The Effect of Crystalline Microstructure of PVDF Binder on Mechanical and Electrochemical Performance of Lithium-Ion Batteries Cathode
-
Mohammad Mohsen Loghavi
,
Saeed Bahadorikhalili
Abstract
In this paper, the effect of the crystalline microstructures of polyvinylidene fluoride (PVDF), as cathode binder, on mechanical and electrochemical properties of the cathode, and on the cell performance is investigated. The crystalline phases of the PVDF films prepared at different temperatures are determined by X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR) and also mechanical strength of PVDF films evaluated by a tensile test. The cathodes were prepared at altered temperatures to achieve different PVDF phases. The effect of various crystalline phases on the cathode performance was studied. The obtained cathodes were analyzed by scanning electron microscope (SEM), contact angle measurement, and adhesion test. The electrochemical performance of the cathodes was evaluated by charge-discharge cycling test and AC impedance spectroscopy. Mechanical tests results showed that the cathode which is prepared at 60 °C has the best adhesion and mechanical stability. In addition, the charge-discharge cycling studies showed that this cathode has the highest capacity efficiency. AC impedance spectroscopy illustrated that this electrode has the lowest charge transfer resistance and SEI resistance.
References
1. B. K. Licht, F. Homeyer, K. Bösebeck, M. Binnewies, P. Heitjans, Z. Phys. Chem. 229 (2015) 1415.10.1515/zpch-2015-0003Search in Google Scholar
2. M. H. Moghim, R. Eqra, M. Babaiee, M. Zarei-Jelyani, M. M. Loghavi, J. Electroanal. Chem. 789 (2017) 67.10.1016/j.jelechem.2017.02.031Search in Google Scholar
3. M. Z. Jelyani, S. Rashid-Nadimi, S. Asghari, J. Solid State Electrochem. 21 (2017) 69.10.1007/s10008-016-3336-ySearch in Google Scholar
4. Z. Du, D. L. Wood, C. Daniel, S. Kalnaus, J. Li, J. Appl. Electrochem. 47 (2017) 405.10.1007/s10800-017-1047-4Search in Google Scholar
5. P. Jakes, L. Kröll, A. Ozarowski, J. van Tol, D. Mikhailova, H. Ehrenberg, R.-A. Eichel, Z. Phys. Chem. 231 (2017) 905.10.1515/zpch-2016-0909Search in Google Scholar
6. K. Volgmann, V. Werth, S. Nakhal, M. Lerch, T. Bredow, P. Heitjans, Z. Phys. Chem. 231 (2017) 1243.10.1515/zpch-2016-0948Search in Google Scholar
7. E. Vasilyeva, A. Nasibulin, O. Tolochko, A. Rudskoy, A. Sachdev, X. Xiao, Z. Phys. Chem. 229 (2015) 1429.10.1515/zpch-2015-0573Search in Google Scholar
8. E. Hüger, B. Jerliu, L. Dörrer, M. Bruns, G. Borchardt, H. Schmidt, Z. Phys. Chem. 229 (2015) 1375.10.1515/zpch-2014-0650Search in Google Scholar
9. R. Hausbrand, A. Schwöbel, W. Jaegermann, M. Motzko, D. Ensling, Z. Phys. Chem. 229 (2015) 1387.10.1515/zpch-2014-0664Search in Google Scholar
10. K. Volgmann, A. Schulz, A.-M. Welsch, T. Bredow, S. Nakhal, M. Lerch, P. Heitjans, Z. Phys. Chem. 229 (2015) 1351.10.1515/zpch-2015-0585Search in Google Scholar
11. D. Wiedemann, S. Nakhal, A. Senyshyn, T. Bredow, M. Lerch, Z. Phys. Chem. 229 (2015) 1275.10.1515/zpch-2014-0659Search in Google Scholar
12. T. Placke, P. Bieker, S. F. Lux, O. Fromm, H.-W. Meyer, S. Passerini, M. Winter, Z. Phys. Chem. 226 (2012) 391.10.1524/zpch.2012.0222Search in Google Scholar
13. S. Laubach, S. Laubach, P. C. Schmidt, M. Gröting, K. Albe, W. Jaegermann, W. Wolf, Z. Phys. Chem. 223 (2009) 1327.10.1524/zpch.2009.6082Search in Google Scholar
14. M. Stein, C.-F. Chen, M. Mullings, D. Jaime, A. Zaleski, P. P. Mukherjee, C. P. Rhodes, J. Electrochem. Energy Convers. Storage. 13 (2016) 031001.10.1115/1.4034755Search in Google Scholar
15. A. Gören, C. Costa, M. M. Silva, S. Lanceros-Mendez, Solid State Ionics. 295 (2016) 57.10.1016/j.ssi.2016.07.012Search in Google Scholar
16. C. Mao, S. J. An, H. M. Meyer III, J. Li, M. Wood, R. E. Ruther, D. L. Wood III, J. Power Sources. 402 (2018) 107.10.1016/j.jpowsour.2018.09.019Search in Google Scholar
17. V. Etacheri, R. Marom, R. Elazari, G. Salitra, D. Aurbach, Energy Environ. Sci. 4 (2011) 3243.10.1039/c1ee01598bSearch in Google Scholar
18. J. W. Fergus, J. Power Sources. 195 (2010) 939.10.1016/j.jpowsour.2009.08.089Search in Google Scholar
19. K. Du, H. Xie, G. Hu, Z. Peng, Y. Cao, F. Yu, ACS Appl. Mater. Interfaces. 8 (2016) 17713.10.1021/acsami.6b05629Search in Google Scholar PubMed
20. N. Leifer, O. Srur-Lavi, I. Matlahov, B. Markovsky, D. Aurbach, G. Goobes, Chem. Mater. 28 (2016) 7594.10.1021/acs.chemmater.6b01412Search in Google Scholar
21. H. Y. Tran, G. Greco, C. Täubert, M. Wohlfahrt-Mehrens, W. Haselrieder, A. Kwade, J. Power Sources. 210 (2012) 276.10.1016/j.jpowsour.2012.03.017Search in Google Scholar
22. Z. Zhang, T. Zeng, Y. Lai, M. Jia, J. Li, J. Power Sources. 247 (2014) 1.10.1016/j.jpowsour.2013.08.051Search in Google Scholar
23. L. Chen, X. Xie, J. Xie, K. Wang, J. Yang, J. Appl. Electrochem. 36 (2006) 1099.10.1007/s10800-006-9191-2Search in Google Scholar
24. H. Maleki, G. Deng, A. Anani, J. Howard, J. Electrochem. Soc. 146 (1999) 3224.10.1149/1.1392458Search in Google Scholar
25. J. Yu, X. Huang, C. Wu, P. Jiang, IEEE Trans. Dielectr. Electr. Insul. 18 (2011) 478.10.1109/TDEI.2011.5739452Search in Google Scholar
26. G.-D. Kang, Y.-M. Cao, J. Membr. Sci. 463 (2014) 145.10.1016/j.memsci.2014.03.055Search in Google Scholar
27. K. P. Singh, A. Mishra, T. Shami, J. Inorg. Organomet. Polym Mater. 28 (2018) 1.10.1007/s10904-017-0690-xSearch in Google Scholar
28. W. Eisenmenger, M. Haardt, Solid State Commun. 41 (1982) 917.10.1016/0038-1098(82)91235-2Search in Google Scholar
29. M. Sharma, G. Madras, S. Bose, Phys. Chem. Chem. Phys. 16 (2014) 14792.10.1039/c4cp01004cSearch in Google Scholar PubMed
30. C. V. S. Reddy, M. Chen, W. Jin, Q. Zhu, W. Chen, S.-I. Mho, J. Appl. Electrochem. 37 (2007) 637.10.1007/s10800-007-9294-4Search in Google Scholar
31. R. Gregorio, J. Appl. Polym. Sci. 100 (2006) 3272.10.1002/app.23137Search in Google Scholar
32. R. Gregorio, E. Ueno, J. Mater. Sci. 34 (1999) 4489.10.1023/A:1004689205706Search in Google Scholar
33. M. Benz, W. B. Euler, J. Appl. Polym. Sci. 89 (2003) 1093.10.1002/app.12267Search in Google Scholar
34. D. W. Chae, S. M. Hong, Macromol. Res. 19 (2011) 326.10.1007/s13233-011-0403-1Search in Google Scholar
35. A. Salimi, A. Yousefi, J. Polym. Sci. Part B: Polym. Phys. 42 (2004) 3487.10.1002/polb.20223Search in Google Scholar
36. A. J. Lovinger, Macromol. 15 (1982) 40.10.1021/ma00229a008Search in Google Scholar
37. G. Prasad, P. Sathiyanathan, A. A. Prabu, K. J. Kim, Macromol. Res. 25 (2017) 981.10.1007/s13233-017-5127-4Search in Google Scholar
38. F. He, S. Lau, H. L. Chan, J. Fan, Adv. Mater. 21 (2009) 710.10.1002/adma.200801758Search in Google Scholar
39. H. M. Correia, M. M. Ramos, Comp. Mater. Sci. 33 (2005) 224.10.1016/j.commatsci.2004.12.040Search in Google Scholar
40. K. M. Kim, W. S. Jeon, I. J. Chung, S. H. Chang, J. Power Sources. 83 (1999) 108.10.1016/S0378-7753(99)00281-5Search in Google Scholar
41. K. Terashita, K. Miyanami, Adv. Powder Technol. 13 (2002) 201.10.1163/156855202760166541Search in Google Scholar
42. H. Zheng, L. Tan, G. Liu, X. Song, V. S. Battaglia, J. Power Sources. 208 (2012) 52.10.1016/j.jpowsour.2012.02.001Search in Google Scholar
43. D. Liu, L.-C. Chen, T.-J. Liu, T. Fan, E.-Y. Tsou, C. Tiu, Adv. Chem. Eng. Sci. 4 (2014) 515.10.4236/aces.2014.44053Search in Google Scholar
44. G. Liu, H. Zheng, A. Simens, A. Minor, X. Song, V. Battaglia, J. Electrochem. Soc. 154 (2007) A1129.10.1149/1.2792293Search in Google Scholar
45. G. Liu, H. Zheng, S. Kim, Y. Deng, A. Minor, X. Song, V. Battaglia, J. Electrochem. Soc. 155 (2008) A887.10.1149/1.2976031Search in Google Scholar
46. H. Zheng, R. Yang, G. Liu, X. Song, V. S. Battaglia, J. Phys. Chem. C. 116 (2012) 4875.10.1021/jp208428wSearch in Google Scholar
47. P. A. Dowben, L. G. Rosa, C. C. Ilie, Z. Phys. Chem. 222 (2008) 755.10.1524/zpch.2008.6007Search in Google Scholar
48. B. Wang, X. Gong, J. Li, Y. Shang, D. Shi, J. de Claville Christiansen, D. Yu, S. Jiang, J. Polym. Res. 22 (2015) 244.10.1007/s10965-015-0889-xSearch in Google Scholar
49. P. Martins, A. Lopes, S. Lanceros-Mendez, Prog. Polym. Sci. 39 (2014) 683.10.1016/j.progpolymsci.2013.07.006Search in Google Scholar
50. R. Gregorio Jr., Rinaldo, M. Cestari, J. Polym. Sci. Part B: Polym. Phys. 32 (1994) 859.10.1002/polb.1994.090320509Search in Google Scholar
51. B.-E. El Mohajir, N. Heymans, Polymer. 42 (2001) 5661.10.1016/S0032-3861(01)00064-7Search in Google Scholar
52. B. Mohammadi, A. A. Yousefi, S. M. Bellah, Polym. Test. 26 (2007) 42.10.1016/j.polymertesting.2006.08.003Search in Google Scholar
53. Y. You, H. Celio, J. Li, A. Dolocan, A. Manthiram, Angew. Chem. Int. Ed. 57 (2018) 6480.10.1002/anie.201801533Search in Google Scholar PubMed
54. D. Mohanty, K. Dahlberg, D. M. King, L. A. David, A. S. Sefat, D. L. Wood, C. Daniel, S. Dhar, V. Mahajan, M. Lee, Sci. Rep. 6 (2016) 26532.10.1038/srep26532Search in Google Scholar PubMed PubMed Central
55. A. Vinogradov, F. Holloway, Ferroelectr. 226 (1999) 169.10.1080/00150199908230298Search in Google Scholar
©2020 Walter de Gruyter GmbH, Berlin/Boston
Articles in the same Issue
- Frontmatter
- The Effect of Crystalline Microstructure of PVDF Binder on Mechanical and Electrochemical Performance of Lithium-Ion Batteries Cathode
- Mechanistic Study on Surface Tension of Binary and Ternary Mixtures Containing Choline Chloride, Ethylene Glycol and Water (Components of Aqueous Solutions of a Deep Eutectic Solvent, Ethaline)
- Thiadiazole-2-Thiol-5-Thione and 2,5-Dimercapto-1,3,4-Thiadiazol Tautomerism, Conformational Stability, Vibrational Assignments, Inhibitor Efficiency and Quantum Chemical Calculations
- The Thermodynamic and pH Metric Binding Studies of Cu+2 Ions with Egg Protein by Spectrometric and Diffusion Current Techniques
- Adsorption of 2,4-Dichlorophenoxyacetic Acid from Aqueous Solution Using Carbonized Chest Nut as Low Cost Adsorbent: Kinetic and Thermodynamic
- The Kinetics and Equilibrium Thermodynamics Study on the Removal of Direct Blue and Titan Yellow Dyes from Aqueous Media by Modified Rice Husk Char
- Investigation of Dielectric Properties, Electric Modulus and Conductivity of the Au/Zn-Doped PVA/n-4H-SiC (MPS) Structure Using Impedance Spectroscopy Method
- Finding Solvent for Polyamide 11 Using a Computer Software
- Phytochemical Synthesis of Silver Nanoparticles Using Anthemis Nobilis Extract and Its Antibacterial Activity
Articles in the same Issue
- Frontmatter
- The Effect of Crystalline Microstructure of PVDF Binder on Mechanical and Electrochemical Performance of Lithium-Ion Batteries Cathode
- Mechanistic Study on Surface Tension of Binary and Ternary Mixtures Containing Choline Chloride, Ethylene Glycol and Water (Components of Aqueous Solutions of a Deep Eutectic Solvent, Ethaline)
- Thiadiazole-2-Thiol-5-Thione and 2,5-Dimercapto-1,3,4-Thiadiazol Tautomerism, Conformational Stability, Vibrational Assignments, Inhibitor Efficiency and Quantum Chemical Calculations
- The Thermodynamic and pH Metric Binding Studies of Cu+2 Ions with Egg Protein by Spectrometric and Diffusion Current Techniques
- Adsorption of 2,4-Dichlorophenoxyacetic Acid from Aqueous Solution Using Carbonized Chest Nut as Low Cost Adsorbent: Kinetic and Thermodynamic
- The Kinetics and Equilibrium Thermodynamics Study on the Removal of Direct Blue and Titan Yellow Dyes from Aqueous Media by Modified Rice Husk Char
- Investigation of Dielectric Properties, Electric Modulus and Conductivity of the Au/Zn-Doped PVA/n-4H-SiC (MPS) Structure Using Impedance Spectroscopy Method
- Finding Solvent for Polyamide 11 Using a Computer Software
- Phytochemical Synthesis of Silver Nanoparticles Using Anthemis Nobilis Extract and Its Antibacterial Activity
