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Lu26 T 17–x In x (T = Rh, Ir, Pt) – first indium intermetallics with Sm26Co11Ga6-type structure

  • Nataliya L. Gulay , Jutta Kösters , Maximilian Kai Reimann , Yaroslav M. Kalychak and Rainer Pöttgen EMAIL logo
Published/Copyright: August 29, 2022
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 77 Issue 10

Abstract

Several Lu26 T 17−x In x (T = Rh, Ir, Pt) phases with varying x values were obtained by induction-melting reactions of the elements in sealed tantalum ampoules. All samples were characterized through their X-ray powder diffraction patterns. These compounds crystallize with the tetragonal Sm26Co11Ga6-type structure, space group P4/mbm and Z = 2. The structure of Lu26Pt7.55In9.45 has been refined from single-crystal X-ray diffractometer data: a = 1165.32(5), c = 1547.46(6) pm, wR2 = 0.0895, 2173 F 2 values and 70 variables. The Lu26 T 17−x In x phases are the first indium representatives of the Sm26Co11Ga6 type. They belong to the n = 4 members of Parthé’s A 5n+6 B 3n+5 series, which show different stacking sequences of square prisms and antiprisms. Lu26Pt7.55In9.45 as a lutetium-rich intermetallic compound exhibits a broader range of shorter Lu–Lu distances (341–375 pm). Temperature dependent magnetic susceptibility measurements show Pauli paramagnetism for Lu26Ir8.5In8.5 and Lu26Rh7In10 with room temperature values of the magnetic susceptibility of χ = 1.53 × 10−3 emu mol−1 for Lu26Rh7In10 and χ = 6.54 × 10−4 emu mol−1 for Lu26Ir8.5In8.5.

Keywords: intermetallics; rare earth compounds; Sm26Co11Ga6 type
Corresponding author: Rainer Pöttgen, Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstrasse 30, 48149 Münster, Germany, E-mail:

Acknowledgements

We thank M. Sc. C. Paulsen for the EDX analyses.

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2022-07-22
Accepted: 2022-08-07
Published Online: 2022-08-29
Published in Print: 2022-10-26

© 2022 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Research Articles
  4. Intermediate ytterbium valence in YbRhSn2
  5. Intermetallic compounds RE2Ga2Mg (RE = Tb–Tm, Lu) with Mo2B2Fe-type structure
  6. Synthesis, crystal structure and magnetic properties of mer-tricyanidoiron(III) precursor-based 1D heterobimetallic complexes
  7. The ternary system Sc–Co–In at 870 K: the isothermal section and the crystal structures of the compounds
  8. High-pressure synthesis of borate-nitrates: crystal structure of M3B7O13(NO3) (M = Co2+, Ni2+, Cu2+, Zn2+, Cd2+)
  9. Mg2MnGa3 – An orthorhombically distorted superstructure variant of the hexagonal Laves phase MgZn2
  10. Lu26 T 17–x In x (T = Rh, Ir, Pt) – first indium intermetallics with Sm26Co11Ga6-type structure
  11. Orthoamide und Iminiumsalze, CVIa. Kondensationsreaktionen von Orthoamiden der Alkincarbonsäuren mit CH-aciden Methylheterocyclen
https://doi.org/10.1515/znb-2022-0111
Keywords for this article
intermetallics; rare earth compounds; Sm26Co11Ga6 type

Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Research Articles
  4. Intermediate ytterbium valence in YbRhSn2
  5. Intermetallic compounds RE2Ga2Mg (RE = Tb–Tm, Lu) with Mo2B2Fe-type structure
  6. Synthesis, crystal structure and magnetic properties of mer-tricyanidoiron(III) precursor-based 1D heterobimetallic complexes
  7. The ternary system Sc–Co–In at 870 K: the isothermal section and the crystal structures of the compounds
  8. High-pressure synthesis of borate-nitrates: crystal structure of M3B7O13(NO3) (M = Co2+, Ni2+, Cu2+, Zn2+, Cd2+)
  9. Mg2MnGa3 – An orthorhombically distorted superstructure variant of the hexagonal Laves phase MgZn2
  10. Lu26 T 17–x In x (T = Rh, Ir, Pt) – first indium intermetallics with Sm26Co11Ga6-type structure
  11. Orthoamide und Iminiumsalze, CVIa. Kondensationsreaktionen von Orthoamiden der Alkincarbonsäuren mit CH-aciden Methylheterocyclen
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