Home Über die Struktur von synthetischem Tinsleyit K[Al2(PO4)2 (OH)(H2O)]·H2O/The Structure of Synthetic Tinsleyite K[Al2(PO4)2(OH)(H2O )]·H2O
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Über die Struktur von synthetischem Tinsleyit K[Al2(PO4)2 (OH)(H2O)]·H2O/The Structure of Synthetic Tinsleyite K[Al2(PO4)2(OH)(H2O )]·H2O

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Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 54 Issue 11

Synthetic tinsleyite K[Al2(PO4)2(OH)(H2O)]·H2O has been obtained by the reaction of gibbsite with a potassium-phosphate solution of pH = 7 at 423 K within five days. A single crystal X-ray structure analysis has shown that synthetic tinsleyite is isotypic with the mineral leucophosphite K[Fe2(PO4 )2(OH)(H2O )]·H2O. Crystal data: monoclinic space group P21/n,a = 949.9(2), b = 950.3(2), c = 953,5(2) pm, β = 103,26(3)°, Z = 4. The structure of tinsleyite consists of tetranuclear A I4O2 units formed by a central pair of edge sharing AlO6 octahedra, to which two additional AlO6 octahedra are attached sharing corners. These units are crosslinked by phosphate ions to a three dimensional framework structure with tunnels along [010], occupied by potassium cations. While one type of water molecules is attached to Al, a second type is fixed in the structure by hydrogen bonds only. As a consequence two steps for thermal loss of water at 341 K and 471 K are observed.

Keywords: Crystal Structure; Phosphate Mineral; Tinsleyite; Leucophosphite
Received: 1999-7-15
Published Online: 2014-6-2
Published in Print: 1999-11-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

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https://doi.org/10.1515/znb-1999-1109
Keywords for this article
Crystal Structure; Phosphate Mineral; Tinsleyite; Leucophosphite

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