston

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