Effect of Mesoporous Diatomite Particles on the Kinetics of SR&NI ATRP of Styrene and Butyl Acrylate
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Khezrollah Khezri
Abstract
Mesoporous diatomite particles were employed to prepare different poly(styrene-co-butyl acrylate)/diatomite nanocomposites. Diatomite nanoplatelets were used for in situ copolymerization of styrene and butyl acrylate by SR&NI ATRP to synthesize well-defined poly(styrene-co-butyl acrylate) nanocomposites. Nitrogen adsorption/desorption isotherm is applied to examine surface area and structural characteristics of the diatomite nanoplatelets. Evaluation of pore size distribution and morphological studies were also performed by SEM and TEM. Conversion and molecular weight determinations were carried out using gas and size exclusion chromatography respectively. Addition of 3 wt% pristine mesoporous diatomite nanoplatelets leads to increase of conversion from 73 to 89%. Molecular weight of poly(styrene-co-butyl acrylate) chains increases from 17,115 to 20,343 g·mol−1 by addition of 3 wt% pristine mesoporous diatomite; however, polydispersity index values increases from 1.14 to 1.37. Increasing thermal stability of the nanocomposites is demonstrated by TGA. Differential scanning calorimetry shows an increase in glass transition temperature from 35.26 to 39.61°C by adding 3 wt% of mesoporous diatomite nanoplatelets.
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©2018 Walter de Gruyter GmbH, Berlin/Boston
Articles in the same Issue
- Frontmatter
- The Electronic Structure Signature of the Spin Cross-Over Transition of [Co(dpzca)2]
- Thermal Degradation of Complexes Derived from Cu (II) Groundnut (Arachis hypogaea) and Sesame (Sesamum indicum) Soaps
- Effect of Mesoporous Diatomite Particles on the Kinetics of SR&NI ATRP of Styrene and Butyl Acrylate
- Removal of Hexavalent Chromium by Adsorption on Microwave Assisted Activated Carbon Prepared from Stems of Leucas Aspera
- Removal of Acid Yellow 17 Dye by Fenton Oxidation Process
- The Efficient Removal of Heavy Metal Ions from Industry Effluents Using Waste Biomass as Low-Cost Adsorbent: Thermodynamic and Kinetic Models
- Degradation of Acetaminophen in Aqueous Media by H2O2 Assisted Gamma Irradiation Process
- M(Al,Ni)-TiO2-Based Photoanode for Photoelectrochemical Solar Cells
- Quantum Mechanical Study of γ-Fe2O3 Nanoparticle as a Nanocarrier for Anticancer Drug Delivery
- Corrigendum
- Corrigendum to: Green Synthesis of CoFe2O4 and Investigation of its Catalytic Efficiency for Degradation of Dyes in Aqueous Medium
Articles in the same Issue
- Frontmatter
- The Electronic Structure Signature of the Spin Cross-Over Transition of [Co(dpzca)2]
- Thermal Degradation of Complexes Derived from Cu (II) Groundnut (Arachis hypogaea) and Sesame (Sesamum indicum) Soaps
- Effect of Mesoporous Diatomite Particles on the Kinetics of SR&NI ATRP of Styrene and Butyl Acrylate
- Removal of Hexavalent Chromium by Adsorption on Microwave Assisted Activated Carbon Prepared from Stems of Leucas Aspera
- Removal of Acid Yellow 17 Dye by Fenton Oxidation Process
- The Efficient Removal of Heavy Metal Ions from Industry Effluents Using Waste Biomass as Low-Cost Adsorbent: Thermodynamic and Kinetic Models
- Degradation of Acetaminophen in Aqueous Media by H2O2 Assisted Gamma Irradiation Process
- M(Al,Ni)-TiO2-Based Photoanode for Photoelectrochemical Solar Cells
- Quantum Mechanical Study of γ-Fe2O3 Nanoparticle as a Nanocarrier for Anticancer Drug Delivery
- Corrigendum
- Corrigendum to: Green Synthesis of CoFe2O4 and Investigation of its Catalytic Efficiency for Degradation of Dyes in Aqueous Medium
