Artikel
Lizenziert
Nicht lizenziert
Erfordert eine Authentifizierung
Synthesis, Structural and Spectroscopic Characterization of the α,ω-Diammonioalkane Hexabromorhodates( III) [H3N(CH2)xNH3]2[H5O2][RhBr6]Br2 (x = 3, 4) – IR Spectra of [H5O2]+ Ions with Weak Solid State Interactions
-
Maciej Bujak
Veröffentlicht/Copyright:
2. Juni 2014
The reaction of rhodium(III) chloride trihydrate with 1,3-diaminopropane and 1,4-diaminobutane in concentrated hydrobromic acid results in the formation of the bis(α,ω-diammonioalkane) diaquahydrogen(1+) hexabromorhodate(III) dibromides [H3N(CH2)xNH3]2[H5O2][RhBr6]Br2 (x = 3, 4). Dark red single crystals were obtained by diffusion-controlled crystallization at room temperature. Both compounds crystallize in space group type P1̄ and their structures are closely related. In view of crystal engineering they are inorganic-organic hybrid materials built up from octahedral [RhBr6]3−, simple Br− and flexible chain-like [H3N(CH2)xNH3]2+ ions with the [H5O2]+ and further Br− ions incorporated and thus might be considered as addition compounds [H3N(CH2)xNH3]2[RhBr6]Br ∙ [H5O2]Br. Cationic and anionic moieties in the crystal are held together by a complex system of N-H∙∙∙Br and O-H∙∙∙Br hydrogen bonds. Geometric features of O-H∙∙∙Br hydrogen bonding as well as the pronounced disorder of the [H5O2]+ ions in the diammoniopropane salt indicate the weak association of these species in the solids. Weak association of the ions is also documented by difference ATR-FT-IR spectra of the compounds and related diammonioalkane dibromides that show the stretching modes of the terminal O-H bonds above 3300 cm−1. Further characteristic bands are recognized at ca. 1635 (s), 985 (vs), and 670 (m) cm−1.
Received: 2002-10-9
Published Online: 2014-6-2
Published in Print: 2002-12-1
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung
Sie haben derzeit keinen Zugang zu diesem Inhalt.
Sie haben derzeit keinen Zugang zu diesem Inhalt.
Artikel in diesem Heft
- Zur Kenntnis von Calciumtetrahydrogen-hexaoxo-diperiodattetrahydrat CaH4I2O10 · 4 H2O: Kristallstruktur, Schwingungsspektren und thermische Analyse / On Calciumtetrahydrogen-hexaoxo-diperiodatetetrahydrate CaH4I2O10 · 4 H2O: Crystal Structure, Vibrational Spectroscopy and Thermal Analysis
- Mg5Pd10Si16 und Mg5Pt10Si16, Magnesium-Platinmetall-Silicide mit Tetraedern und gekappten Tetraedern aus Silicium-Atomen / Mg5Pd10Si16 and Mg5Pt10Si16, Magnesium Platinum Metal Silicides with Si4 Tetrahedra and Si12 Truncated Tetrahedra
- Synthesis and Crystal Structure of Zr5Rh2In4 and Hf5Rh2In4 – New Ternary Indides with Lu5Ni2In4 Type Structure
- Crystal Structure of the Ternary Arsenide CeNi1.91As1.94
- Kristallstrukturen und elektronische Eigenschaften von Ge1/3NbS2 und Ge1/4NbS2 / Crystal Structures and Electronic Properties of Ge1/3NbS2 and Ge1/4NbS2
- Ni(C2(COO)2)(H2O)4 · 2 H2O und Ni(C2(COO)2)(H2O)2: zwei Koordinationspolymere mit dem Acetylendicarboxylat-Dianion / Ni(C2(COO)2)(H2O)4 · 2 H2O and Ni(C2 (COO)2)(H2O)2: Two Co-ordination Polymers of the Acetylenedicarboxylate Dianion
- Reactions in Molten Alkalimetal Polychalcogenides: What Happens in the Melt? A Study of the Reactions in the System K-Nb-S Using Differential Scanning Calorimetry, Infrared Spectroscopy, and X-Ray Powder Diffraction
- Synthesis and X-Ray Crystal Structure Determination of Thiotrithiazyl Iododichloride, S4N3ICl2
- Synthesis, Structural and Spectroscopic Characterization of the α,ω-Diammonioalkane Hexabromorhodates( III) [H3N(CH2)xNH3]2[H5O2][RhBr6]Br2 (x = 3, 4) – IR Spectra of [H5O2]+ Ions with Weak Solid State Interactions
- ortho-Lithiation of Benzene-1,2-dithiol: A Methodology for ortho-Functionalization of Benzene-1,2-dithiol
- New Ternary Phosphide La7Pd17P12: Preparation and Crystal Structure
- NdClSeO3 and ErClSeO3: First Chloride-Selenites of the Rare Earth Elements
- Ca(SCN)2 and Ca(SCN)2 · 2 H2O: Crystal Structure, Thermal Behavior and Vibrational Spectroscopy
- Sulfidisch derivatisierte Oxodisilicate der schweren Lanthanide vom Formeltyp M4S3[Si2O7] (M = Gd - Tm) / Sulfide Derivatized Oxodisilicates of the Heavy Lanthanides with the Formula M4S3[Si2O7] (M = Gd - Tm)
- Novel Thioborates of Cesium: Cs3BS3 and Li2CsBS3
- Untersuchungen im System ScCl3 / K2CO3 / H2O: Synthese und Kristallstrukturen von K5[Sc(CO3)4] · 5 H2O und K7[Sc(CO3)4]CO3 · 9 H2O / Investigations on the System ScCl3 / K2CO3 / H2O: Synthesis and Crystal Structures of K5[Sc(CO3)4] · 5 H2O and K7[Sc(CO3)4] CO3 · 9 H2O
- Polyol-Metall-Komplexe, 43 [1]. Galactarato-Komplexe mit Aluminium und Kupfer(II) / Polyol Metal Complexes, 43 [1]. Galactarato Complexes with Aluminium and Copper(II)
- A New Copper (II) Complex with the N,N'-Bis(antipyryl-4-methyl)-piperazine (BAMP) Ligand: [Cu(BAMP)](ClO4)2
- Synthesis and Characterisation of Na5[CoO2]CO3
Schlagwörter für diesen Artikel
Hexabromorhodates(III);
α,ω-Diammonioalkane Cations;
Diaquahydrogen Cation
Artikel in diesem Heft
- Zur Kenntnis von Calciumtetrahydrogen-hexaoxo-diperiodattetrahydrat CaH4I2O10 · 4 H2O: Kristallstruktur, Schwingungsspektren und thermische Analyse / On Calciumtetrahydrogen-hexaoxo-diperiodatetetrahydrate CaH4I2O10 · 4 H2O: Crystal Structure, Vibrational Spectroscopy and Thermal Analysis
- Mg5Pd10Si16 und Mg5Pt10Si16, Magnesium-Platinmetall-Silicide mit Tetraedern und gekappten Tetraedern aus Silicium-Atomen / Mg5Pd10Si16 and Mg5Pt10Si16, Magnesium Platinum Metal Silicides with Si4 Tetrahedra and Si12 Truncated Tetrahedra
- Synthesis and Crystal Structure of Zr5Rh2In4 and Hf5Rh2In4 – New Ternary Indides with Lu5Ni2In4 Type Structure
- Crystal Structure of the Ternary Arsenide CeNi1.91As1.94
- Kristallstrukturen und elektronische Eigenschaften von Ge1/3NbS2 und Ge1/4NbS2 / Crystal Structures and Electronic Properties of Ge1/3NbS2 and Ge1/4NbS2
- Ni(C2(COO)2)(H2O)4 · 2 H2O und Ni(C2(COO)2)(H2O)2: zwei Koordinationspolymere mit dem Acetylendicarboxylat-Dianion / Ni(C2(COO)2)(H2O)4 · 2 H2O and Ni(C2 (COO)2)(H2O)2: Two Co-ordination Polymers of the Acetylenedicarboxylate Dianion
- Reactions in Molten Alkalimetal Polychalcogenides: What Happens in the Melt? A Study of the Reactions in the System K-Nb-S Using Differential Scanning Calorimetry, Infrared Spectroscopy, and X-Ray Powder Diffraction
- Synthesis and X-Ray Crystal Structure Determination of Thiotrithiazyl Iododichloride, S4N3ICl2
- Synthesis, Structural and Spectroscopic Characterization of the α,ω-Diammonioalkane Hexabromorhodates( III) [H3N(CH2)xNH3]2[H5O2][RhBr6]Br2 (x = 3, 4) – IR Spectra of [H5O2]+ Ions with Weak Solid State Interactions
- ortho-Lithiation of Benzene-1,2-dithiol: A Methodology for ortho-Functionalization of Benzene-1,2-dithiol
- New Ternary Phosphide La7Pd17P12: Preparation and Crystal Structure
- NdClSeO3 and ErClSeO3: First Chloride-Selenites of the Rare Earth Elements
- Ca(SCN)2 and Ca(SCN)2 · 2 H2O: Crystal Structure, Thermal Behavior and Vibrational Spectroscopy
- Sulfidisch derivatisierte Oxodisilicate der schweren Lanthanide vom Formeltyp M4S3[Si2O7] (M = Gd - Tm) / Sulfide Derivatized Oxodisilicates of the Heavy Lanthanides with the Formula M4S3[Si2O7] (M = Gd - Tm)
- Novel Thioborates of Cesium: Cs3BS3 and Li2CsBS3
- Untersuchungen im System ScCl3 / K2CO3 / H2O: Synthese und Kristallstrukturen von K5[Sc(CO3)4] · 5 H2O und K7[Sc(CO3)4]CO3 · 9 H2O / Investigations on the System ScCl3 / K2CO3 / H2O: Synthesis and Crystal Structures of K5[Sc(CO3)4] · 5 H2O and K7[Sc(CO3)4] CO3 · 9 H2O
- Polyol-Metall-Komplexe, 43 [1]. Galactarato-Komplexe mit Aluminium und Kupfer(II) / Polyol Metal Complexes, 43 [1]. Galactarato Complexes with Aluminium and Copper(II)
- A New Copper (II) Complex with the N,N'-Bis(antipyryl-4-methyl)-piperazine (BAMP) Ligand: [Cu(BAMP)](ClO4)2
- Synthesis and Characterisation of Na5[CoO2]CO3
