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Investigation of the Thionation Reaction of Cyclic Imides

  • A. Orzeszko , J. K. Maurin and D. Melon-Ksyta
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 56 Issue 10

A series of monothioimides and dithioimides were synthesised using Lawesson’s reagent. It has been found that two main effects affect thionation reaction. The high polarity of carbonyl groups leads to good yields of mono- and dithioimides. On the other hand, steric hindrance in the vicinity of the carbonyl group strongly inhibits the replacement of the oxygen atom by sulfur.

Keywords : Imides; Monothioimides; Dithioimides
Received: 2001-5-11
Published Online: 2014-6-2
Published in Print: 2001-10-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Darstellung und Strukturaufklärung von Tricäsiumundecaphosphid- Ammoniakat(1/3) Cs3P11 · 3 NH3 / Synthesis and Crystal Structure of Tricesium Undecaphosphide-Ammonia(l/3) Cs3P11 · 3 NH3
  2. Magnetic Properties and Crystal Structure of a 3,5-Dimethylpyrazolate-Bridged Binuclear Copper(II) Complex
  3. Enantioselective Catalysis, 139 [1]. A Chiral Cyclic Amidine Containing a Pyridine Substituent - Synthesis, Coordination Chemistry, Catalysis
  4. Tetraberyllium-η4-oxo-hexa(arylcarboxylates)
  5. Drei Formen des Samarium(III)-Sulfidselenids Sm2S2-xSe1+x (0,1 ≤ x < 0,2) / Tree Types of the Samarium(III) Sulfide Selenide Sm2S2-xSe1+x (0,1 ≤ x < 0,2)
  6. Investigations on the Thermal Decomposition of Coordination Polymers Based on Copper(I) Halides and 2-Methylpyrazine
  7. Crystal Structure and Tautomerism of 1-[N-(4-Iodophenyl)]aminomethylidene-2(1H)naphthalenone
  8. N-Silylaminotin Trichlorides. Synthesis and Characterisation by Multinuclear Magnetic Resonance Spectroscopy
  9. Synthese und Eigenschaften von 2-Cyanimino-l,3-dimethylimidazolin [1] / Synthesis and Properties of 2-Cyanimino-l,3-dimethylimidazoline [1]
  10. Synthesis and Crystal Structure of (dmaaH)2(dmaH)2[P12Sn12N12(NH)2] · 4 dmaa, dmaa = N,N-Dimethylacetamide, dma = Dimethylamine, an Anhydrous Example of the P12N14Cage
  11. Synthesen, Kristallstrukturen und magnetische Eigenschaften von [Li(12-Krone-4)2][Li(12-Krone-4)(OH2)]2[Nb6Cl18], [Li(15-Krone-5)2(OH2)]3[Nb6Cl18] und [(18-Krone-6)2(O2H5)]3[Nb6Cl18] / Syntheses, Crystal Structures and Magnetic Behaviour of [Li(12-Krone-4)2][Li(12-Krone-4)(OH2)]2[Nb6Cl18], [Li(15-Krone-5)2(OH2)]3[Nb6Cl18] and [(18-Krone-6)2(O2H5)]3[Nb6Cl18]
  12. Investigation of the Thionation Reaction of Cyclic Imides
  13. Polysulfonylamine, CXLII [1]. Ein supramolekulares Monomer-Dimer-Paar: Starke und schwache Wasserstoffbrücken in den Kristallstrukturen von Pyridinium-dimesylamid und 4,4´-Bipyridindiium-bis(dimesylamid) / Polysulfonylamines, CXLII [1]. A Supramolecular Monomer-Dimer Pair: Strong and Weak Hydrogen Bonding in the Crystal Structures of Pyridinium Dimesylamide and 4,4´-Bipyridinediium Bis(dimesylamide)
  14. Polysulfonylamine, CXLIII [1], Rolle schwacher Wasserstoffbrücken (C - H···O) in den Kristallstrukturen von 2,6-Dimethylpyridinium-, 1-Hydroxypyridinium- und Imidazolium-dimesylamid / Polysulfonylamines, CXLIII [1], Role of Weak Hydrogen Bonds (C - H···O) in the Crystal Structures of 2,6-Dimethylpyridinium , 1-Hydroxypyridinium and Imidazolium Dimesylamide
  15. Synthesis and Structural Studies of 5, 11, 17, 23-Tetrahydroxyresorc[4]arenes
  16. Enaminones as Building Blocks In Heterocyclic Synthesis: A New One Pot Synthesis of Polyfunctional Substituted Pyridines
  17. Remangilone D, a New Bisnoroleanane Triterpene, and a New Flavone from Physena madagascariensis [1]
  18. Notizen: Metallkomplexe mit biologisch wichtigen Liganden, CXXXIX [1], Ein Ferrocenylen-verbrücktes Pseudohexapeptid Fe[C5H4CH 2OGlyValOMe(Val-Boc)]2 / Metal Complexes of Biologically Important Ligands, CXXXIX [1]. A Ferrocenylene Bridged Pseudohexapeptide Fe[C5H4CH 2OGlyValOMe(Val-Boc)]2
https://doi.org/10.1515/znb-2001-1012
Keywords for this article
Imides; Monothioimides; Dithioimides

Articles in the same Issue

  1. Darstellung und Strukturaufklärung von Tricäsiumundecaphosphid- Ammoniakat(1/3) Cs3P11 · 3 NH3 / Synthesis and Crystal Structure of Tricesium Undecaphosphide-Ammonia(l/3) Cs3P11 · 3 NH3
  2. Magnetic Properties and Crystal Structure of a 3,5-Dimethylpyrazolate-Bridged Binuclear Copper(II) Complex
  3. Enantioselective Catalysis, 139 [1]. A Chiral Cyclic Amidine Containing a Pyridine Substituent - Synthesis, Coordination Chemistry, Catalysis
  4. Tetraberyllium-η4-oxo-hexa(arylcarboxylates)
  5. Drei Formen des Samarium(III)-Sulfidselenids Sm2S2-xSe1+x (0,1 ≤ x < 0,2) / Tree Types of the Samarium(III) Sulfide Selenide Sm2S2-xSe1+x (0,1 ≤ x < 0,2)
  6. Investigations on the Thermal Decomposition of Coordination Polymers Based on Copper(I) Halides and 2-Methylpyrazine
  7. Crystal Structure and Tautomerism of 1-[N-(4-Iodophenyl)]aminomethylidene-2(1H)naphthalenone
  8. N-Silylaminotin Trichlorides. Synthesis and Characterisation by Multinuclear Magnetic Resonance Spectroscopy
  9. Synthese und Eigenschaften von 2-Cyanimino-l,3-dimethylimidazolin [1] / Synthesis and Properties of 2-Cyanimino-l,3-dimethylimidazoline [1]
  10. Synthesis and Crystal Structure of (dmaaH)2(dmaH)2[P12Sn12N12(NH)2] · 4 dmaa, dmaa = N,N-Dimethylacetamide, dma = Dimethylamine, an Anhydrous Example of the P12N14Cage
  11. Synthesen, Kristallstrukturen und magnetische Eigenschaften von [Li(12-Krone-4)2][Li(12-Krone-4)(OH2)]2[Nb6Cl18], [Li(15-Krone-5)2(OH2)]3[Nb6Cl18] und [(18-Krone-6)2(O2H5)]3[Nb6Cl18] / Syntheses, Crystal Structures and Magnetic Behaviour of [Li(12-Krone-4)2][Li(12-Krone-4)(OH2)]2[Nb6Cl18], [Li(15-Krone-5)2(OH2)]3[Nb6Cl18] and [(18-Krone-6)2(O2H5)]3[Nb6Cl18]
  12. Investigation of the Thionation Reaction of Cyclic Imides
  13. Polysulfonylamine, CXLII [1]. Ein supramolekulares Monomer-Dimer-Paar: Starke und schwache Wasserstoffbrücken in den Kristallstrukturen von Pyridinium-dimesylamid und 4,4´-Bipyridindiium-bis(dimesylamid) / Polysulfonylamines, CXLII [1]. A Supramolecular Monomer-Dimer Pair: Strong and Weak Hydrogen Bonding in the Crystal Structures of Pyridinium Dimesylamide and 4,4´-Bipyridinediium Bis(dimesylamide)
  14. Polysulfonylamine, CXLIII [1], Rolle schwacher Wasserstoffbrücken (C - H···O) in den Kristallstrukturen von 2,6-Dimethylpyridinium-, 1-Hydroxypyridinium- und Imidazolium-dimesylamid / Polysulfonylamines, CXLIII [1], Role of Weak Hydrogen Bonds (C - H···O) in the Crystal Structures of 2,6-Dimethylpyridinium , 1-Hydroxypyridinium and Imidazolium Dimesylamide
  15. Synthesis and Structural Studies of 5, 11, 17, 23-Tetrahydroxyresorc[4]arenes
  16. Enaminones as Building Blocks In Heterocyclic Synthesis: A New One Pot Synthesis of Polyfunctional Substituted Pyridines
  17. Remangilone D, a New Bisnoroleanane Triterpene, and a New Flavone from Physena madagascariensis [1]
  18. Notizen: Metallkomplexe mit biologisch wichtigen Liganden, CXXXIX [1], Ein Ferrocenylen-verbrücktes Pseudohexapeptid Fe[C5H4CH 2OGlyValOMe(Val-Boc)]2 / Metal Complexes of Biologically Important Ligands, CXXXIX [1]. A Ferrocenylene Bridged Pseudohexapeptide Fe[C5H4CH 2OGlyValOMe(Val-Boc)]2
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