Startseite N-Silylaminotin Trichlorides. Synthesis and Characterisation by Multinuclear Magnetic Resonance Spectroscopy
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N-Silylaminotin Trichlorides. Synthesis and Characterisation by Multinuclear Magnetic Resonance Spectroscopy

  • Bernd Wrackmeyer EMAIL logo , Andreas Pedall und Jürgen Weidinger
Veröffentlicht/Copyright: 2. Juni 2014
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Zeitschrift für Naturforschung B
Aus der Zeitschrift Zeitschrift für Naturforschung B Band 56 Heft 10

N-Silyl-aminotin trichlorides, R1R2N-SnCl3[R1 = R2 = SiMe3 (1a), R1 = SiMe3, R2 = tBu (1b), R = SiMe3, R2 = 9-borabicyclo[3.3.1]nonyl (1c), R1R2 = Me2 SiCH2CH2SiMe2 (1d)] were prepared by the reaction of tin tetrachloride with the respective bis(amino)plumbylenes, (R1R2N)2Pb 4. The analogous reactions with bis(amino)stannylenes, (R1R2N)2Sn 3, afforded only mixtures of the aminotin trichlorides 1 and bis(amino)tin dichlorides, (R1R2N)2 SnCl2 2 . The products were characterised by 1H, 11B, 13C, 15N, 29Si and 119Sn NMR spectroscopy, and the NMR data of 1 were compared with those of the corresponding N-silylamino(trimethyl)tin compounds 8.

Keywords : Tin; Lead; Amides
Received: 2001-6-18
Published Online: 2014-6-2
Published in Print: 2001-10-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Artikel in diesem Heft

  1. Darstellung und Strukturaufklärung von Tricäsiumundecaphosphid- Ammoniakat(1/3) Cs3P11 · 3 NH3 / Synthesis and Crystal Structure of Tricesium Undecaphosphide-Ammonia(l/3) Cs3P11 · 3 NH3
  2. Magnetic Properties and Crystal Structure of a 3,5-Dimethylpyrazolate-Bridged Binuclear Copper(II) Complex
  3. Enantioselective Catalysis, 139 [1]. A Chiral Cyclic Amidine Containing a Pyridine Substituent - Synthesis, Coordination Chemistry, Catalysis
  4. Tetraberyllium-η4-oxo-hexa(arylcarboxylates)
  5. Drei Formen des Samarium(III)-Sulfidselenids Sm2S2-xSe1+x (0,1 ≤ x < 0,2) / Tree Types of the Samarium(III) Sulfide Selenide Sm2S2-xSe1+x (0,1 ≤ x < 0,2)
  6. Investigations on the Thermal Decomposition of Coordination Polymers Based on Copper(I) Halides and 2-Methylpyrazine
  7. Crystal Structure and Tautomerism of 1-[N-(4-Iodophenyl)]aminomethylidene-2(1H)naphthalenone
  8. N-Silylaminotin Trichlorides. Synthesis and Characterisation by Multinuclear Magnetic Resonance Spectroscopy
  9. Synthese und Eigenschaften von 2-Cyanimino-l,3-dimethylimidazolin [1] / Synthesis and Properties of 2-Cyanimino-l,3-dimethylimidazoline [1]
  10. Synthesis and Crystal Structure of (dmaaH)2(dmaH)2[P12Sn12N12(NH)2] · 4 dmaa, dmaa = N,N-Dimethylacetamide, dma = Dimethylamine, an Anhydrous Example of the P12N14Cage
  11. Synthesen, Kristallstrukturen und magnetische Eigenschaften von [Li(12-Krone-4)2][Li(12-Krone-4)(OH2)]2[Nb6Cl18], [Li(15-Krone-5)2(OH2)]3[Nb6Cl18] und [(18-Krone-6)2(O2H5)]3[Nb6Cl18] / Syntheses, Crystal Structures and Magnetic Behaviour of [Li(12-Krone-4)2][Li(12-Krone-4)(OH2)]2[Nb6Cl18], [Li(15-Krone-5)2(OH2)]3[Nb6Cl18] and [(18-Krone-6)2(O2H5)]3[Nb6Cl18]
  12. Investigation of the Thionation Reaction of Cyclic Imides
  13. Polysulfonylamine, CXLII [1]. Ein supramolekulares Monomer-Dimer-Paar: Starke und schwache Wasserstoffbrücken in den Kristallstrukturen von Pyridinium-dimesylamid und 4,4´-Bipyridindiium-bis(dimesylamid) / Polysulfonylamines, CXLII [1]. A Supramolecular Monomer-Dimer Pair: Strong and Weak Hydrogen Bonding in the Crystal Structures of Pyridinium Dimesylamide and 4,4´-Bipyridinediium Bis(dimesylamide)
  14. Polysulfonylamine, CXLIII [1], Rolle schwacher Wasserstoffbrücken (C - H···O) in den Kristallstrukturen von 2,6-Dimethylpyridinium-, 1-Hydroxypyridinium- und Imidazolium-dimesylamid / Polysulfonylamines, CXLIII [1], Role of Weak Hydrogen Bonds (C - H···O) in the Crystal Structures of 2,6-Dimethylpyridinium , 1-Hydroxypyridinium and Imidazolium Dimesylamide
  15. Synthesis and Structural Studies of 5, 11, 17, 23-Tetrahydroxyresorc[4]arenes
  16. Enaminones as Building Blocks In Heterocyclic Synthesis: A New One Pot Synthesis of Polyfunctional Substituted Pyridines
  17. Remangilone D, a New Bisnoroleanane Triterpene, and a New Flavone from Physena madagascariensis [1]
  18. Notizen: Metallkomplexe mit biologisch wichtigen Liganden, CXXXIX [1], Ein Ferrocenylen-verbrücktes Pseudohexapeptid Fe[C5H4CH 2OGlyValOMe(Val-Boc)]2 / Metal Complexes of Biologically Important Ligands, CXXXIX [1]. A Ferrocenylene Bridged Pseudohexapeptide Fe[C5H4CH 2OGlyValOMe(Val-Boc)]2
https://doi.org/10.1515/znb-2001-1008
Schlagwörter für diesen Artikel
Tin; Lead; Amides

Artikel in diesem Heft

  1. Darstellung und Strukturaufklärung von Tricäsiumundecaphosphid- Ammoniakat(1/3) Cs3P11 · 3 NH3 / Synthesis and Crystal Structure of Tricesium Undecaphosphide-Ammonia(l/3) Cs3P11 · 3 NH3
  2. Magnetic Properties and Crystal Structure of a 3,5-Dimethylpyrazolate-Bridged Binuclear Copper(II) Complex
  3. Enantioselective Catalysis, 139 [1]. A Chiral Cyclic Amidine Containing a Pyridine Substituent - Synthesis, Coordination Chemistry, Catalysis
  4. Tetraberyllium-η4-oxo-hexa(arylcarboxylates)
  5. Drei Formen des Samarium(III)-Sulfidselenids Sm2S2-xSe1+x (0,1 ≤ x < 0,2) / Tree Types of the Samarium(III) Sulfide Selenide Sm2S2-xSe1+x (0,1 ≤ x < 0,2)
  6. Investigations on the Thermal Decomposition of Coordination Polymers Based on Copper(I) Halides and 2-Methylpyrazine
  7. Crystal Structure and Tautomerism of 1-[N-(4-Iodophenyl)]aminomethylidene-2(1H)naphthalenone
  8. N-Silylaminotin Trichlorides. Synthesis and Characterisation by Multinuclear Magnetic Resonance Spectroscopy
  9. Synthese und Eigenschaften von 2-Cyanimino-l,3-dimethylimidazolin [1] / Synthesis and Properties of 2-Cyanimino-l,3-dimethylimidazoline [1]
  10. Synthesis and Crystal Structure of (dmaaH)2(dmaH)2[P12Sn12N12(NH)2] · 4 dmaa, dmaa = N,N-Dimethylacetamide, dma = Dimethylamine, an Anhydrous Example of the P12N14Cage
  11. Synthesen, Kristallstrukturen und magnetische Eigenschaften von [Li(12-Krone-4)2][Li(12-Krone-4)(OH2)]2[Nb6Cl18], [Li(15-Krone-5)2(OH2)]3[Nb6Cl18] und [(18-Krone-6)2(O2H5)]3[Nb6Cl18] / Syntheses, Crystal Structures and Magnetic Behaviour of [Li(12-Krone-4)2][Li(12-Krone-4)(OH2)]2[Nb6Cl18], [Li(15-Krone-5)2(OH2)]3[Nb6Cl18] and [(18-Krone-6)2(O2H5)]3[Nb6Cl18]
  12. Investigation of the Thionation Reaction of Cyclic Imides
  13. Polysulfonylamine, CXLII [1]. Ein supramolekulares Monomer-Dimer-Paar: Starke und schwache Wasserstoffbrücken in den Kristallstrukturen von Pyridinium-dimesylamid und 4,4´-Bipyridindiium-bis(dimesylamid) / Polysulfonylamines, CXLII [1]. A Supramolecular Monomer-Dimer Pair: Strong and Weak Hydrogen Bonding in the Crystal Structures of Pyridinium Dimesylamide and 4,4´-Bipyridinediium Bis(dimesylamide)
  14. Polysulfonylamine, CXLIII [1], Rolle schwacher Wasserstoffbrücken (C - H···O) in den Kristallstrukturen von 2,6-Dimethylpyridinium-, 1-Hydroxypyridinium- und Imidazolium-dimesylamid / Polysulfonylamines, CXLIII [1], Role of Weak Hydrogen Bonds (C - H···O) in the Crystal Structures of 2,6-Dimethylpyridinium , 1-Hydroxypyridinium and Imidazolium Dimesylamide
  15. Synthesis and Structural Studies of 5, 11, 17, 23-Tetrahydroxyresorc[4]arenes
  16. Enaminones as Building Blocks In Heterocyclic Synthesis: A New One Pot Synthesis of Polyfunctional Substituted Pyridines
  17. Remangilone D, a New Bisnoroleanane Triterpene, and a New Flavone from Physena madagascariensis [1]
  18. Notizen: Metallkomplexe mit biologisch wichtigen Liganden, CXXXIX [1], Ein Ferrocenylen-verbrücktes Pseudohexapeptid Fe[C5H4CH 2OGlyValOMe(Val-Boc)]2 / Metal Complexes of Biologically Important Ligands, CXXXIX [1]. A Ferrocenylene Bridged Pseudohexapeptide Fe[C5H4CH 2OGlyValOMe(Val-Boc)]2
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