Cd(II) and Zn(II) thiocyanate coordination compounds with 3-ethylpyridine: synthesis, crystal structures and properties
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Tristan Neumann
Abstract
Reaction of Cd(NCS)2 and Zn(NCS)2 with 3-ethylpyridine leads to the formation of compounds of compositions M(NCS)2(3-ethylpyridine)4 (M=Cd, 1-Cd; Zn, 1-Zn) and M(NCS)2(3-ethylpyridine)2 (M=Cd, 2-Cd; Zn, 2-Zn). 1-Cd and 1-Zn are isotypic and form discrete complexes in which the metal cations are octahedrally coordinated by two trans-coordinating N-bonded thiocyanate anions and four 3-ethylpyridine co-ligands. In 2-Cd the cations are also octahedrally coordinated but linked into chains by pairs of μ-1,3-bridging anionic ligands. 2-Zn is built up of discrete complexes, in which the Zn cation is tetrahedrally coordinated by two N-bonded thiocyanate anions and two 3-ethylpyridine co-ligands. Compounds 1-Cd, 2-Cd and 2-Zn can be prepared in a pure state, whereas 1-Zn is unstable and transforms on storage into 2-Zn. If 1-Cd and 1-Zn are heated, a transformation into 2-Cd, respectively 2-Zn is observed. Luminescence measurements reveal that 1-Cd, 2-Cd and 2-Zn emit light in the blue spectral range with maxima at, respectively, 21724, 21654 and 22055 cm−1, assigned to ligand-based luminescence.
Acknowledgments
This project was supported by the Deutsche Forschungsgemeinschaft (Project No. Na 720/5-2 and TE1147/1-1) and the State of Schleswig-Holstein. We thank Prof. Dr. Wolfgang Bensch for access to his experimental facilities.
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Articles in the same Issue
- Frontmatter
- In this Issue
- Synthesis and biological evaluation of chalcone-triazole hybrid derivatives as 15-LOX inhibitors
- Synthesis, crystal structure, and photoluminescence of a lithium isothiocyanate compound with 18-crown-6
- Synthesis of madecassic acid derivatives and their cytotoxic activity
- Charge density studies on methylene blue – a potential anti-Alzheimer agent
- Fused thia-heterocycles via isothiocyanates. Part II. A convenient synthesis of some new thieno[2,3-b]thiopyran-4-one derivatives
- Cd(II) and Zn(II) thiocyanate coordination compounds with 3-ethylpyridine: synthesis, crystal structures and properties
- Aminkomplexe des Goldes, Teil 10: Gold(I)-thiocyanat-Komplexe mit Tetrahydrothiophen, Dimethylsulfid, Ammoniak, Aminen und Azaaromatena
Articles in the same Issue
- Frontmatter
- In this Issue
- Synthesis and biological evaluation of chalcone-triazole hybrid derivatives as 15-LOX inhibitors
- Synthesis, crystal structure, and photoluminescence of a lithium isothiocyanate compound with 18-crown-6
- Synthesis of madecassic acid derivatives and their cytotoxic activity
- Charge density studies on methylene blue – a potential anti-Alzheimer agent
- Fused thia-heterocycles via isothiocyanates. Part II. A convenient synthesis of some new thieno[2,3-b]thiopyran-4-one derivatives
- Cd(II) and Zn(II) thiocyanate coordination compounds with 3-ethylpyridine: synthesis, crystal structures and properties
- Aminkomplexe des Goldes, Teil 10: Gold(I)-thiocyanat-Komplexe mit Tetrahydrothiophen, Dimethylsulfid, Ammoniak, Aminen und Azaaromatena
