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Structural Characterization Of Rh(Iii) Complexes Containing The Polypyridyl Ligands And Some Properties Of Their Derivatives

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Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 56 Issue 8

The structures of the compounds [Rh(bpy)2(py)(Cl)](ClO4 )2 (2 (ClO4 )2) and [Rh(phen)2(py)- (Cl)](ClO4 )2 (7 -(ClO4 )2) were determined by single-crystal X-ray diffraction. Both complexes show a six-coordinate rhodium atom with two bpy or phen ligands in the cis configuration. The Rh-Cl distances are 2.334(3) and 2.323(2) Å, respectively. The bond angles N-Rh-Cl formed with the axially-positioned nitrogen atom are 174.4(2) and 173.8(2)°. The oxidation of aquo complexes, prepared from the corresponding rhodium chloride complexes, by two equivalents of Ce(IV) in 60% HCIO4 solution yields the corresponding mono-oxo products. All complexes have been identified and characterized by elemental analyses, IR, and 1H NMR data

Keywords : Rhodium; Polypyridyl
Received: 2001-1-26
Published Online: 2014-6-2
Published in Print: 2001-8-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Multianvil High-Pressure Synthesis And Crystal Structure Of β-YbBO3
  2. 2.3-Dihydro-2-Methoxyethylimino-L,3-Dimethylimidazol - Ein Neuer Hemilabil Koordinierender Chelatligand [1]
  3. Soluble Pyridine Complexes Of The Ternary Gallium(III) Chalcogenide Halides (GaEX)3, With E = S, Se And X = Cl, Br
  4. Antiferromagnetic Coupling In A (μ-Hydroxo)(μ-Pyrazolato)Dicopper(II) Complex. Synthesis, Crystal Structure, Magnetic Properties, And Theoretical Studies
  5. Synthesis Of A Large Water-Soluble Gold Cluster (Au32.36) And Its Properties As A Potential Label In Electron Microscopy
  6. Koordination Des Anions Von 2,4-Dicyanoglutaconsäurediethylester An Tripodeisen(Ii)-Einheiten. Die Entstehung Helikaler Strukturen
  7. Structural Characterization Of Rh(Iii) Complexes Containing The Polypyridyl Ligands And Some Properties Of Their Derivatives
  8. Preparation And Crystal Structures Of (Hg3 )(PO4 )Cl, (Hg3)(AsO4)Cl And (Hg3)(AsO4)Br - Mercury Compounds With The Triangular Hg34+ Cluster
  9. Synthese Und Kristallstrukturen Von Chlorometallaten [M = V(III), Mo(V)]
  10. Polysulfonylamine, CXL [1]. N-Cycloalkyldimesylamine C„H2n-1/N(SO2CH3)2: Synthesen (n = 3 -6 ), Festkörper-Molekülstrukturen (n = 4 -6 ) Und Rolle Schwacher Wasserstoffbrücken C-H···O In Den Kristallstrukturen
  11. Synthesis And Spectroscopic Studies Of New Bis(N-1-hydroxy-2,6-Di-Fe/Tf-Butylphenyl- Salicylideneaminato)Cobalt(Ii) Complexes And Their Oxidation With PbO2
  12. Guaianolide Sesquiterpene Lactones From Cichorium Intybus (Asteraceae) [1]
  13. Chloroisosulochrin, Chloroisosulochrin Dehydrate, And Pestheic Acid, Plant Growth Regulators, Produced By Pestalotiopsis Theae
  14. Synthesis And Antiviral Activity Of 2'-Deoxy-2'-Fluoro-L-Arabinofuranosyl 1,2,3-Triazole Derivatives
  15. Synthesis Of New Cyclopentadienyl-, Indenyl- And Fluorenylphosphanes By The Reaction Of Carbanions Of The Cyclopentadienyl Type With Alkyl(Aryl)Chloro-N,N-Dialkylaminophosphanes
  16. Three Reagents In One: Ammonium Permanganate In The Oxidation Of Benzyl Alcohol
  17. 4′, x-Seco And 4′,x-4′,5′-Diseco C-Nucleosides From 2-Hydrazino-(3H)- Thieno [2,3-D] Pyrimidin-4-Ones
  18. Phytol And Glycerol Derivatives From The Marine Green Alga Codium Iyengarii Of The Karachi Coast (Arabian Sea)
  19. Dihydroquinol And Quinol Derivatives From Ajuga Parviflora
https://doi.org/10.1515/znb-2001-0807
Keywords for this article
Rhodium; Polypyridyl

Articles in the same Issue

  1. Multianvil High-Pressure Synthesis And Crystal Structure Of β-YbBO3
  2. 2.3-Dihydro-2-Methoxyethylimino-L,3-Dimethylimidazol - Ein Neuer Hemilabil Koordinierender Chelatligand [1]
  3. Soluble Pyridine Complexes Of The Ternary Gallium(III) Chalcogenide Halides (GaEX)3, With E = S, Se And X = Cl, Br
  4. Antiferromagnetic Coupling In A (μ-Hydroxo)(μ-Pyrazolato)Dicopper(II) Complex. Synthesis, Crystal Structure, Magnetic Properties, And Theoretical Studies
  5. Synthesis Of A Large Water-Soluble Gold Cluster (Au32.36) And Its Properties As A Potential Label In Electron Microscopy
  6. Koordination Des Anions Von 2,4-Dicyanoglutaconsäurediethylester An Tripodeisen(Ii)-Einheiten. Die Entstehung Helikaler Strukturen
  7. Structural Characterization Of Rh(Iii) Complexes Containing The Polypyridyl Ligands And Some Properties Of Their Derivatives
  8. Preparation And Crystal Structures Of (Hg3 )(PO4 )Cl, (Hg3)(AsO4)Cl And (Hg3)(AsO4)Br - Mercury Compounds With The Triangular Hg34+ Cluster
  9. Synthese Und Kristallstrukturen Von Chlorometallaten [M = V(III), Mo(V)]
  10. Polysulfonylamine, CXL [1]. N-Cycloalkyldimesylamine C„H2n-1/N(SO2CH3)2: Synthesen (n = 3 -6 ), Festkörper-Molekülstrukturen (n = 4 -6 ) Und Rolle Schwacher Wasserstoffbrücken C-H···O In Den Kristallstrukturen
  11. Synthesis And Spectroscopic Studies Of New Bis(N-1-hydroxy-2,6-Di-Fe/Tf-Butylphenyl- Salicylideneaminato)Cobalt(Ii) Complexes And Their Oxidation With PbO2
  12. Guaianolide Sesquiterpene Lactones From Cichorium Intybus (Asteraceae) [1]
  13. Chloroisosulochrin, Chloroisosulochrin Dehydrate, And Pestheic Acid, Plant Growth Regulators, Produced By Pestalotiopsis Theae
  14. Synthesis And Antiviral Activity Of 2'-Deoxy-2'-Fluoro-L-Arabinofuranosyl 1,2,3-Triazole Derivatives
  15. Synthesis Of New Cyclopentadienyl-, Indenyl- And Fluorenylphosphanes By The Reaction Of Carbanions Of The Cyclopentadienyl Type With Alkyl(Aryl)Chloro-N,N-Dialkylaminophosphanes
  16. Three Reagents In One: Ammonium Permanganate In The Oxidation Of Benzyl Alcohol
  17. 4′, x-Seco And 4′,x-4′,5′-Diseco C-Nucleosides From 2-Hydrazino-(3H)- Thieno [2,3-D] Pyrimidin-4-Ones
  18. Phytol And Glycerol Derivatives From The Marine Green Alga Codium Iyengarii Of The Karachi Coast (Arabian Sea)
  19. Dihydroquinol And Quinol Derivatives From Ajuga Parviflora
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