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Preparation and Crystal Structure of the Calcium Rhenate(VI, VII) Ca5Re3O15-x

  • Wolfgang Jeitschko , Horst A. Mons and Ute Ch. Rodewald
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 54 Issue 12

The title compound was prepared by reaction of elemental calcium with the calcium metaperrhenate Ca(ReO4)2. Its crystal structure was determined from single-crystal X-ray data: Amm2, a = 560.31 (5)pm, b = 1572.4( 1)pm, c = 719.91 (6)pm ,Z = 2 ,R = 0.033 for 930 structure factors and 46 variable parameters. The calcium atoms occupy three atomic sites, all with seven oxygen neighbors. Of the two different rhenium atoms one has square-pyramidal oxygen coordination with an average oxidation number +6.25. The other rhenium site (oxidation number +7) was refined as a split position with trigonal-bipyramidal (75%) and tetrahedral oxygen coordination (25%). One oxygen site remains unoccupied, whenever the tetrahedral rhenium site is occupied, resulting in the composition Ca5Re3O14.75. A test for superconductivity of this black compound down to 1.5 K was negative.

Keywords : Crystal Structure; Mixed Valence; Rhenates; Perrhenates
Received: 1999-8-16
Published Online: 2014-6-2
Published in Print: 1999-12-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Preparation and Crystal Structure of the Calcium Rhenate(VI, VII) Ca5Re3O15-x
  2. The Silver(I) Mercury(II) Oxide Nitrate with the Empirical Formula AgHg2NO5
  3. A Simple and Convenient Route to Arylxenon(II) Tetrafluoroborates
  4. New Chalcogenogermanates with Adamantane Type Complex Anions: Preparation and Crystal Structures of K4Ge4S10; Rb4Ge4S10, Rb4Ge4Se10, and Cs4Ge4Se10
  5. Neue Chalkogenometallate mit binuklearen Anionen, I: Darstellung und Kristallstruktur von Rb6Sn2S7 / New Chalcogenometallates with Binuclear Anions, I: Preparation and Crystal Structure of Rb6Sn2S7
  6. Three-dimensional Copper(I) Halide Based Coordination Networks with Asymmetrically Substituted Bridging N-Donor Ligands
  7. Equilibrium and Structural Study of Chloro Complexes of Iron(III) Ion in Acidic Aqueous Solution by Means of X-Ray Absorption Spectroscopy
  8. (CH3NH3)2Sb2S4, a New Thioantimonate(III) with Building Groups Stabilized by Hydrogen Bonds
  9. The Molecular and Electronic Structure of Tris(dimethylarsino)amine (Me2As)3N
  10. Wasserlösliche Phosohane, XIV. Hydrophile Derivate des Triphenylphosphans mit NH2-, COOH- und P(O)(OR)2-funktionalisierten Seitenketten / Water Soluble Phosphanes, XIV. Hydrophilic Derivatives of Triphenylphosphane with NH2, COOH and P (O)(OR)2 Functionalized Side Chains
  11. Aminocyclophosphazene Derivatives of Tungsten Carbonyl
  12. Darstellung von phosphorylierten Glucosiden durch Umsetzung am Glucosegerüst sowie am Aglycon / Synthesis of Phosphorylated Glucosides through Reaction at the Glucose Framework and at the Aglycon
  13. Schiff Bases of Methanesulfonylhydrazine. Synthesis, Spectroscopic Characterization, Conformational Analysis, and Biological Activity
  14. Zirconium Reagents for Organometallic Synthesis. Crystal Structures of ZrCl4 ·2Et2O and (Et2N)ZrCl3·Et2O
  15. Nitriles in Heterocyclic Organic Synthesis: Synthesis of Pyrano[2,3-h]coumarines, Pyrano[3,2-c]coumarines, and their Derivatives
  16. Redox Properties of 1,2-Dihydro[60]fullerene Derivatives with Electron-Withdrawing Substituents
  17. Chinazolinderivate durch Cyclodehydrierung von N-(2-substituierten Aryl)-Piperidinen / Quinazoline Derivatives by Cyclodehydrogenation of N-(2-Substituted Aryl)-Piperidines
  18. Reactions of Cyanothioacetamide Derivatives with 2-Hydrazinothiazol-4(5H)-one: Synthesis, Cyclization and Biological Evaluation of Several New Annelated Pyran, Thiazole, 1,2,4-Triazole and 1,2,4-Triazine Derivatives
  19. Structure of the 2-Pyrrolidinone Monohydrate
  20. X-Ray Structure Analysis of Substituted 5-(2,3-Dihydro-7-benzofuryl)- 1-methylpyrazolo[4,3-d]pyrimidin-7-one (Biagra)
  21. Coordination of the Hetero(N,S)- bidentate Ligand 1-Methyl-2- (methylthiomethyl)-1H-benzimidazole to [(Ph3P)Au)]+ Exclusively through the Imine Nitrogen Donor
  22. Die Kristallstruktur von [YbCl2(THF)5]+[WOCl4(THF)]- / Crystal Structure of [YbCl2(THF)5]+[WOCl4(THF)]-
  23. Die Kristallstrukturen von Ph3AsCI2 und β-Ph3AsBr2 / Crystal Structures of Ph3AsCI2 and β-Ph3AsBr2
  24. Neuuntersuchung der Kristallstruktur von α-ICl / Novel Investigation on the Crystal Structure of α-ICl
  25. A Facile Synthesis of Quino[2,3-a]carbazoles
  26. Subject Index
  27. Authors Index / Autorenverzeichnis
https://doi.org/10.1515/znb-1999-1201
Keywords for this article
Crystal Structure; Mixed Valence; Rhenates; Perrhenates

Articles in the same Issue

  1. Preparation and Crystal Structure of the Calcium Rhenate(VI, VII) Ca5Re3O15-x
  2. The Silver(I) Mercury(II) Oxide Nitrate with the Empirical Formula AgHg2NO5
  3. A Simple and Convenient Route to Arylxenon(II) Tetrafluoroborates
  4. New Chalcogenogermanates with Adamantane Type Complex Anions: Preparation and Crystal Structures of K4Ge4S10; Rb4Ge4S10, Rb4Ge4Se10, and Cs4Ge4Se10
  5. Neue Chalkogenometallate mit binuklearen Anionen, I: Darstellung und Kristallstruktur von Rb6Sn2S7 / New Chalcogenometallates with Binuclear Anions, I: Preparation and Crystal Structure of Rb6Sn2S7
  6. Three-dimensional Copper(I) Halide Based Coordination Networks with Asymmetrically Substituted Bridging N-Donor Ligands
  7. Equilibrium and Structural Study of Chloro Complexes of Iron(III) Ion in Acidic Aqueous Solution by Means of X-Ray Absorption Spectroscopy
  8. (CH3NH3)2Sb2S4, a New Thioantimonate(III) with Building Groups Stabilized by Hydrogen Bonds
  9. The Molecular and Electronic Structure of Tris(dimethylarsino)amine (Me2As)3N
  10. Wasserlösliche Phosohane, XIV. Hydrophile Derivate des Triphenylphosphans mit NH2-, COOH- und P(O)(OR)2-funktionalisierten Seitenketten / Water Soluble Phosphanes, XIV. Hydrophilic Derivatives of Triphenylphosphane with NH2, COOH and P (O)(OR)2 Functionalized Side Chains
  11. Aminocyclophosphazene Derivatives of Tungsten Carbonyl
  12. Darstellung von phosphorylierten Glucosiden durch Umsetzung am Glucosegerüst sowie am Aglycon / Synthesis of Phosphorylated Glucosides through Reaction at the Glucose Framework and at the Aglycon
  13. Schiff Bases of Methanesulfonylhydrazine. Synthesis, Spectroscopic Characterization, Conformational Analysis, and Biological Activity
  14. Zirconium Reagents for Organometallic Synthesis. Crystal Structures of ZrCl4 ·2Et2O and (Et2N)ZrCl3·Et2O
  15. Nitriles in Heterocyclic Organic Synthesis: Synthesis of Pyrano[2,3-h]coumarines, Pyrano[3,2-c]coumarines, and their Derivatives
  16. Redox Properties of 1,2-Dihydro[60]fullerene Derivatives with Electron-Withdrawing Substituents
  17. Chinazolinderivate durch Cyclodehydrierung von N-(2-substituierten Aryl)-Piperidinen / Quinazoline Derivatives by Cyclodehydrogenation of N-(2-Substituted Aryl)-Piperidines
  18. Reactions of Cyanothioacetamide Derivatives with 2-Hydrazinothiazol-4(5H)-one: Synthesis, Cyclization and Biological Evaluation of Several New Annelated Pyran, Thiazole, 1,2,4-Triazole and 1,2,4-Triazine Derivatives
  19. Structure of the 2-Pyrrolidinone Monohydrate
  20. X-Ray Structure Analysis of Substituted 5-(2,3-Dihydro-7-benzofuryl)- 1-methylpyrazolo[4,3-d]pyrimidin-7-one (Biagra)
  21. Coordination of the Hetero(N,S)- bidentate Ligand 1-Methyl-2- (methylthiomethyl)-1H-benzimidazole to [(Ph3P)Au)]+ Exclusively through the Imine Nitrogen Donor
  22. Die Kristallstruktur von [YbCl2(THF)5]+[WOCl4(THF)]- / Crystal Structure of [YbCl2(THF)5]+[WOCl4(THF)]-
  23. Die Kristallstrukturen von Ph3AsCI2 und β-Ph3AsBr2 / Crystal Structures of Ph3AsCI2 and β-Ph3AsBr2
  24. Neuuntersuchung der Kristallstruktur von α-ICl / Novel Investigation on the Crystal Structure of α-ICl
  25. A Facile Synthesis of Quino[2,3-a]carbazoles
  26. Subject Index
  27. Authors Index / Autorenverzeichnis
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