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Attempted Synthesis of Divalent Neodymium Derivatives. Crystal Structure of the Nd(III) Complex [{NdCl2 (2 ,4 ,6-t-Bu3C6H2O )(μ-Cl)(THF)}Li(THF)2]2

  • E. N. Kirillov , A. A. Trifonov , S. E. Nefedov EMAIL logo , I. L. Eremenko , F. T. Edelmann and M. N. Bochkarev
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 54 Issue 11

The interaction of NdCl3 with lithium metal in THF in the presence of naphthalene produces a mixture of naphthalene complexes of di- and trivalent neodymium chloride of an aggregate composition [NdCl2(THF)2LiCl]nC10H8 (n = 4- 7). By the reaction of these compounds with 2,4,6-t-Bu3C6H2OH in THF the complex [{NdCl2(2,4,6-t-Bu3C6H2O)(μ-Cl)(THF)}Li(THF)2]2 has been obtained in 70% yield and its X-ray crystal structure determined.

Keywords: Neodymium; Divalent Oxidation State; Synthesis; Structure; Phenoxide
Received: 1999-3-3
Published Online: 2014-6-2
Published in Print: 1999-11-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

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  4. Metallkomplexe mit biologisch wichtigen Liganden, CXXIV [1]. NMR-spektroskopische Bestimmung des Enantiomerenverhältnisses von α-Aminosäuren mit Hilfe eines chiralen orthometallierten Palladiumkomplexes/Metal Complexes of Biologically Important Ligands, CXXIV [1]. NMR-Spectroscopic Determination of the Enantiomeric Ratio of α-Amino Acidsby Use of a Chiral Orthometallated Palladium Complex
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https://doi.org/10.1515/znb-1999-1108
Keywords for this article
Neodymium; Divalent Oxidation State; Synthesis; Structure; Phenoxide

Articles in the same Issue

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