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Effect of Moisture on Methane Permeation Through Fermenter Covering Films in Biogas Plants

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Published/Copyright: November 18, 2017

Abstract

Methane permeation through polyamide and polyethylene mono and multilayer films has been measured via direct coupling of a gaschromatograph with a permeation measurement cell. Methane permeabilities [in cm3 (STP)·mm·d−1·bar−1·m−2] for single films were found to be 335 for polyethylene (PE) at 40°C, 0.64 for polyamide (PA) 6/6.6 with dry gas and 8.7 for PA 6/6.6 with water vapour saturated test gas. As a result, under operating conditions of biogas production facilities (40°C, water vapour saturated), the replacement of PE by PA, as biogas membrane on top of a fermenter, can reduce methane emission through permeation by a factor of about 40.


Dedicated to: Eckart Rühl on the occasion of his 60th birthday.


Acknowledgements

We thank Dr. R. Minkwitz and Dr. S.A. Gruener from BASF for providing the samples and for many useful discussions. Financial support from BASF is also gratefully acknowledged.

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Received: 2017-8-9
Accepted: 2017-10-18
Published Online: 2017-11-18
Published in Print: 2018-5-24

©2018 Walter de Gruyter GmbH, Berlin/Boston

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