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Reactivity and Structure of Diferrocenylamine and N,N - Diferrocenylcarbamoylchloride

  • Benno Bildstein EMAIL logo , Michael Malaun , Holger Kopacka and Klaus Wurst
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 54 Issue 11

The reactivity of diferrocenylamine has been investigated aiming at the preparation of novel diferrocenylamino compounds, including nitrenium salts, amino radicals, transition metal amides, carbamato ligands, and others. However, diferrocenylamine is unexpectedly difficult to derivatize; only simple metalation by butyl lithium, alkylation by iodomethane, and chloroformylation by phosgene were possible. X-ray crystal structures are reported for the starting diferrocenylamine, and for the derivatives diferrocenylmethylamine and N,N diferrocenylcarbamoylchloride.

Keywords: Ferrocene; Diferrocenylamine; Carbamoylchloride; X -Ray Data
Received: 1999-6-29
Published Online: 2014-6-2
Published in Print: 1999-11-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

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  1. Darstellung und Kristallstruktur von Lithiumozonid-Ammoniakat (1/5) LiO3 · 5 NH3/Synthesis and Crystal Structure of Lithiumozonide-Ammonia (1/5) LiO3 · 5 NH3
  2. Carbene Adducts of Dimethylcadmium
  3. Carbacylamidophosphates: Structure and Properties of Bis(N,N′,-morpholido)-[(N″-morpholido)-carboxamido] phosphate
  4. Metallkomplexe mit biologisch wichtigen Liganden, CXXIV [1]. NMR-spektroskopische Bestimmung des Enantiomerenverhältnisses von α-Aminosäuren mit Hilfe eines chiralen orthometallierten Palladiumkomplexes/Metal Complexes of Biologically Important Ligands, CXXIV [1]. NMR-Spectroscopic Determination of the Enantiomeric Ratio of α-Amino Acidsby Use of a Chiral Orthometallated Palladium Complex
  5. Synthese und Kristallstruktur neuer 1,1,1,3,3,3-Hexaamino-1λ5,3λ5- diphosphazenium-Salze/ Synthesis and Crystal Structure of Novel 1,1,1,3,3,3-Hexaamino-1λ5,3λ5- diphosphazenium Salts
  6. Synthesis and Structure of 2,2,-Bis(2,2,5-trimethyl-pyrrolidinyl)methane
  7. Darstellung und Charakterisierung von Rubidiumhydrogencyanamid/Synthesis and Characterization of Rubidium Hydrogen Cyanamide
  8. Attempted Synthesis of Divalent Neodymium Derivatives. Crystal Structure of the Nd(III) Complex [{NdCl2 (2 ,4 ,6-t-Bu3C6H2O )(μ-Cl)(THF)}Li(THF)2]2
  9. Über die Struktur von synthetischem Tinsleyit K[Al2(PO4)2 (OH)(H2O)]·H2O/The Structure of Synthetic Tinsleyite K[Al2(PO4)2(OH)(H2O )]·H2O
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  11. N,N′-Bis(trimethylsilyl) benzamidinato-Komplexe von Vanadium(V), Niob(V) und Tantal(V)/ N,N′-Bis(trimethylsilyl)benzamidinato Complexes of Vanadium(V), Niobium(V) and Tantalum(V)
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  15. Polysulfonylamine, CXVII Wasserstoffbrücken in kristallinen Onium-dimesylamiden: Sechs systematisch variierte sek.-Ammonium-dimesylamide mit sechs verschiedenen null-, ein-oder zweidimensionalen Wasserstoffbrückenmustern/ Polysulfonylamines, CXVII Hydrogen Bonding in Crystalline Onium Dimesylamides: Six Systematically Varied sec. - Ammonium Dimesylamides Exhibiting Six Different Zero-, One-, or Two-Dimensional Hydrogen Bonding Patterns
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  18. Reactivity and Structure of Diferrocenylamine and N,N - Diferrocenylcarbamoylchloride
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https://doi.org/10.1515/znb-1999-1118
Keywords for this article
Ferrocene; Diferrocenylamine; Carbamoylchloride; X -Ray Data

Articles in the same Issue

  1. Darstellung und Kristallstruktur von Lithiumozonid-Ammoniakat (1/5) LiO3 · 5 NH3/Synthesis and Crystal Structure of Lithiumozonide-Ammonia (1/5) LiO3 · 5 NH3
  2. Carbene Adducts of Dimethylcadmium
  3. Carbacylamidophosphates: Structure and Properties of Bis(N,N′,-morpholido)-[(N″-morpholido)-carboxamido] phosphate
  4. Metallkomplexe mit biologisch wichtigen Liganden, CXXIV [1]. NMR-spektroskopische Bestimmung des Enantiomerenverhältnisses von α-Aminosäuren mit Hilfe eines chiralen orthometallierten Palladiumkomplexes/Metal Complexes of Biologically Important Ligands, CXXIV [1]. NMR-Spectroscopic Determination of the Enantiomeric Ratio of α-Amino Acidsby Use of a Chiral Orthometallated Palladium Complex
  5. Synthese und Kristallstruktur neuer 1,1,1,3,3,3-Hexaamino-1λ5,3λ5- diphosphazenium-Salze/ Synthesis and Crystal Structure of Novel 1,1,1,3,3,3-Hexaamino-1λ5,3λ5- diphosphazenium Salts
  6. Synthesis and Structure of 2,2,-Bis(2,2,5-trimethyl-pyrrolidinyl)methane
  7. Darstellung und Charakterisierung von Rubidiumhydrogencyanamid/Synthesis and Characterization of Rubidium Hydrogen Cyanamide
  8. Attempted Synthesis of Divalent Neodymium Derivatives. Crystal Structure of the Nd(III) Complex [{NdCl2 (2 ,4 ,6-t-Bu3C6H2O )(μ-Cl)(THF)}Li(THF)2]2
  9. Über die Struktur von synthetischem Tinsleyit K[Al2(PO4)2 (OH)(H2O)]·H2O/The Structure of Synthetic Tinsleyite K[Al2(PO4)2(OH)(H2O )]·H2O
  10. Bis(N-tnmethylsilylamino)titanium Dichlorides Bearing Two Identical or Two Different Amino Groups
  11. N,N′-Bis(trimethylsilyl) benzamidinato-Komplexe von Vanadium(V), Niob(V) und Tantal(V)/ N,N′-Bis(trimethylsilyl)benzamidinato Complexes of Vanadium(V), Niobium(V) and Tantalum(V)
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  13. Thermisches Verhalten von festem LaAlCl6 und chemischer Transport von LaCl3 mit AlCl3/Thermical Behaviour of Solid LaAlCl6 and Chemical Transport of LaCl3 with AlCl3
  14. Bis[(2-diphenyIphosphino)phenyl]phenylphosphine as an Inflexible Tridentate Ligand for Indium Trichloride
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  18. Reactivity and Structure of Diferrocenylamine and N,N - Diferrocenylcarbamoylchloride
  19. Beiträge zur Chemie des Phosphors, 242 Tri-tert-butylcyclotriphosphan-monoxid, (PBut )3O - Bildung und 31P-NMR-spektroskopische Strukturbestimmung/ Contributions to the Chemistry of Phosphorus, 242 Tri-tert-butylcyclotriphosphane Monoxide, (PButO — Formation and Structure Determination by 31P NMR Spectroscopy
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  21. Synthesis and Properties of Biagra . A 5-(2,3-Dihydro-7-benzofuryl) Analog of Viagra®
  22. Notizen: Polysulfonylamine, CXX II Nicht-konventionelle Wasserstoffbrücken in Bis[diphenylphosphino- (diphenylphosphinselenid)methan]- gold(I)-di(m ethansulfonyl)amid/Polysulfonylamines, CXXII. Non-Conventional Hydrogen Bonds in Bis[diphenylphosphino(diphenylphosphinselenide) methane]gold(I) Di(methanesulfonyl)amide
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