Startseite peri-Interactions in Naphthalenes, 11 . A New Approach to the Investigation of Dative peri Bonding/A New Approach to the Investigation of Dative peri Bonding
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peri-Interactions in Naphthalenes, 11 . A New Approach to the Investigation of Dative peri Bonding/A New Approach to the Investigation of Dative peri Bonding

  • Günter Paulus Schiemenz EMAIL logo , Söke Petersen und Simon Pörksen
Veröffentlicht/Copyright: 2. Juni 2014
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Zeitschrift für Naturforschung B
Aus der Zeitschrift Zeitschrift für Naturforschung B Band 58 Heft 8

The failure of the sum of van der Waals radii axiom to provide information about donor-acceptor interactions in 8-dimethylamino-naphth-1-yl phosphines and their derivatives called for alternative methods. The coupling constants J(C,H) of the Me2N groups proved useful and indicate that in these compounds, N→P interactions are negligible.

Keywords: Octet Rule; Naphthalene peri-Interactions; N→P Bonding; 1J and 3J(C,H) Coupling
Received: 2003-4-7
Published Online: 2014-6-2
Published in Print: 2003-8-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Artikel in diesem Heft

  1. Triiodotelluronium Hexafluoroarsenate TeI3[AsF6]. The Crystal Structure of the Hemi SO2 Solvate and the Structure Relation to the Unsolvated Form
  2. peri-Interactions in Naphthalenes, 11 . A New Approach to the Investigation of Dative peri Bonding/A New Approach to the Investigation of Dative peri Bonding
  3. Zu den pseudobinären Zustandssystemen Bi2Ch3-BiX3 und den ternären Phasen auf diesen Schnitten (Ch = S, Se, Te; X = Cl, Br, I), I: Bismutsulfidhalogenide/The Pseudobinary Systems Bi2Ch3-BiX3 and the Ternary Phases on their Boundary Lines (Ch = S, Se, Te; X = Cl, Br, I), I: Bismuth Sulfide Halides
  4. Investigations on the Redox-Photochromism of Rhodium Acetonitrile Complexes
  5. Synthesis, Spectroscopic Properties, and Crystal Structure of the Oxonium Acid [H(OEt2)2]+[Ti2Cl9]–
  6. Ligand Properties of Tri(2-thienyl)- and Tri(2-furyl)phosphine and -arsine (2-C4H3E)3P/As (E = O, S) in Gold(I) Complexes
  7. Synthesis and Structures of Simple (Silylmethyl)(methyl)ethers
  8. Regioselective Glycosylation of Glucosamine and Galactosamine Derivates Using O-Pivaloyl Galactosyl Donors
  9. Guest-Host Systems of 1,3,5-Tristyrylbenzenes
  10. 6-Phenyldibenzo[b,d]phosphinine
  11. Kinetics and Mechanism of Oxidation of Dimethyl Sulphoxide by Mono- and Di-Substituted N,N-Dichlorobenzenesulphonamides in Aqueous Acetic Acid
  12. A New Diterpene from Dictyota crenulata
  13. Synthesis and Radiosynthesis of 17α-[p-(Iodophenylethynyl)]estra-3,17β-diols
  14. Synthesis and Structure of YbIrIn5
  15. NMR Spectroscopy of Tetra(propyn- 1-yl)silane in the Solid State and in Solution
  16. Preparation and Characterization of 5,6-Dimethyl-5,6-dihydro-[1,4]diselenino[ 2,3-d][1,3]dithiole-2-thione and Similar Compounds
  17. Crystal Structure and Optical Properties of 4-[4-(Dimethylamino)- styryl]-1-methyl-pyridinium Lead Tribromide
  18. Synthesis and Structure of a Zwitterionic Imidazolium 1,3-Dioxanide
  19. ERRATUM
https://doi.org/10.1515/znb-2003-0802
Schlagwörter für diesen Artikel
Octet Rule; Naphthalene peri-Interactions; N→P Bonding; 1J and 3J(C,H) Coupling

Artikel in diesem Heft

  1. Triiodotelluronium Hexafluoroarsenate TeI3[AsF6]. The Crystal Structure of the Hemi SO2 Solvate and the Structure Relation to the Unsolvated Form
  2. peri-Interactions in Naphthalenes, 11 . A New Approach to the Investigation of Dative peri Bonding/A New Approach to the Investigation of Dative peri Bonding
  3. Zu den pseudobinären Zustandssystemen Bi2Ch3-BiX3 und den ternären Phasen auf diesen Schnitten (Ch = S, Se, Te; X = Cl, Br, I), I: Bismutsulfidhalogenide/The Pseudobinary Systems Bi2Ch3-BiX3 and the Ternary Phases on their Boundary Lines (Ch = S, Se, Te; X = Cl, Br, I), I: Bismuth Sulfide Halides
  4. Investigations on the Redox-Photochromism of Rhodium Acetonitrile Complexes
  5. Synthesis, Spectroscopic Properties, and Crystal Structure of the Oxonium Acid [H(OEt2)2]+[Ti2Cl9]–
  6. Ligand Properties of Tri(2-thienyl)- and Tri(2-furyl)phosphine and -arsine (2-C4H3E)3P/As (E = O, S) in Gold(I) Complexes
  7. Synthesis and Structures of Simple (Silylmethyl)(methyl)ethers
  8. Regioselective Glycosylation of Glucosamine and Galactosamine Derivates Using O-Pivaloyl Galactosyl Donors
  9. Guest-Host Systems of 1,3,5-Tristyrylbenzenes
  10. 6-Phenyldibenzo[b,d]phosphinine
  11. Kinetics and Mechanism of Oxidation of Dimethyl Sulphoxide by Mono- and Di-Substituted N,N-Dichlorobenzenesulphonamides in Aqueous Acetic Acid
  12. A New Diterpene from Dictyota crenulata
  13. Synthesis and Radiosynthesis of 17α-[p-(Iodophenylethynyl)]estra-3,17β-diols
  14. Synthesis and Structure of YbIrIn5
  15. NMR Spectroscopy of Tetra(propyn- 1-yl)silane in the Solid State and in Solution
  16. Preparation and Characterization of 5,6-Dimethyl-5,6-dihydro-[1,4]diselenino[ 2,3-d][1,3]dithiole-2-thione and Similar Compounds
  17. Crystal Structure and Optical Properties of 4-[4-(Dimethylamino)- styryl]-1-methyl-pyridinium Lead Tribromide
  18. Synthesis and Structure of a Zwitterionic Imidazolium 1,3-Dioxanide
  19. ERRATUM
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