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Preparation and Characterization of [C6H5CH2 NH3]2PbI4, [C6H5CH2CH2SC(NH2)2]3 PbI5 and [C10H7CH2NH3]PbI3 Organic-Inorganic Hybrid Compounds

  • G. C. Papavassiliou , G. A. Mousdis , C. P. Raptopoulou and A. Terzis
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 54 Issue 11

The preparation, crystal structures, optical absorption spectra, and photoluminescence spectra of the title compounds are reported. The compounds were prepared in single crystal form. [C6H5CH2NH3]2PbI4 consists of anionic perovskite sheets of corner-sharing Pbl6 octahedra, which alternate with the C6H5CH2NH3+ sheets. [ C6H5CH2CH2SC(NH2)2]3 PbI5 consists of zig-zag chains of anionic corner sharing PbI6 octahedra separated by C6H5CH2CH2SC(NH2)2 cations. [C10H7CH2NH3]Pbl3 consists of twin chains of edge-sharing PbI6 octahedra separated by C10H7CH2NH3 cations. The compounds are thus low-dimensional systems. The excitonic spectra were observed in all cases, even at room temperature, and the possibility of organicinorganic excitonic interactions is discussed.

Keywords: Organic-Inorganic Hybrides; Perovskites; Low-Dimensional Compounds; Excitonic Spectra
Received: 1999-7-7
Published Online: 2014-6-2
Published in Print: 1999-11-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

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https://doi.org/10.1515/znb-1999-1112
Keywords for this article
Organic-Inorganic Hybrides; Perovskites; Low-Dimensional Compounds; Excitonic Spectra

Articles in the same Issue

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  4. Metallkomplexe mit biologisch wichtigen Liganden, CXXIV [1]. NMR-spektroskopische Bestimmung des Enantiomerenverhältnisses von α-Aminosäuren mit Hilfe eines chiralen orthometallierten Palladiumkomplexes/Metal Complexes of Biologically Important Ligands, CXXIV [1]. NMR-Spectroscopic Determination of the Enantiomeric Ratio of α-Amino Acidsby Use of a Chiral Orthometallated Palladium Complex
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  7. Darstellung und Charakterisierung von Rubidiumhydrogencyanamid/Synthesis and Characterization of Rubidium Hydrogen Cyanamide
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