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2.3-Dihydro-2-Methoxyethylimino-L,3-Dimethylimidazol - Ein Neuer Hemilabil Koordinierender Chelatligand [1]
-
Norbert Kuhn
,
Martin Grathwohl
Veröffentlicht/Copyright:
2. Juni 2014
The bifunctional 2,3-dihydro-2-methoxyethylimino-l,3-dimethylimidazole (C8H 15N3O , 10) is obtained from the reaction of methoxyethyl tosylate (7) and 2,3-dihydro-2-imino-1,3- dimethylimidazole (8) followed by deprotonation in good yield. 10 reacts with {(COD)RhCl}2 (COD = 1,5-cyclooctadiene) to give the imine complex (C8H 15N3O)Rh(COD)Cl (11), which is converted into the chelate complex [(C8H15N3O)Rh(COD)]BF4 (12) on treatment with AgBF4. The imine complex (C8H15N3O) 2PdCl2 (13) is formed through the reaction of 10 with (PhCN)2PdCl2. The X-ray structures of 11, 13 and 2 C8H15N3O · H2PdCl4 (15) are reported
Received: 2001-3-28
Published Online: 2014-6-2
Published in Print: 2001-8-1
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Artikel in diesem Heft
- Multianvil High-Pressure Synthesis And Crystal Structure Of β-YbBO3
- 2.3-Dihydro-2-Methoxyethylimino-L,3-Dimethylimidazol - Ein Neuer Hemilabil Koordinierender Chelatligand [1]
- Soluble Pyridine Complexes Of The Ternary Gallium(III) Chalcogenide Halides (GaEX)3, With E = S, Se And X = Cl, Br
- Antiferromagnetic Coupling In A (μ-Hydroxo)(μ-Pyrazolato)Dicopper(II) Complex. Synthesis, Crystal Structure, Magnetic Properties, And Theoretical Studies
- Synthesis Of A Large Water-Soluble Gold Cluster (Au32.36) And Its Properties As A Potential Label In Electron Microscopy
- Koordination Des Anions Von 2,4-Dicyanoglutaconsäurediethylester An Tripodeisen(Ii)-Einheiten. Die Entstehung Helikaler Strukturen
- Structural Characterization Of Rh(Iii) Complexes Containing The Polypyridyl Ligands And Some Properties Of Their Derivatives
- Preparation And Crystal Structures Of (Hg3 )(PO4 )Cl, (Hg3)(AsO4)Cl And (Hg3)(AsO4)Br - Mercury Compounds With The Triangular Hg34+ Cluster
- Synthese Und Kristallstrukturen Von Chlorometallaten [M = V(III), Mo(V)]
- Polysulfonylamine, CXL [1]. N-Cycloalkyldimesylamine C„H2n-1/N(SO2CH3)2: Synthesen (n = 3 -6 ), Festkörper-Molekülstrukturen (n = 4 -6 ) Und Rolle Schwacher Wasserstoffbrücken C-H···O In Den Kristallstrukturen
- Synthesis And Spectroscopic Studies Of New Bis(N-1-hydroxy-2,6-Di-Fe/Tf-Butylphenyl- Salicylideneaminato)Cobalt(Ii) Complexes And Their Oxidation With PbO2
- Guaianolide Sesquiterpene Lactones From Cichorium Intybus (Asteraceae) [1]
- Chloroisosulochrin, Chloroisosulochrin Dehydrate, And Pestheic Acid, Plant Growth Regulators, Produced By Pestalotiopsis Theae
- Synthesis And Antiviral Activity Of 2'-Deoxy-2'-Fluoro-L-Arabinofuranosyl 1,2,3-Triazole Derivatives
- Synthesis Of New Cyclopentadienyl-, Indenyl- And Fluorenylphosphanes By The Reaction Of Carbanions Of The Cyclopentadienyl Type With Alkyl(Aryl)Chloro-N,N-Dialkylaminophosphanes
- Three Reagents In One: Ammonium Permanganate In The Oxidation Of Benzyl Alcohol
- 4′, x-Seco And 4′,x-4′,5′-Diseco C-Nucleosides From 2-Hydrazino-(3H)- Thieno [2,3-D] Pyrimidin-4-Ones
- Phytol And Glycerol Derivatives From The Marine Green Alga Codium Iyengarii Of The Karachi Coast (Arabian Sea)
- Dihydroquinol And Quinol Derivatives From Ajuga Parviflora
