Startseite Die Kristallstrukturen von Ph3AsCI2 und β-Ph3AsBr2 / Crystal Structures of Ph3AsCI2 and β-Ph3AsBr2
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Die Kristallstrukturen von Ph3AsCI2 und β-Ph3AsBr2 / Crystal Structures of Ph3AsCI2 and β-Ph3AsBr2

  • Bernhard Neumüller , Soheila Chitsaz und Kurt Dehnicke
Veröffentlicht/Copyright: 2. Juni 2014
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Zeitschrift für Naturforschung B
Aus der Zeitschrift Zeitschrift für Naturforschung B Band 54 Heft 12

Colourless single crystals of Ph3AsCl2 as well as of β-Ph3AsBr2 were obtained from acetonitrile solutions and were suitable for X-ray structure determinations. Ph3AsCl2: Space group P212121, Z = 4, lattice dimensions at -90 °C: a = 1247.9(2), b = 1267.5(1), c = 1033.4(1) pm, R x = 0.0484.

β-Ph3AsBr2: Space group P1̄ , Z = 4, lattice dimensions at -80 °C: a = 949.1(1), b = 1189.7(1), c = 1693.7(2) pm, a = 98.32(1)°, ß = 103.64(1)°, γ = 109.44(1)°, R x - 0.0628. The structures consist of Ph3AsX2 molecules (X = Cl, Br) with trigonalbipyramidal coordination of the arsenic atom with the halogen atoms in the axial positions.

Keywords : Arsenic; Triphenylarsenic Dichloride; Triphenylarsenic Dibromide; Crystal Structure
Received: 1999-8-1
Published Online: 2014-6-2
Published in Print: 1999-12-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Artikel in diesem Heft

  1. Preparation and Crystal Structure of the Calcium Rhenate(VI, VII) Ca5Re3O15-x
  2. The Silver(I) Mercury(II) Oxide Nitrate with the Empirical Formula AgHg2NO5
  3. A Simple and Convenient Route to Arylxenon(II) Tetrafluoroborates
  4. New Chalcogenogermanates with Adamantane Type Complex Anions: Preparation and Crystal Structures of K4Ge4S10; Rb4Ge4S10, Rb4Ge4Se10, and Cs4Ge4Se10
  5. Neue Chalkogenometallate mit binuklearen Anionen, I: Darstellung und Kristallstruktur von Rb6Sn2S7 / New Chalcogenometallates with Binuclear Anions, I: Preparation and Crystal Structure of Rb6Sn2S7
  6. Three-dimensional Copper(I) Halide Based Coordination Networks with Asymmetrically Substituted Bridging N-Donor Ligands
  7. Equilibrium and Structural Study of Chloro Complexes of Iron(III) Ion in Acidic Aqueous Solution by Means of X-Ray Absorption Spectroscopy
  8. (CH3NH3)2Sb2S4, a New Thioantimonate(III) with Building Groups Stabilized by Hydrogen Bonds
  9. The Molecular and Electronic Structure of Tris(dimethylarsino)amine (Me2As)3N
  10. Wasserlösliche Phosohane, XIV. Hydrophile Derivate des Triphenylphosphans mit NH2-, COOH- und P(O)(OR)2-funktionalisierten Seitenketten / Water Soluble Phosphanes, XIV. Hydrophilic Derivatives of Triphenylphosphane with NH2, COOH and P (O)(OR)2 Functionalized Side Chains
  11. Aminocyclophosphazene Derivatives of Tungsten Carbonyl
  12. Darstellung von phosphorylierten Glucosiden durch Umsetzung am Glucosegerüst sowie am Aglycon / Synthesis of Phosphorylated Glucosides through Reaction at the Glucose Framework and at the Aglycon
  13. Schiff Bases of Methanesulfonylhydrazine. Synthesis, Spectroscopic Characterization, Conformational Analysis, and Biological Activity
  14. Zirconium Reagents for Organometallic Synthesis. Crystal Structures of ZrCl4 ·2Et2O and (Et2N)ZrCl3·Et2O
  15. Nitriles in Heterocyclic Organic Synthesis: Synthesis of Pyrano[2,3-h]coumarines, Pyrano[3,2-c]coumarines, and their Derivatives
  16. Redox Properties of 1,2-Dihydro[60]fullerene Derivatives with Electron-Withdrawing Substituents
  17. Chinazolinderivate durch Cyclodehydrierung von N-(2-substituierten Aryl)-Piperidinen / Quinazoline Derivatives by Cyclodehydrogenation of N-(2-Substituted Aryl)-Piperidines
  18. Reactions of Cyanothioacetamide Derivatives with 2-Hydrazinothiazol-4(5H)-one: Synthesis, Cyclization and Biological Evaluation of Several New Annelated Pyran, Thiazole, 1,2,4-Triazole and 1,2,4-Triazine Derivatives
  19. Structure of the 2-Pyrrolidinone Monohydrate
  20. X-Ray Structure Analysis of Substituted 5-(2,3-Dihydro-7-benzofuryl)- 1-methylpyrazolo[4,3-d]pyrimidin-7-one (Biagra)
  21. Coordination of the Hetero(N,S)- bidentate Ligand 1-Methyl-2- (methylthiomethyl)-1H-benzimidazole to [(Ph3P)Au)]+ Exclusively through the Imine Nitrogen Donor
  22. Die Kristallstruktur von [YbCl2(THF)5]+[WOCl4(THF)]- / Crystal Structure of [YbCl2(THF)5]+[WOCl4(THF)]-
  23. Die Kristallstrukturen von Ph3AsCI2 und β-Ph3AsBr2 / Crystal Structures of Ph3AsCI2 and β-Ph3AsBr2
  24. Neuuntersuchung der Kristallstruktur von α-ICl / Novel Investigation on the Crystal Structure of α-ICl
  25. A Facile Synthesis of Quino[2,3-a]carbazoles
  26. Subject Index
  27. Authors Index / Autorenverzeichnis
https://doi.org/10.1515/znb-1999-1223
Schlagwörter für diesen Artikel
Arsenic; Triphenylarsenic Dichloride; Triphenylarsenic Dibromide; Crystal Structure

Artikel in diesem Heft

  1. Preparation and Crystal Structure of the Calcium Rhenate(VI, VII) Ca5Re3O15-x
  2. The Silver(I) Mercury(II) Oxide Nitrate with the Empirical Formula AgHg2NO5
  3. A Simple and Convenient Route to Arylxenon(II) Tetrafluoroborates
  4. New Chalcogenogermanates with Adamantane Type Complex Anions: Preparation and Crystal Structures of K4Ge4S10; Rb4Ge4S10, Rb4Ge4Se10, and Cs4Ge4Se10
  5. Neue Chalkogenometallate mit binuklearen Anionen, I: Darstellung und Kristallstruktur von Rb6Sn2S7 / New Chalcogenometallates with Binuclear Anions, I: Preparation and Crystal Structure of Rb6Sn2S7
  6. Three-dimensional Copper(I) Halide Based Coordination Networks with Asymmetrically Substituted Bridging N-Donor Ligands
  7. Equilibrium and Structural Study of Chloro Complexes of Iron(III) Ion in Acidic Aqueous Solution by Means of X-Ray Absorption Spectroscopy
  8. (CH3NH3)2Sb2S4, a New Thioantimonate(III) with Building Groups Stabilized by Hydrogen Bonds
  9. The Molecular and Electronic Structure of Tris(dimethylarsino)amine (Me2As)3N
  10. Wasserlösliche Phosohane, XIV. Hydrophile Derivate des Triphenylphosphans mit NH2-, COOH- und P(O)(OR)2-funktionalisierten Seitenketten / Water Soluble Phosphanes, XIV. Hydrophilic Derivatives of Triphenylphosphane with NH2, COOH and P (O)(OR)2 Functionalized Side Chains
  11. Aminocyclophosphazene Derivatives of Tungsten Carbonyl
  12. Darstellung von phosphorylierten Glucosiden durch Umsetzung am Glucosegerüst sowie am Aglycon / Synthesis of Phosphorylated Glucosides through Reaction at the Glucose Framework and at the Aglycon
  13. Schiff Bases of Methanesulfonylhydrazine. Synthesis, Spectroscopic Characterization, Conformational Analysis, and Biological Activity
  14. Zirconium Reagents for Organometallic Synthesis. Crystal Structures of ZrCl4 ·2Et2O and (Et2N)ZrCl3·Et2O
  15. Nitriles in Heterocyclic Organic Synthesis: Synthesis of Pyrano[2,3-h]coumarines, Pyrano[3,2-c]coumarines, and their Derivatives
  16. Redox Properties of 1,2-Dihydro[60]fullerene Derivatives with Electron-Withdrawing Substituents
  17. Chinazolinderivate durch Cyclodehydrierung von N-(2-substituierten Aryl)-Piperidinen / Quinazoline Derivatives by Cyclodehydrogenation of N-(2-Substituted Aryl)-Piperidines
  18. Reactions of Cyanothioacetamide Derivatives with 2-Hydrazinothiazol-4(5H)-one: Synthesis, Cyclization and Biological Evaluation of Several New Annelated Pyran, Thiazole, 1,2,4-Triazole and 1,2,4-Triazine Derivatives
  19. Structure of the 2-Pyrrolidinone Monohydrate
  20. X-Ray Structure Analysis of Substituted 5-(2,3-Dihydro-7-benzofuryl)- 1-methylpyrazolo[4,3-d]pyrimidin-7-one (Biagra)
  21. Coordination of the Hetero(N,S)- bidentate Ligand 1-Methyl-2- (methylthiomethyl)-1H-benzimidazole to [(Ph3P)Au)]+ Exclusively through the Imine Nitrogen Donor
  22. Die Kristallstruktur von [YbCl2(THF)5]+[WOCl4(THF)]- / Crystal Structure of [YbCl2(THF)5]+[WOCl4(THF)]-
  23. Die Kristallstrukturen von Ph3AsCI2 und β-Ph3AsBr2 / Crystal Structures of Ph3AsCI2 and β-Ph3AsBr2
  24. Neuuntersuchung der Kristallstruktur von α-ICl / Novel Investigation on the Crystal Structure of α-ICl
  25. A Facile Synthesis of Quino[2,3-a]carbazoles
  26. Subject Index
  27. Authors Index / Autorenverzeichnis
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