Home The ternary system Sc–Co–In at 870 K: the isothermal section and the crystal structures of the compounds
Article
Licensed
Unlicensed Requires Authentication

The ternary system Sc–Co–In at 870 K: the isothermal section and the crystal structures of the compounds

  • Nataliya L. Gulay , Yuriy B. Tyvanchuk , Rainer Pöttgen EMAIL logo and Yaroslav M. Kalychak
Published/Copyright: August 29, 2022
Become an author with De Gruyter Brill
Author Information Explore this Subject
Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 77 Issue 10

Abstract

The isothermal section of the Sc–Co–In system at T = 870 K has been constructed using X-ray powder diffraction and SEM/EDX data. At the studied temperature, nine ternary compounds are formed: Sc50Co12.5In3.5 (Ag7+x Mg24−x -type structure, space group Fm 3 ‾ , a = 17.7411 Å), Sc14Co3.10In2.59 (Lu14Co3In3 type, P42/nmc, a = 8.8913, c = 21.387 Å), Sc6Co2.18In0.82 (Ho6Co2Ga type, Immm, a = 8.867, b = 8.780, c = 9.321 Å), Sc2CoIn (Pt2ZnCd type, P4/mmm, a = 3.2887, c = 7.1642 Å), Sc11Co4In9 (Nd11Pd4In9 type, Cmmm, a = 13.836, b = 20.758, c = 3.351 Å), Sc5Co2In4 (Lu5Ni2In4 type, Pbam, a = 17.3400, b = 7.5940, c = 3.3128 Å), Sc3Co1.64In4 (Lu3Co2−x In4 type, P 6 ‾ , a = 7.6702, c = 3.3595 Å), Sc10Co9In20 (Ho10Ni9In20 type, P4/nmm, a = 12.8331, c = 9.0226 Å), Sc0.5In0.5Co2 (ternary non-centrosymmetric derivative of the Laves phase MgNi2, P63 mc, a = 4.8910, c = 16.0166 Å, with a homogeneity range from 12.3 to 16.7 at% of indium). The cubic phase ScCo4In (MgCu4Sn type, F 4 ‾ 3m, a = 6.9230(8) Å) is evidently present in the cast samples and disappears after the annealing procedure. A Sc/In substitution was observed for the solid solution Sc1−x In x Co2 (x = 0–0.26) with the structure of the cubic Laves phase (MgCu2 type) and also for the hexagonal Sc0.5In0.5Co2-type phase.

Keywords: crystal structure; isothermal section; solid solution; ternary system Sc–Co–In
Corresponding author: Rainer Pöttgen, Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstraße 30, 48149 Münster, Germany, E-mail:

Acknowledgements

The authors thank R. Ya. Serkiz (Laboratory of Low Temperature Investigations, Ivan Franko National University of Lviv) for collecting the SEM/EDX data.

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

1. Kalychak, Y. M., Zaremba, V. I., Pöttgen, R., Lukachuk, M., Hoffmann, R. D. Rare earth-transition metal-indides. In Handbook on the Physics and Chemistry of Rare Earths; GschneidnerJr.K. A., Bünzli, J. C. G., Pecharsky, V. K., Eds., Vol. 34. Elsevier: Amsterdam, 2005, pp. 1–133.10.1016/S0168-1273(04)34001-8Search in Google Scholar

2. Villars, P., Cenzual, K. Pearson’s Crystal Data: Crystal Structure Database for Inorganic Compounds (Release 2021/22); ASM International®: Materials Park, Ohio (USA), 2021.Search in Google Scholar

3. Kalychak, Y. M. Metally 1998, 4, 110–118.10.1111/j.1559-3584.1998.tb02937.xSearch in Google Scholar

4. Kalychak, Y. M. Ukr J. Chem. 1998, 64, 15–20.10.1108/07363769810202718Search in Google Scholar

5. Zaremba, V., Dzevenko, M., Nychyporuk, G., Kalychak, Y. Visn. Lviv Univ. Ser. Chem. 2021, 62, 18–27; https://doi.org/10.30970/vch.6201.018.Search in Google Scholar

6. Zaremba, V., Dzevenko, M., Pöttgen, R., Kalychak, Y. Z. Naturforsch. 2019, 74b, 613–618; https://doi.org/10.1515/znb-2019-0083.Search in Google Scholar

7. Dzevenko, M., Tyvanchuk, Y., Demidova, C., Lukachuk, M., Kalychak, Y. Visn. Lviv Univ. Ser. Chem. 2014, 55, 21–28.Search in Google Scholar

8. Tyvanchuk, Y. B., Zaremba, V. I., Akselrud, L. G., Szytula, A., Kalychak, Y. M. J. Alloys Compd. 2017, 704, 717–723; https://doi.org/10.1016/j.jallcom.2017.02.023.Search in Google Scholar

9. Dzevenko, M., Tyvanchuk, Y., Bratash, L., Zaremba, V., Havela, L., Kalychak, Y. J. Solid State Chem. 2011, 184, 2707–2712; https://doi.org/10.1016/j.jssc.2011.08.006.Search in Google Scholar

10. Tyvanchuk, Y. B., Lukachuk, M., Pöttgen, R., Szytuła, A., Kalychak, Y. M. Z. Naturforsch. 2015, 70b, 665–670; https://doi.org/10.1515/znb-2015-0075.Search in Google Scholar

11. Kalychak, Y. M. Visn. Lviv Univ. Ser. Chem. 1999, 38, 70–73.Search in Google Scholar

12. Dzevenko, M., Hamyk, A., Tyvanchuk, Y., Kalychak, Y. Cent. Eur. J. Chem. 2013, 11, 604–609; https://doi.org/10.2478/s11532-012-0195-y.Search in Google Scholar

13. Gabay, A. M., Hadjipanayis, G. C. J. Alloys Compd. 2010, 500, 161–166; https://doi.org/10.1016/j.jallcom.2010.03.247.Search in Google Scholar

14. Gulay, N. L., Tyvanchuk, Y. B., Kalychak, Y. M., Kaczorowski, D. J. Alloys Compd. 2018, 731, 222–228; https://doi.org/10.1016/j.jallcom.2017.10.023.Search in Google Scholar

15. Gulay, N. L., Kalychak, Y. M., Pöttgen, R. Z. Naturforsch. 2020, 75b, 799–803; https://doi.org/10.1515/znb-2020-0104.Search in Google Scholar

16. Zaremba, R. I., Kalychak, Y. M., Rodewald, U. C., Pöttgen, R., Zaremba, V. I. Z. Naturforsch. 2006, 61b, 942–948; https://doi.org/10.1515/znb-2006-0803.Search in Google Scholar

17. Tyvanchuk, Y., Gulay, N., Bigun, I., Galadzhun, Y., Kalychak, Y. Z. Naturforsch. 2015, 70b, 283–287; https://doi.org/10.1515/znb-2014-0216.Search in Google Scholar

18. Gulay, N., Tyvanchuk, Y., Kalychak, Y. Visn. Lviv Univ. Ser. Chem. 2017, 58, 63–68.Search in Google Scholar

19. Gulay, N., Tyvanchuk, Y., Daszkiewicz, M., Stelmakhovych, B., Kalychak, Y. Z. Naturforsch. 2019, 74b, 289–295; https://doi.org/10.1515/znb-2018-0275.Search in Google Scholar

20. Gulay, N. L., Kalychak, Y. M., Pöttgen, R. Z. Anorg. Allg. Chem. 2021, 647, 75–80; https://doi.org/10.1002/zaac.202000362.Search in Google Scholar

21. Gulay, N. L., Kalychak, Y. M., Pöttgen, R. Z. Naturforsch. 2021, 76b, 345–354.10.1515/znb-2021-0052Search in Google Scholar

22. Gulay, N., Daszkiewicz, M., Tyvanchuk, Y., Kalychak, Y. Visn. Lviv Univ. Ser. Chem. 2018, 59, 60–66; https://doi.org/10.30970/vch.5901.060.Search in Google Scholar

23. Gulay, N., Tyvanchuk, Y., Daszkiewicz, M., Kaczorowski, D., Kalychak, Y. Abstr. XXth Ukr. Conf. Inorg. Chem., Dnipro, 2018; p. 111.Search in Google Scholar

24. Massalsky, T. B., Ed. Binary Alloy Phase Diagrams. American Society for Metals: Metal Park, Ohio, Vols. 1–3, 1986.Search in Google Scholar

25. Schöbel, J. D., Stadelmaier, H. H. Z. Metallkd. 1970, 61, 342–343.Search in Google Scholar

26. Markiv, V. Y., Gavrilenko, I. S., Pet’kov, V. V., Belyavina, N. N. Metallofizika 1978, 73, 39–45.Search in Google Scholar

27. Yatsenko, S. P., Semyannikov, A. A., Shakarov, H. O., Fedorova, E. G. J. Less-Common Met. 1983, 90, 95–108; https://doi.org/10.1016/0022-5088(83)90121-2.Search in Google Scholar

28. Palenzona, A., Manfrinetti, P., Palenzona, R. J. Alloys Compd. 1996, 243, 182–185; https://doi.org/10.1016/s0925-8388(96)02402-4.Search in Google Scholar

29. Gulay, N. L., Kösters, J., Kalychak, Y. M., Matar, S. F., Rabenbauer, A., Nilges, T., Pöttgen, R. Z. Kristallogr. 2022, 237, 239–248; https://doi.org/10.1515/zkri-2022-0020.Search in Google Scholar

30. Kraus, W., Nolze, G. PowderCell for Windows (Version 2.4); Federal Institute for Materials Research and Testing: Berlin (Germany), 2000.Search in Google Scholar

31. Yvon, K., Jeitschko, W., Parthé, E. J. Appl. Crystallogr. 1977, 10, 73–74; https://doi.org/10.1107/s0021889877012898.Search in Google Scholar

32. Akselrud, L., Grin, Y. J. Appl. Crystallogr. 2014, 47, 803–805; https://doi.org/10.1107/s1600576714001058.Search in Google Scholar

33. Donohue, J. The Structures of the Elements; Wiley: New York, 1974.Search in Google Scholar

34. Kalychak, Y. M., Akselrud, L. G., Zaremba, V. I., Baranyak, V. M. Dopov. Akad. Nauk Ukr. RSR, Ser. B 1984, 8, 35–37.Search in Google Scholar

35. Kalychak, Y. M., Zaremba, V. I., Stepien-Damm, J., Galadzhun, Y. V., Akselrud, L. G. Kristallografia 1998, 43, 17–20.Search in Google Scholar

36. Dzevenko, M. V., Zaremba, R. I., Hlukhyy, V. H., Rodewald, U. C., Pöttgen, R., Kalychak, Y. M. Z. Anorg. Allg. Chem. 2007, 633, 724–728; https://doi.org/10.1002/zaac.200600328.Search in Google Scholar

37. Gulay, N. L., Kösters, J., Kalychak, Y. M., Pöttgen, R. Z. Naturforsch. 2020, 75b, 715–720; https://doi.org/10.1515/znb-2020-0048.Search in Google Scholar

38. Gulay, N. L., Kalychak, Y. M., Reimann, M. K., Paulsen, C., Kösters, J., Pöttgen, R. Monatsh. Chem. 2020, 151, 1673–1679; https://doi.org/10.1007/s00706-020-02701-7.Search in Google Scholar

39. Kersting, M., Rodewald, U. C., Pöttgen, R. Z. Kristallogr. 2015, 230, 151–155; https://doi.org/10.1515/zkri-2014-1831.Search in Google Scholar

40. Gulay, N. L., Osthues, H., Amirjalayer, S., Doltsinis, N. L., Reimann, M. K., Kalychak, Y. M., Pöttgen, R. Dalton Trans. 2022, to be submitted.Search in Google Scholar

41. Emsley, J. The Elements; Oxford University Press: Oxford, 1999.Search in Google Scholar

42. Lukachuk, M., Zaremba, V. I., Hoffmann, R. D., Pöttgen, R. Z. Naturforsch. 2004, 59b, 182–189; https://doi.org/10.1515/znb-2004-0210.Search in Google Scholar

43. Kalychak, Y. M. J. Alloys Compd. 1999, 291, 80–88; https://doi.org/10.1016/s0925-8388(99)00290-x.Search in Google Scholar

44. Sojka, L., Daszkiewicz, M., Manyako, M., Belan, B., Marciniak, B., Rozycka-Sokolowska, E., Kalychak, Y. Proc. Shevchenko Sci. Soc., Ser. Chem. and Biochem. 2007, 18, 174–182.Search in Google Scholar

45. Thimmaiah, S., Weber, J., Miller, G. J. Z. Anorg. Allg. Chem. 2009, 635, 1831–1839; https://doi.org/10.1002/zaac.200900222.Search in Google Scholar

46. Zaremba, V. I., Muts, I. R., Rodewald, U. C., Hlukhyy, V., Pöttgen, R. Z. Anorg. Allg. Chem. 2004, 630, 1903–1907; https://doi.org/10.1002/zaac.200400187.Search in Google Scholar

47. Lukachuk, M., Rodewald, U. C., Zaremba, V. I., Hoffmann, R. D., Pöttgen, R. Z. Anorg. Allg. Chem. 2004, 630, 2253–2261; https://doi.org/10.1002/zaac.200400160.Search in Google Scholar

48. Khan, Y., Schubert, K. J. Less-Common Met. 1970, 20, 266–268; https://doi.org/10.1016/0022-5088(70)90071-8.Search in Google Scholar
Received: 2022-07-13
Accepted: 2022-08-01
Published Online: 2022-08-29
Published in Print: 2022-10-26

© 2022 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Research Articles
  4. Intermediate ytterbium valence in YbRhSn2
  5. Intermetallic compounds RE2Ga2Mg (RE = Tb–Tm, Lu) with Mo2B2Fe-type structure
  6. Synthesis, crystal structure and magnetic properties of mer-tricyanidoiron(III) precursor-based 1D heterobimetallic complexes
  7. The ternary system Sc–Co–In at 870 K: the isothermal section and the crystal structures of the compounds
  8. High-pressure synthesis of borate-nitrates: crystal structure of M3B7O13(NO3) (M = Co2+, Ni2+, Cu2+, Zn2+, Cd2+)
  9. Mg2MnGa3 – An orthorhombically distorted superstructure variant of the hexagonal Laves phase MgZn2
  10. Lu26 T 17–x In x (T = Rh, Ir, Pt) – first indium intermetallics with Sm26Co11Ga6-type structure
  11. Orthoamide und Iminiumsalze, CVIa. Kondensationsreaktionen von Orthoamiden der Alkincarbonsäuren mit CH-aciden Methylheterocyclen
https://doi.org/10.1515/znb-2022-0105
Keywords for this article
crystal structure; isothermal section; solid solution; ternary system Sc–Co–In

Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Research Articles
  4. Intermediate ytterbium valence in YbRhSn2
  5. Intermetallic compounds RE2Ga2Mg (RE = Tb–Tm, Lu) with Mo2B2Fe-type structure
  6. Synthesis, crystal structure and magnetic properties of mer-tricyanidoiron(III) precursor-based 1D heterobimetallic complexes
  7. The ternary system Sc–Co–In at 870 K: the isothermal section and the crystal structures of the compounds
  8. High-pressure synthesis of borate-nitrates: crystal structure of M3B7O13(NO3) (M = Co2+, Ni2+, Cu2+, Zn2+, Cd2+)
  9. Mg2MnGa3 – An orthorhombically distorted superstructure variant of the hexagonal Laves phase MgZn2
  10. Lu26 T 17–x In x (T = Rh, Ir, Pt) – first indium intermetallics with Sm26Co11Ga6-type structure
  11. Orthoamide und Iminiumsalze, CVIa. Kondensationsreaktionen von Orthoamiden der Alkincarbonsäuren mit CH-aciden Methylheterocyclen
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 25.7.2025 from https://www.degruyterbrill.com/document/doi/10.1515/znb-2022-0105/html
Scroll to top button