Home Lu26 T 17–x In x (T = Rh, Ir, Pt) – first indium intermetallics with Sm26Co11Ga6-type structure
Article
Licensed
Unlicensed Requires Authentication

Lu26 T 17–x In x (T = Rh, Ir, Pt) – first indium intermetallics with Sm26Co11Ga6-type structure

  • Nataliya L. Gulay , Jutta Kösters , Maximilian Kai Reimann , Yaroslav M. Kalychak and Rainer Pöttgen EMAIL logo
Published/Copyright: August 29, 2022
Become an author with De Gruyter Brill
Author Information Explore this Subject
Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 77 Issue 10

Abstract

Several Lu26 T 17−x In x (T = Rh, Ir, Pt) phases with varying x values were obtained by induction-melting reactions of the elements in sealed tantalum ampoules. All samples were characterized through their X-ray powder diffraction patterns. These compounds crystallize with the tetragonal Sm26Co11Ga6-type structure, space group P4/mbm and Z = 2. The structure of Lu26Pt7.55In9.45 has been refined from single-crystal X-ray diffractometer data: a = 1165.32(5), c = 1547.46(6) pm, wR2 = 0.0895, 2173 F 2 values and 70 variables. The Lu26 T 17−x In x phases are the first indium representatives of the Sm26Co11Ga6 type. They belong to the n = 4 members of Parthé’s A 5n+6 B 3n+5 series, which show different stacking sequences of square prisms and antiprisms. Lu26Pt7.55In9.45 as a lutetium-rich intermetallic compound exhibits a broader range of shorter Lu–Lu distances (341–375 pm). Temperature dependent magnetic susceptibility measurements show Pauli paramagnetism for Lu26Ir8.5In8.5 and Lu26Rh7In10 with room temperature values of the magnetic susceptibility of χ = 1.53 × 10−3 emu mol−1 for Lu26Rh7In10 and χ = 6.54 × 10−4 emu mol−1 for Lu26Ir8.5In8.5.

Keywords: intermetallics; rare earth compounds; Sm26Co11Ga6 type
Corresponding author: Rainer Pöttgen, Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstrasse 30, 48149 Münster, Germany, E-mail:

Acknowledgements

We thank M. Sc. C. Paulsen for the EDX analyses.

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

1. Villars, P., Cenzual, K. Pearson’s Crystal Data: Crystal Structure Database for Inorganic Compounds (Release 2021/22); ASM International®: Materials Park, Ohio (USA), 2021.Search in Google Scholar

2. Gulay, N. L., Kalychak, Y. M., Pöttgen, R. Z. Anorg. Allg. Chem. 2022, 648; https://doi.org/10.1002/zaac.202100356.Search in Google Scholar

3. Gulay, N. L., Reimann, M. K., Kalychak, Y. M., Pöttgen, R. Z. Anorg. Allg. Chem. 2022, 648, 49–57.10.1002/zaac.202100356Search in Google Scholar

4. Gulay, N. L., Reimann, M. K., Kalychak, Y. M., Pöttgen, R. Z. Naturforsch. 2022, 77b, 347–352; https://doi.org/10.1515/znb-2021-0166.Search in Google Scholar

5. Dzevenko, M. V., Zaremba, R. I., Hlukhyy, V. H., Rodewald, U. C., Pöttgen, R., Kalychak, Y. M. Z. Anorg. Allg. Chem. 2007, 633, 724–728; https://doi.org/10.1002/zaac.200600328.Search in Google Scholar

6. Kalychak, J. M., Zaremba, V. I., Zavalij, P. Y. Z. Kristallogr. 1993, 208, 380–381; https://doi.org/10.1524/zkri.1993.208.12.380.Search in Google Scholar

7. Zaremba, V. I., Kalychak, Y. M., Zavalii, P. Y. Sov. Phys. Crystallogr. 1992, 37, 178–180.Search in Google Scholar

8. Zaremba, V. I., Kalychak, Y. M., Dzevenko, M. V., Rodewald, U. C., Heying, B., Pöttgen, R. Z. Naturforsch. 2006, 61b, 23–28; https://doi.org/10.1515/znb-2006-0105.Search in Google Scholar

9. Galadzhun, Y. V., Hoffmann, R. D., Heletta, L., Horiacha, M., Pöttgen, R. Z. Anorg. Allg. Chem. 2018, 644, 1513–1518; https://doi.org/10.1002/zaac.201800188.Search in Google Scholar

10. Zaremba, R., Rodewald, U. C., Hoffmann, R. D., Pöttgen, R. Monatsh. Chem. 2007, 138, 523–528; https://doi.org/10.1007/s00706-007-0663-9.Search in Google Scholar

11. Gulay, N. L., Kreiner, G., Kalychak, Y. M., Pöttgen, R. Z. Kristallogr. 2022, 237, 293–302. https://doi.org/10.1515/zkri-2022-0031.Search in Google Scholar

12. Yarmolyuk, Y. P., Grin, Y. N., Olesh, O. M. Sov. Phys. Crystallogr. 1980, 25, 143–146.Search in Google Scholar

13. Le Roy, J., Moreau, J. M., Paccard, D., Parthé, E. J. Less-Common Met. 1980, 76, 131–135; https://doi.org/10.1016/0022-5088(80)90016-8.Search in Google Scholar

14. Pöttgen, R., Gulden, Th., Simon, A. GIT Labor-Fachzeitschrift 1999, 43, 133–136.Search in Google Scholar

15. Pöttgen, R., Lang, A., Hoffmann, R. D., Künnen, B., Kotzyba, G., Müllmann, R., Mosel, B. D., Rosenhahn, C. Z. Kristallogr. 1999, 214, 143–150.10.1524/zkri.1999.214.3.143Search in Google Scholar

16. Yvon, K., Jeitschko, W., Parthé, E. J. Appl. Crystallogr. 1977, 10, 73–74; https://doi.org/10.1107/s0021889877012898.Search in Google Scholar

17. Palatinus, L. Acta Crystallogr. 2013, B69, 1–16; https://doi.org/10.1107/s0108767313099868.Search in Google Scholar

18. Palatinus, L., Chapuis, G. J. Appl. Crystallogr. 2007, 40, 786–790; https://doi.org/10.1107/s0021889807029238.Search in Google Scholar

19. Petříček, V., Dušek, M., Palatinus, L. Z. Kristallogr. 2014, 229, 345–352; https://doi.org/10.1515/zkri-2014-1737.Search in Google Scholar

20. OriginPro 2016G (version 9.3.2.303); OriginLab Corporation: Northampton, Massachusetts (USA), 2016.Search in Google Scholar

21. CorelDraw Graphics Suite 2017 (version 19.0.0.328); Corel Corporation: Ottawa, Ontario (Canada), 2017.Search in Google Scholar

22. Sichevich, O. M., Grin, Yu., Yarmolyuk, Y. P. Russ. Metall. 1989, 2, 198–200.Search in Google Scholar

23. Morozkin, A. V., Garshev, A. V., Knotko, A. V., Yapaskurt, V. O., Yao, J. J. Solid State Chem. 2019, 277, 303–315; https://doi.org/10.1016/j.jssc.2019.06.026.Search in Google Scholar

24. Gladyshevskii, R. E., Grin, Y., Yarmolyuk, Y. P. Stabiln. Metastabiln. Fazovye Ravnovesiya Met. Sist. 1985, 49–54.Search in Google Scholar

25. Myakush, O. R., Fedorchuk, A. A., Zelinskii, A. V. Inorg. Mater. 1998, 34, 562–565.Search in Google Scholar

26. Murashova, E. V. Kurenbaeva Zh. M. Inorg. Mater. 2019, 55, 785–792; https://doi.org/10.1134/s0020168519080107.Search in Google Scholar

27. Myakush, O., Fedorchuk, A. Visn. Lviv Univ. Ser. Chem. 2001, 40, 32–35.Search in Google Scholar

28. Hermes, W., Matar, S. F., Pöttgen, R. Z. Naturforsch. 2009, 64b, 901–908; https://doi.org/10.1515/znb-2009-0805.Search in Google Scholar

29. Mishra, T., Hoffmann, R. D., Schwickert, C., Pöttgen, R. Z. Naturforsch. 2011, 66b, 771–776; https://doi.org/10.5560/znb.2011.66b0771.Search in Google Scholar

30. Aronsson, B. Acta Chem. Scand. 1955, 9, 1107–1110; https://doi.org/10.3891/acta.chem.scand.09-1107.Search in Google Scholar

31. Moreau, J. M., Paccard, D., Parthé, E. Acta Crystallogr. 1976, B32, 1767–1771; https://doi.org/10.1107/s0567740876006365.Search in Google Scholar

32. Fornasini, M. L., Franceschi, E. Acta Crystallogr. 1977, B33, 3476–3479; https://doi.org/10.1107/s0567740877011236.Search in Google Scholar

33. Cromer, D. T., Larson, A. C. Acta Crystallogr. 1977, B33, 2620–2627; https://doi.org/10.1107/s0567740877009030.Search in Google Scholar

34. Leon-Escamilla, E. A., Hurng, W. M., Peterson, E. S. Corbett J. D. Inorg. Chem. 1997, 36, 703–710; https://doi.org/10.1021/ic961035w.Search in Google Scholar

35. Tappe, F., Schappacher, F. M., Langer, T., Schellenberg, I., Pöttgen, R. Z. Naturforsch. 2012, 67b, 594–604; https://doi.org/10.5560/znb.2012-0070.Search in Google Scholar

36. Leon-Escamilla, E. A. Corbett J. D. Inorg. Chem. 1999, 38, 738–743; https://doi.org/10.1021/ic980861x.Search in Google Scholar

37. Kurenbaeva, Z. M., Tursina, A. I., Murashova, E. V., Nesterenko, S. N., Seropegin, Y. D. Russ. J. Inorg. Chem. 2011, 56, 218–222; https://doi.org/10.1134/s003602361102015x.Search in Google Scholar

38. Emsley, J. The Elements; Oxford University Press: Oxford, 1999.Search in Google Scholar

39. Donohue, J. The Structures of the Elements; Wiley: New York, 1974.Search in Google Scholar
Received: 2022-07-22
Accepted: 2022-08-07
Published Online: 2022-08-29
Published in Print: 2022-10-26

© 2022 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Research Articles
  4. Intermediate ytterbium valence in YbRhSn2
  5. Intermetallic compounds RE2Ga2Mg (RE = Tb–Tm, Lu) with Mo2B2Fe-type structure
  6. Synthesis, crystal structure and magnetic properties of mer-tricyanidoiron(III) precursor-based 1D heterobimetallic complexes
  7. The ternary system Sc–Co–In at 870 K: the isothermal section and the crystal structures of the compounds
  8. High-pressure synthesis of borate-nitrates: crystal structure of M3B7O13(NO3) (M = Co2+, Ni2+, Cu2+, Zn2+, Cd2+)
  9. Mg2MnGa3 – An orthorhombically distorted superstructure variant of the hexagonal Laves phase MgZn2
  10. Lu26 T 17–x In x (T = Rh, Ir, Pt) – first indium intermetallics with Sm26Co11Ga6-type structure
  11. Orthoamide und Iminiumsalze, CVIa. Kondensationsreaktionen von Orthoamiden der Alkincarbonsäuren mit CH-aciden Methylheterocyclen
https://doi.org/10.1515/znb-2022-0111
Keywords for this article
intermetallics; rare earth compounds; Sm26Co11Ga6 type

Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Research Articles
  4. Intermediate ytterbium valence in YbRhSn2
  5. Intermetallic compounds RE2Ga2Mg (RE = Tb–Tm, Lu) with Mo2B2Fe-type structure
  6. Synthesis, crystal structure and magnetic properties of mer-tricyanidoiron(III) precursor-based 1D heterobimetallic complexes
  7. The ternary system Sc–Co–In at 870 K: the isothermal section and the crystal structures of the compounds
  8. High-pressure synthesis of borate-nitrates: crystal structure of M3B7O13(NO3) (M = Co2+, Ni2+, Cu2+, Zn2+, Cd2+)
  9. Mg2MnGa3 – An orthorhombically distorted superstructure variant of the hexagonal Laves phase MgZn2
  10. Lu26 T 17–x In x (T = Rh, Ir, Pt) – first indium intermetallics with Sm26Co11Ga6-type structure
  11. Orthoamide und Iminiumsalze, CVIa. Kondensationsreaktionen von Orthoamiden der Alkincarbonsäuren mit CH-aciden Methylheterocyclen
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 26.9.2025 from https://www.degruyterbrill.com/document/doi/10.1515/znb-2022-0111/html
Scroll to top button