Synthesis, crystal structures and third-order nonlinear optical properties of Ni2+/Mn2+/Zn2+ naphthalene-1,5-disulfonates
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Zhaoxun Lian
und
Ning Zhao
Abstract
In this study, we present the synthesis and characterization of three transition metal 1,5-naphthalenedisulfonates: [Ni(PTP)₂]·(1,5-NDS)·2H₂O (1), [Mn(PTP)(1,5-NDS)] (2), and [Zn(PTP)(1,5-NDS)(H₂O)]2·2.5H₂O (3). Herein, PTP refers to 4′-phenyl-2,2′:6′,2″-terpyridine while 1,5-NDS denotes the naphthalene-1,5-disulfonate dianion. Compound 1 exhibits a structure in which the sulfonate groups of the 1,5-naphthalenedisulfonate anions are not engaged in coordination. In compound 2, the Mn(II) ions are interconnected through 1,5-NDS anions to form chains along the c axis. Compound 3 features a chain structure via coordination interactions between the metal cations and the 1,5-naphthalenedisulfonate anions; adjacent chains are linked by hydrogen bonds to create a double-chain arrangement. Solid diffuse reflection spectra reveal that these compounds exhibit maximum absorption around 290 nm. The third-order nonlinear optical (NLO) properties of these complexes was investigated using the single-beam Z-scan techniques under laser irradiation at a wavelength of 532 nm. All three compounds demonstrate significant third-order nonlinear optical absorption effects with absorption coefficients of 1.85 × 10−5 m W−1 for compound 1, 1.12 × 10−5 m W−1 for compound 2 and 1.73 × 10−5 m W−1 for compound 3. The corresponding calculated values for third-order NLO susceptibility χ³ are 3.00 × 10⁻7 esu, 1.81 × 10⁻7 esu and 2.80 × 10⁻7 esu, respectively.
Funding source: High-Level Talent Program of Kaili University
Award Identifier / Grant number: BS20240205
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Research ethics: Not applicable.
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Informed consent: Not applicable.
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Author contributions: All authors have accepted responsibility for the entire content of this manuscript and approved its submission.
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Use of Large Language Models, AI and Machine Learning Tools: None declared.
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Conflict of interest: The author states no conflict of interest.
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Research funding: The work was financially supported by High-Level Talent Program of Kaili University (No. BS20240205).
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Data availability: Not applicable.
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© 2024 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- In this issue
- Review
- Intermetallics from cadmium self-flux reactions
- Research Articles
- Take five: the isotypic structures of Y2WO6 and Ho2WO6 comprising non-condensed [WO5]4− units
- The lithium-rich stannide Li4Rh3Sn5
- Iridium-rich silicides RE 5Ir19Si12 (RE = Y, Gd–Dy, Er, Tm, Lu) with Sc5Co19P12-type structure
- A solution, X-ray crystallographic and theoretical study of acylhydrazonyl compounds: the influence of the NHCO arrangement on the structures of (E)-N′-benzylidene-2-(thiophen-2-yl)acetohydrazides
- Synthesis, crystal structures and third-order nonlinear optical properties of Ni2+/Mn2+/Zn2+ naphthalene-1,5-disulfonates
- Rutile-type Ni–TiO2 nanocrystals with Ni-induced p-type channels for enhanced photocatalytic degradation of organic pollutants
- Syntheses, molecular structures and properties of (Ph4P)2[trans-O2RuCl4]·CH2Cl2 and [(Ph3P)2N]2[trans-O2RuCl4]·CH2Cl2
Artikel in diesem Heft
- Frontmatter
- In this issue
- Review
- Intermetallics from cadmium self-flux reactions
- Research Articles
- Take five: the isotypic structures of Y2WO6 and Ho2WO6 comprising non-condensed [WO5]4− units
- The lithium-rich stannide Li4Rh3Sn5
- Iridium-rich silicides RE 5Ir19Si12 (RE = Y, Gd–Dy, Er, Tm, Lu) with Sc5Co19P12-type structure
- A solution, X-ray crystallographic and theoretical study of acylhydrazonyl compounds: the influence of the NHCO arrangement on the structures of (E)-N′-benzylidene-2-(thiophen-2-yl)acetohydrazides
- Synthesis, crystal structures and third-order nonlinear optical properties of Ni2+/Mn2+/Zn2+ naphthalene-1,5-disulfonates
- Rutile-type Ni–TiO2 nanocrystals with Ni-induced p-type channels for enhanced photocatalytic degradation of organic pollutants
- Syntheses, molecular structures and properties of (Ph4P)2[trans-O2RuCl4]·CH2Cl2 and [(Ph3P)2N]2[trans-O2RuCl4]·CH2Cl2
