Startseite Preparation, Physical Characterization and Adsorption Properties of Synthesized Co–Ni–Cr Nanocomposites for Highly Effective Removal of Nitrate: Isotherms, Kinetics and Thermodynamic Studies
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Preparation, Physical Characterization and Adsorption Properties of Synthesized Co–Ni–Cr Nanocomposites for Highly Effective Removal of Nitrate: Isotherms, Kinetics and Thermodynamic Studies

  • Somayeh Rahdar , Abbas Rahdar EMAIL logo , Shahin Ahmadi , Zhara Mehdizadeh und Mahmoud Taghavi
Veröffentlicht/Copyright: 22. April 2019
Zeitschrift für Physikalische Chemie
Aus der Zeitschrift Zeitschrift für Physikalische Chemie Band 234 Heft 1

Abstract

In the current effort, the Co–Ni–Cr Nanocomposites were synthesized by chemical method and characterized by means of scanning electron micrographs (SEM), X-ray diffraction (XRD), Fourier trans from infra-red (FTIR), and vibration sample magnetization (VSM). In the final step, these nanoparticles were used to study the nitrate removal efficiency from aqueous solution. The effect of important factor including pH, concentration of Nitrate (NO3−) ion, contact time and nanoparticle dose were studied in order to find the optimum adsorption conditions. A maximum of removal of the nitrate was observed at pH 4, initial concentration of 40 mg L−1, amount of nanoparticle of 0.06 g L−1 and contact time 60 min. The adsorption isotherm values were obtained and analyzed using the Langmuir, Frenudlich, Temkin and Dubinin–Radushkevich equations, the Temkin isotherm being the one that showed the best correlation coefficient (R2 = 0.999). In addition to, the adsorption kinetics studied by the pseudo-first-order, pseudo-second-order, Elovich model, Ritchie and intraparticle diffusion models. The experimental data fitted to pseudo-second-order (R2 = 0.999).

Keywords: aqueous solution; Co–Ni–Cr nanoferrites; isotherm; kinetic; nitrate

Acknowledgments

S. Rahdar, S. Ahmadi, and Z. Mehdizadeh are grateful to the Zabol University of Medical Sciences for the financial support of this study (Project No. 1396.324). A. Rahdar would like to thank the University of Zabol for financial support (UOZ-GR-9618-40) for this work.

References

1. S. Tyagi, D. Rawtani, N. Khatri, M. Tharmavaram, J. Water Process. Eng. 21 (2018) 84.10.1016/j.jwpe.2017.12.005Suche in Google Scholar

2. A. Bhatnagar, E. Kumar, M. Sillanpää, Chem. Eng. 163 (2010) 317.10.1016/j.cej.2010.08.008Suche in Google Scholar

3. M. Francavilla, L. Beneduce, G. Gatta, E. Montoneri, M. Monteleone, D. Mainero, Biochem. Eng. 116 (2016) 75.10.1016/j.bej.2016.02.015Suche in Google Scholar

4. C. Vereda-Alonso, J. M. Rodríguez-Maroto, R. A. Garcıa-Delgado, C. Gómez-Lahoz, F. Garcıa-Herruzo, International Conference on Education and New Learning Technologies, Barcelona, Spain (2009), P. 6.Suche in Google Scholar

5. T. Shubair, O. Eljamal, A. M. Khalil, N. Matsunaga, Sep. Purif. Technol. 193 (2018) 242.10.1016/j.seppur.2017.10.069Suche in Google Scholar

6. H. Jiang, P. Chen, S. Luo, X. Tu, Q. Cao, M. Shu, Appl. Sci. Res. 284 (2013) 942.10.1016/j.apsusc.2013.04.013Suche in Google Scholar

7. P. Ganesan, R. Kamaraj, S. Vasudevan, J. Taiwan. Inst. Chem. Eng. 44 (2013) 808.10.1016/j.jtice.2013.01.029Suche in Google Scholar

8. A. A. Hekmatzadeh, A. Karimi-Jashani, N. Talebbeydokhti, B. Kløve, Desalination 284 (2012) 22.10.1016/j.desal.2011.08.033Suche in Google Scholar

9. D. M. Manassaram, L. C. Backer, D. M. Moll, Environ. Health Perspect. 114 (2005) 320.10.1289/ehp.8407Suche in Google Scholar PubMed PubMed Central

10. M. A. Salam, O. Fageeh, S. A. Al-Thabaiti, A. Y. Obaid, J. Mol. Liq. 212 (2015) 708.10.1016/j.molliq.2015.09.029Suche in Google Scholar

11. Z. H. Farooqi, R. Khalid, R. Begum, U. Farooq, Q. Wu, W. Wu, M. Ajmal, A. Irfan, K. Naseem, Environ Technol. 20 (2018) 1.Suche in Google Scholar

12. M. Kalaruban, P. Loganathan, W. G. Shim, J. Kandasamy, G. Naidu, T. V. Nguyen, S. Vigneswaran, Sep Purif Technol. 158 (2016) 62.10.1016/j.seppur.2015.12.022Suche in Google Scholar

13. M. Pirsaheb, T. Khosravi, K. Sharafi, M. Mouradi, Desalin. Water Treat. 57 (2016) 5391.10.1080/19443994.2015.1004592Suche in Google Scholar

14. F. D. Belkada, O. Kitous, N. Drouiche, S. Aoudj, O. Bouchelaghem, N. Abdi, H. Grib, N. Mameri, Sep. Purif. Technol. 204 (2018) 108.10.1016/j.seppur.2018.04.068Suche in Google Scholar

15. J. Wang, L. Chu, Biotechnol. Adv. 34 (2016) 1103.10.1016/j.biotechadv.2016.07.001Suche in Google Scholar PubMed

16. M. Ahmadi, H. Rahmani, B. Ramavandi, B. Kakavandi, Desalin. Water Treat. 76 (2017) 265.10.5004/dwt.2017.20705Suche in Google Scholar

17. Z. He, Y. Xia, B. Tang, J. Su, X. Jiang, Z. Phys. Chem. 233 (2019) 347.10.1515/zpch-2017-1017Suche in Google Scholar

18. K. Naseem, Z. H. Farooqi, M. Z. Rehman, M. A. Rehman, M. Ghufran, Rev. Chem. Eng. 35 (2019) 285.10.1515/revce-2017-0042Suche in Google Scholar

19. K. Naseem, R. Huma, A. Shahbaz, J. Jamal, M. Z. Rehman, A. Sharif, E. Ahmed, R. Begum, A. Irfan, A. G. Al-Sehemi, Z. H. Farooqi, Z. Phys. Chem. 233 (2019) 201.10.1515/zpch-2018-1182Suche in Google Scholar

20. A. Naseer, A. Jamshaid, A. Hamid, N. Muhammad, M. Ghauri, J. Iqbal, S. Rafiq, S. Khuram, N. S. Shah, Z. Phys. Chem. 23 (2019) 315.10.1515/zpch-2018-1209Suche in Google Scholar

21. N. U. Khan, H. N. Bhatti, M. Iqbal, A. Nazir, Z. Phys. Chem. 233 (2019) 361.10.1515/zpch-2018-1194Suche in Google Scholar

22. A. Bhatnagar, M. Sillanpää, Chem. Eng. J. 168 (2011) 493.10.1016/j.cej.2011.01.103Suche in Google Scholar

23. Z. He, Y. Xia, B. Tang, J. Su, X. Jiang, Z. Phys. Chem. 233 (2019) 347.10.1515/zpch-2017-1017Suche in Google Scholar

24. C. Richard, J. Simmchen, Z. Phys. Chem. 232 (2018) 747.10.1515/zpch-2017-1087Suche in Google Scholar

25. Y. R. Zhang, S. Q. Wang, S. L. Shen, B. X. Zhao, Chem. Eng. J. 233 (2013) 258.10.1016/j.cej.2013.07.009Suche in Google Scholar

26. V. K. Gupta, A. Nayak, Chem. Eng. J. 180 (2012) 81.10.1016/j.cej.2011.11.006Suche in Google Scholar

27. S. Ata, A. Tabassum, I. Bibi, S. Ghafoor, A. Ahad, M. A. Bhatti, A. Islam, H. Rizvi, M. Iqbal, Z. Phys. Chem. 233 (2019) 995.10.1515/zpch-2018-1203Suche in Google Scholar

28. F. Cuomo, F. Venditti, G. Cinelli, A. Ceglie, F. Lopez, Z. Phys. Chem. 230 (2016) 1269.10.1515/zpch-2015-0725Suche in Google Scholar

29. R. S. Raveendra, P. A. Prashanth, R. Hari Krishna, N. P. Bhagya, B. M. Nagabhushana, H. Raja Naika, K. Lingaraju, H. Nagabhushana, B. Daruka Prasad, J. Asian Ceram. Soc. 4 (2014) 357.10.1016/j.jascer.2014.07.008Suche in Google Scholar

30. S. J. Liu, Z. Y. Zhao, J. Li, J. Wang, Y. Qi, Water Res. 47 (2013) 5977.10.1016/j.watres.2013.06.028Suche in Google Scholar PubMed

31. R. H. Kadam, A. P. Birajdar, S. T. Alone, S. E. Shirsath, J. Magn. Magan. Mater 28 (2013) 167.10.1016/j.jmmm.2012.09.059Suche in Google Scholar

32. Standard Methods. 4500-NO3- B. 22. ed. Washington: [S.n], 2012.Suche in Google Scholar

33. S. Ahmadi, L. Mohammadi, C. A. Igwegbe, S. Rahdar, B. Artur Marek, Int. J. Ind. Eng. Chem. 9 (2018) 241.10.1007/s40090-018-0153-4Suche in Google Scholar

34. S. Rahdar, A. Rahdar, C. Adaobi Igwegbe, F. Moghaddam, Desalin. Water Treat. 141 (2019) 1.10.5004/dwt.2019.22720Suche in Google Scholar

35. E. Bazrafshan, F. Kord Mostafapour, S. Rahdar, A. H. Mahvi, Desalin. Water Treat. 54 (2015) 2241.10.1080/19443994.2014.895778Suche in Google Scholar

36. M. H. Shahmoradi, B. A. Zade, A. Torabian, M. S. Salehi, Arpn. J. Eng. Appl. Sci. 17 (2015) 7856.Suche in Google Scholar

37. M. Sanchooli Moghaddam, S. Rahdar, M. Taghavi, Iran. J. Chem. Chem. Eng. 35 (2016) 45.Suche in Google Scholar

38. N. Öztürk, T. E. Bektaş, J. Hazard. Mater. 112 (2004) 155.10.1016/j.jhazmat.2004.05.001Suche in Google Scholar PubMed

39. D. W. Cho, C. M. Chon, Y. Kim, B. H. Jeon, F. W. Schwartz, E. S. Lee, H. Song, Chem. Eng. 175 (2011) 298.10.1016/j.cej.2011.09.108Suche in Google Scholar

40. M. Islam, R. Patel, Desalination 256 (2010) 120.10.1016/j.desal.2010.02.003Suche in Google Scholar

41. A. Teimouri, S. G. Nasab, N. Vahdatpoor, S. Habibollahi, H. Salavati, A. N. Chermahini, Int. J. Biol. Macromol. 93 (2016) 254.10.1016/j.ijbiomac.2016.05.089Suche in Google Scholar PubMed

42. C. F. Iscen, I. Kiran, S. Ilhan, J. Hazard. Mater. 143 (2007) 335.10.1016/j.jhazmat.2006.09.028Suche in Google Scholar PubMed

43. S. T. Akar, A. S. Özcan, Z. Kaynak, Desalination 249 (2009) 757.10.1016/j.desal.2008.09.012Suche in Google Scholar

44. S. Banerjee, M. C. Chattopadhyaya, Arab. J. Chem. 10 (2017) 1629.10.1016/j.arabjc.2013.06.005Suche in Google Scholar

45. W. W. Ngah, M. A. K. M. Hanafiah, Biochem. Eng. 39 (2008) 521.10.1016/j.bej.2007.11.006Suche in Google Scholar

46. O. Gulnaz, A. Kaya, S. Dincer, Chem. Mater. 134 (2006) 190.10.1016/j.jhazmat.2005.10.050Suche in Google Scholar

47. S. L. Hii, S. Y. Yong, C. L. Wong, J. Appl. Phycol. 21 (2009) 625.10.1007/s10811-009-9448-3Suche in Google Scholar

48. S. Banerjee, M. C. Chattopadhyaya, Arab. J. Chem. 10 (2017) 629.10.1016/j.arabjc.2013.06.005Suche in Google Scholar

49. K. Naseem, R. Huma, A. Shahbaz, J. Jamal, M. Z. Rehman, A. Sharif, E. Ahmed, R. Begum, A. Irfan, A. G. Al-Sehemi, Z. H. Farooqi, Z. Phys. Chem. 233 (2019) 201.10.1515/zpch-2018-1182Suche in Google Scholar

50. G. Z. Kyzas, P. I. Siafaka, E. G. Pavlidou, K. J. Chrissafis, D. N. Bikiaris, Chem. Eng. 259 (2015) 438.10.1016/j.cej.2014.08.019Suche in Google Scholar

51. S. Gholitabar, H. Tahermansouri, Carbon Lett. 30 (2017) 14.Suche in Google Scholar

52. H. M. F. Freundlich, J. Phys. Chem. 57 (1906) 385.Suche in Google Scholar

53. E. Bazrafshan, S. Rahdar, D. Balarak, F. K. Mostafapour, M. A. Zazouli, Iran. J. Med. Sci. 15 (2015) 15.Suche in Google Scholar

54. K. Naseem, R. Begum, W. Wu, M. Usman, A. Irfan, A. G. Al-Sehemi, Z. H. Farooqi, J. Mol. Liq. 277 (2019) 22.10.1016/j.molliq.2018.12.051Suche in Google Scholar

55. A. Kara, E. Demirbel, Water Air Soil. Pollut. 223 (2012) 2387.10.1007/s11270-011-1032-1Suche in Google Scholar PubMed PubMed Central

56. P. Indhumathi, S. Sathiyaraj, J. P. Koelmel, S. U. Shoba, C. Jayabalakrishnan, M. Saravanabhavan, Z. Phys. Chem. 232 (2018) 527.10.1515/zpch-2016-0900Suche in Google Scholar

57. S. Ahmadi, S. Rahdar, C. A. Igwegbe, A. Rahdar, N. Shafighi, F. Sadeghfar, Methods X 6 (2019) 98.Suche in Google Scholar

58. K. Naseem, Z. H. Farooqi, M. Z. Rehman, M. A. Rehman, R. Begum, R. Huma, A. Shahbaz, J. Najeeb, A. Irfan, Water Sci. Technol. 77 (2018) 2355.10.2166/wst.2018.190Suche in Google Scholar PubMed

59. K. Naseem, Z. H. Farooqi, R. Begum, M. Ghufran, M. Z. Rehman, J. Najeeb, A. Irfan, A. G. Al-Sehemi, J. Mol. Liq. 268 (2018) 229.10.1016/j.molliq.2018.07.039Suche in Google Scholar

60. S. Ahmadi, S. Rahdar, C. A. Igwegbe, A. Rahdar, N. Shafighi, F. Sadeghfar, Methods X 6 (2019) 98.10.1016/j.mex.2018.12.009Suche in Google Scholar

61. J. Liu, L. Wu, X. Chen, Desalin. Water Treat 5 (2015) 2307.10.1080/19443994.2014.898000Suche in Google Scholar

62. A. Rahdar, S. Ahmadi, J. Fu, S. Rahdar, Desalin. Water Treat 137 (2019) 174.10.5004/dwt.2019.23350Suche in Google Scholar

63. A. Bhatnagar, E. Kumar, M. Sillanpää, Chem. Eng. 163 (2010) 317.10.1016/j.cej.2010.08.008Suche in Google Scholar

64. G. R. Mahdavinia, M. Soleymani, H. Etemadi, M. Sabzi, Z. Atlasi, Int. J. Biol. Macromol. 107 (2018) 719.10.1016/j.ijbiomac.2017.09.042Suche in Google Scholar PubMed

Supplementary Material

The online version of this article offers supplementary material (DOI: https://doi.org/10.1515/zpch-2019-1372).

Received: 2019-01-14
Accepted: 2019-03-29
Published Online: 2019-04-22
Published in Print: 2020-01-28

©2020 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. The Maximum of Minimal Conductivity in Aqueous Electrolytes
  3. The Effect of Low Weight Percent Multiwalled Carbon Nanotubes on the Dielectric Properties of Non-Conducting Polymer/Ceramic Nanocomposites for Energy Storage Materials
  4. Synthesis, Characterization and Electrical Conductivity of Silver Doped Polyvinyl Acetate/Graphene Nanocomposites: A Novel Humidity Sensor
  5. Preparation, Physical Characterization and Adsorption Properties of Synthesized Co–Ni–Cr Nanocomposites for Highly Effective Removal of Nitrate: Isotherms, Kinetics and Thermodynamic Studies
  6. New Heterocyclic Derivative to Stop Carbon Steel Corrosion
  7. Investigating of Erosion-Corrosion Behavior of Carbon Steel in Egyptian Crude Oil-Water Mixture Using Electrochemical Method
  8. Structural, Vibrational and UV/Vis Studies of Adamantane-Containing Triazole Thiones by Spectral, DFT and Multi-reference ab initio Methods
  9. The Effect of Grain Size and Shape on Sliding Friction of Wet Granular Media
  10. Decomposition Kinetics of Levofloxacin: Drug-Excipient Interaction
  11. ZnO/UV/H2O2 Based Advanced Oxidation of Disperse Red Dye
  12. An Efficient Ultrasonic-Assisted Synthesis and Nonlinear Optical Property of Donor (D) -π-Acceptor (A) Chalcone (DDFP)
  13. Synthesized and Photocatalytic Mechanism of the NiO Supported YMnO3 Nanoparticles for Photocatalytic Degradation of the Methyl Orange Dye
https://doi.org/10.1515/zpch-2019-1372
Schlagwörter für diesen Artikel
aqueous solution; Co–Ni–Cr nanoferrites; isotherm; kinetic; nitrate

Artikel in diesem Heft

  1. Frontmatter
  2. The Maximum of Minimal Conductivity in Aqueous Electrolytes
  3. The Effect of Low Weight Percent Multiwalled Carbon Nanotubes on the Dielectric Properties of Non-Conducting Polymer/Ceramic Nanocomposites for Energy Storage Materials
  4. Synthesis, Characterization and Electrical Conductivity of Silver Doped Polyvinyl Acetate/Graphene Nanocomposites: A Novel Humidity Sensor
  5. Preparation, Physical Characterization and Adsorption Properties of Synthesized Co–Ni–Cr Nanocomposites for Highly Effective Removal of Nitrate: Isotherms, Kinetics and Thermodynamic Studies
  6. New Heterocyclic Derivative to Stop Carbon Steel Corrosion
  7. Investigating of Erosion-Corrosion Behavior of Carbon Steel in Egyptian Crude Oil-Water Mixture Using Electrochemical Method
  8. Structural, Vibrational and UV/Vis Studies of Adamantane-Containing Triazole Thiones by Spectral, DFT and Multi-reference ab initio Methods
  9. The Effect of Grain Size and Shape on Sliding Friction of Wet Granular Media
  10. Decomposition Kinetics of Levofloxacin: Drug-Excipient Interaction
  11. ZnO/UV/H2O2 Based Advanced Oxidation of Disperse Red Dye
  12. An Efficient Ultrasonic-Assisted Synthesis and Nonlinear Optical Property of Donor (D) -π-Acceptor (A) Chalcone (DDFP)
  13. Synthesized and Photocatalytic Mechanism of the NiO Supported YMnO3 Nanoparticles for Photocatalytic Degradation of the Methyl Orange Dye
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2025 De Gruyter Brill
Heruntergeladen am 6.10.2025 von https://www.degruyterbrill.com/document/doi/10.1515/zpch-2019-1372/html
Button zum nach oben scrollen