Article
Licensed
Unlicensed
Requires Authentication
Multianvil High-Pressure Synthesis And Crystal Structure Of β-YbBO3
-
Hubert Huppertz
Published/Copyright:
June 2, 2014
β-Ytterbium borate (β-YbBO3) was synthesized under high-pressure in a Walker-type multianvil apparatus at 2.2 GPa and 1400 °C. The title-compound crystallizes in the trigonal calcite structure, space group R3̄̄c. Single crystal X-ray data yielded a = 492.1(2), c = 1630.5(9) pm, wR2 = 0.0344 for 165 F2 values and 11 variable parameters. Within the trigonal planar BO3 groups the B-O distance is 137.8(4) pm. The ytterbium atoms have a slightly distorted octahedral oxygen coordination (Yb-O: 224.4(2) pm)
Received: 2001-4-5
Published Online: 2014-6-2
Published in Print: 2001-8-1
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung
You are currently not able to access this content.
You are currently not able to access this content.
Articles in the same Issue
- Multianvil High-Pressure Synthesis And Crystal Structure Of β-YbBO3
- 2.3-Dihydro-2-Methoxyethylimino-L,3-Dimethylimidazol - Ein Neuer Hemilabil Koordinierender Chelatligand [1]
- Soluble Pyridine Complexes Of The Ternary Gallium(III) Chalcogenide Halides (GaEX)3, With E = S, Se And X = Cl, Br
- Antiferromagnetic Coupling In A (μ-Hydroxo)(μ-Pyrazolato)Dicopper(II) Complex. Synthesis, Crystal Structure, Magnetic Properties, And Theoretical Studies
- Synthesis Of A Large Water-Soluble Gold Cluster (Au32.36) And Its Properties As A Potential Label In Electron Microscopy
- Koordination Des Anions Von 2,4-Dicyanoglutaconsäurediethylester An Tripodeisen(Ii)-Einheiten. Die Entstehung Helikaler Strukturen
- Structural Characterization Of Rh(Iii) Complexes Containing The Polypyridyl Ligands And Some Properties Of Their Derivatives
- Preparation And Crystal Structures Of (Hg3 )(PO4 )Cl, (Hg3)(AsO4)Cl And (Hg3)(AsO4)Br - Mercury Compounds With The Triangular Hg34+ Cluster
- Synthese Und Kristallstrukturen Von Chlorometallaten [M = V(III), Mo(V)]
- Polysulfonylamine, CXL [1]. N-Cycloalkyldimesylamine C„H2n-1/N(SO2CH3)2: Synthesen (n = 3 -6 ), Festkörper-Molekülstrukturen (n = 4 -6 ) Und Rolle Schwacher Wasserstoffbrücken C-H···O In Den Kristallstrukturen
- Synthesis And Spectroscopic Studies Of New Bis(N-1-hydroxy-2,6-Di-Fe/Tf-Butylphenyl- Salicylideneaminato)Cobalt(Ii) Complexes And Their Oxidation With PbO2
- Guaianolide Sesquiterpene Lactones From Cichorium Intybus (Asteraceae) [1]
- Chloroisosulochrin, Chloroisosulochrin Dehydrate, And Pestheic Acid, Plant Growth Regulators, Produced By Pestalotiopsis Theae
- Synthesis And Antiviral Activity Of 2'-Deoxy-2'-Fluoro-L-Arabinofuranosyl 1,2,3-Triazole Derivatives
- Synthesis Of New Cyclopentadienyl-, Indenyl- And Fluorenylphosphanes By The Reaction Of Carbanions Of The Cyclopentadienyl Type With Alkyl(Aryl)Chloro-N,N-Dialkylaminophosphanes
- Three Reagents In One: Ammonium Permanganate In The Oxidation Of Benzyl Alcohol
- 4′, x-Seco And 4′,x-4′,5′-Diseco C-Nucleosides From 2-Hydrazino-(3H)- Thieno [2,3-D] Pyrimidin-4-Ones
- Phytol And Glycerol Derivatives From The Marine Green Alga Codium Iyengarii Of The Karachi Coast (Arabian Sea)
- Dihydroquinol And Quinol Derivatives From Ajuga Parviflora
Articles in the same Issue
- Multianvil High-Pressure Synthesis And Crystal Structure Of β-YbBO3
- 2.3-Dihydro-2-Methoxyethylimino-L,3-Dimethylimidazol - Ein Neuer Hemilabil Koordinierender Chelatligand [1]
- Soluble Pyridine Complexes Of The Ternary Gallium(III) Chalcogenide Halides (GaEX)3, With E = S, Se And X = Cl, Br
- Antiferromagnetic Coupling In A (μ-Hydroxo)(μ-Pyrazolato)Dicopper(II) Complex. Synthesis, Crystal Structure, Magnetic Properties, And Theoretical Studies
- Synthesis Of A Large Water-Soluble Gold Cluster (Au32.36) And Its Properties As A Potential Label In Electron Microscopy
- Koordination Des Anions Von 2,4-Dicyanoglutaconsäurediethylester An Tripodeisen(Ii)-Einheiten. Die Entstehung Helikaler Strukturen
- Structural Characterization Of Rh(Iii) Complexes Containing The Polypyridyl Ligands And Some Properties Of Their Derivatives
- Preparation And Crystal Structures Of (Hg3 )(PO4 )Cl, (Hg3)(AsO4)Cl And (Hg3)(AsO4)Br - Mercury Compounds With The Triangular Hg34+ Cluster
- Synthese Und Kristallstrukturen Von Chlorometallaten [M = V(III), Mo(V)]
- Polysulfonylamine, CXL [1]. N-Cycloalkyldimesylamine C„H2n-1/N(SO2CH3)2: Synthesen (n = 3 -6 ), Festkörper-Molekülstrukturen (n = 4 -6 ) Und Rolle Schwacher Wasserstoffbrücken C-H···O In Den Kristallstrukturen
- Synthesis And Spectroscopic Studies Of New Bis(N-1-hydroxy-2,6-Di-Fe/Tf-Butylphenyl- Salicylideneaminato)Cobalt(Ii) Complexes And Their Oxidation With PbO2
- Guaianolide Sesquiterpene Lactones From Cichorium Intybus (Asteraceae) [1]
- Chloroisosulochrin, Chloroisosulochrin Dehydrate, And Pestheic Acid, Plant Growth Regulators, Produced By Pestalotiopsis Theae
- Synthesis And Antiviral Activity Of 2'-Deoxy-2'-Fluoro-L-Arabinofuranosyl 1,2,3-Triazole Derivatives
- Synthesis Of New Cyclopentadienyl-, Indenyl- And Fluorenylphosphanes By The Reaction Of Carbanions Of The Cyclopentadienyl Type With Alkyl(Aryl)Chloro-N,N-Dialkylaminophosphanes
- Three Reagents In One: Ammonium Permanganate In The Oxidation Of Benzyl Alcohol
- 4′, x-Seco And 4′,x-4′,5′-Diseco C-Nucleosides From 2-Hydrazino-(3H)- Thieno [2,3-D] Pyrimidin-4-Ones
- Phytol And Glycerol Derivatives From The Marine Green Alga Codium Iyengarii Of The Karachi Coast (Arabian Sea)
- Dihydroquinol And Quinol Derivatives From Ajuga Parviflora
