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Zu den pseudobinären Zustandssystemen Bi2Ch3-BiX3 und den ternären Phasen auf diesen Schnitten (Ch = S, Se, Te; X = Cl, Br, I), I: Bismutsulfidhalogenide/The Pseudobinary Systems Bi2Ch3-BiX3 and the Ternary Phases on their Boundary Lines (Ch = S, Se, Te; X = Cl, Br, I), I: Bismuth Sulfide Halides

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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 58 Issue 8

The phase diagrams of the systems Bi2S3-BiX3 were constructed from results of DTA and total pressure measurements and x-ray analysis. The phases: BiSCl, Bi4S5Cl2 and Bi19S27Cl3 for X = Cl; BiSBr and Bi19S27Br3 for X = Br; BiSI and Bi19S27I3 for X = I exist on the boundary lines. The enthalpies of formation and standard entropies of the phases follow from the coexistence decomposition pressure functions. The data are:

ΔH°B(BiSClf,298) =−49,6 ± 1,6 kcal/mol S°(BiSClf,298) = 30,3 ± 2,5 cal/K·mol

ΔH°B(Bi4S5Cl2,f,298) =−144,4 ± 3 kcal/mol S°(Bi4S5Cl2,f,298) = 114,0 ± 4,6 cal/K·mol

ΔH°B(Bi19S27Cl3,f,298) = −520 ± 10 kcal/mol S°(Bi19S27Cl3,f,298) = 490 ± 10 cal/K·mol

ΔH°B(BiSBrf,298) = −40,2 ± 1,4 kcal/mol S°(BiSBrf,298) = 32,0 ± 3 cal/K·mol

ΔH°B(Bi19S27Br3,f,298) = −493,6 ± 6,7 kcal/mol S°(Bi19S27Br3,f,298) = 499,8 ± 17 cal/K·mol

ΔH°B(BiSIf,298) =−27,8 ± 1,4 kcal/mol S°(BiSIf,298) = 36,1 ± 2,5 cal/K·mol

ΔH°B(Bi19S27I3,f,298) =−464,4 ± 15 kcal/mol S°(Bi19S27I3,f,298) = 502,7 ± 15 cal/K·mol

Keywords: Bismuth Sulfide Halides; Phase Diagrams; Barograms; Total Pressure Measurements; Thermodynamic Data
Received: 2003-3-31
Published Online: 2014-6-2
Published in Print: 2003-8-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Triiodotelluronium Hexafluoroarsenate TeI3[AsF6]. The Crystal Structure of the Hemi SO2 Solvate and the Structure Relation to the Unsolvated Form
  2. peri-Interactions in Naphthalenes, 11 . A New Approach to the Investigation of Dative peri Bonding/A New Approach to the Investigation of Dative peri Bonding
  3. Zu den pseudobinären Zustandssystemen Bi2Ch3-BiX3 und den ternären Phasen auf diesen Schnitten (Ch = S, Se, Te; X = Cl, Br, I), I: Bismutsulfidhalogenide/The Pseudobinary Systems Bi2Ch3-BiX3 and the Ternary Phases on their Boundary Lines (Ch = S, Se, Te; X = Cl, Br, I), I: Bismuth Sulfide Halides
  4. Investigations on the Redox-Photochromism of Rhodium Acetonitrile Complexes
  5. Synthesis, Spectroscopic Properties, and Crystal Structure of the Oxonium Acid [H(OEt2)2]+[Ti2Cl9]–
  6. Ligand Properties of Tri(2-thienyl)- and Tri(2-furyl)phosphine and -arsine (2-C4H3E)3P/As (E = O, S) in Gold(I) Complexes
  7. Synthesis and Structures of Simple (Silylmethyl)(methyl)ethers
  8. Regioselective Glycosylation of Glucosamine and Galactosamine Derivates Using O-Pivaloyl Galactosyl Donors
  9. Guest-Host Systems of 1,3,5-Tristyrylbenzenes
  10. 6-Phenyldibenzo[b,d]phosphinine
  11. Kinetics and Mechanism of Oxidation of Dimethyl Sulphoxide by Mono- and Di-Substituted N,N-Dichlorobenzenesulphonamides in Aqueous Acetic Acid
  12. A New Diterpene from Dictyota crenulata
  13. Synthesis and Radiosynthesis of 17α-[p-(Iodophenylethynyl)]estra-3,17β-diols
  14. Synthesis and Structure of YbIrIn5
  15. NMR Spectroscopy of Tetra(propyn- 1-yl)silane in the Solid State and in Solution
  16. Preparation and Characterization of 5,6-Dimethyl-5,6-dihydro-[1,4]diselenino[ 2,3-d][1,3]dithiole-2-thione and Similar Compounds
  17. Crystal Structure and Optical Properties of 4-[4-(Dimethylamino)- styryl]-1-methyl-pyridinium Lead Tribromide
  18. Synthesis and Structure of a Zwitterionic Imidazolium 1,3-Dioxanide
  19. ERRATUM
https://doi.org/10.1515/znb-2003-0803
Keywords for this article
Bismuth Sulfide Halides; Phase Diagrams; Barograms; Total Pressure Measurements; Thermodynamic Data

Articles in the same Issue

  1. Triiodotelluronium Hexafluoroarsenate TeI3[AsF6]. The Crystal Structure of the Hemi SO2 Solvate and the Structure Relation to the Unsolvated Form
  2. peri-Interactions in Naphthalenes, 11 . A New Approach to the Investigation of Dative peri Bonding/A New Approach to the Investigation of Dative peri Bonding
  3. Zu den pseudobinären Zustandssystemen Bi2Ch3-BiX3 und den ternären Phasen auf diesen Schnitten (Ch = S, Se, Te; X = Cl, Br, I), I: Bismutsulfidhalogenide/The Pseudobinary Systems Bi2Ch3-BiX3 and the Ternary Phases on their Boundary Lines (Ch = S, Se, Te; X = Cl, Br, I), I: Bismuth Sulfide Halides
  4. Investigations on the Redox-Photochromism of Rhodium Acetonitrile Complexes
  5. Synthesis, Spectroscopic Properties, and Crystal Structure of the Oxonium Acid [H(OEt2)2]+[Ti2Cl9]–
  6. Ligand Properties of Tri(2-thienyl)- and Tri(2-furyl)phosphine and -arsine (2-C4H3E)3P/As (E = O, S) in Gold(I) Complexes
  7. Synthesis and Structures of Simple (Silylmethyl)(methyl)ethers
  8. Regioselective Glycosylation of Glucosamine and Galactosamine Derivates Using O-Pivaloyl Galactosyl Donors
  9. Guest-Host Systems of 1,3,5-Tristyrylbenzenes
  10. 6-Phenyldibenzo[b,d]phosphinine
  11. Kinetics and Mechanism of Oxidation of Dimethyl Sulphoxide by Mono- and Di-Substituted N,N-Dichlorobenzenesulphonamides in Aqueous Acetic Acid
  12. A New Diterpene from Dictyota crenulata
  13. Synthesis and Radiosynthesis of 17α-[p-(Iodophenylethynyl)]estra-3,17β-diols
  14. Synthesis and Structure of YbIrIn5
  15. NMR Spectroscopy of Tetra(propyn- 1-yl)silane in the Solid State and in Solution
  16. Preparation and Characterization of 5,6-Dimethyl-5,6-dihydro-[1,4]diselenino[ 2,3-d][1,3]dithiole-2-thione and Similar Compounds
  17. Crystal Structure and Optical Properties of 4-[4-(Dimethylamino)- styryl]-1-methyl-pyridinium Lead Tribromide
  18. Synthesis and Structure of a Zwitterionic Imidazolium 1,3-Dioxanide
  19. ERRATUM
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