Home Enhancement of thermal conductivity and ultrasonic properties by incorporating CdS nanoparticles to PVA nanofluids
Article
Licensed
Unlicensed Requires Authentication

Enhancement of thermal conductivity and ultrasonic properties by incorporating CdS nanoparticles to PVA nanofluids

  • Shakti Pratap Singh EMAIL logo , Upendra Mani Tripathi EMAIL logo , Alok Kumar Verma , Aashit Kumar Jaiswal , Punit Kumar Dhawan and Raja Ram Yadav
Published/Copyright: May 6, 2021

Abstract

In the present work, semiconducting cadmium sulfide (CdS) nanoparticles have been synthesized by co-precipitation method. X-ray diffraction (XRD), UV–visible (UV/Vis) absorption spectroscopy, and high-resolution transmission electron microscopy (HRTEM) have been used for the characterization of the synthesized nanoparticles. Two-step technique has been used to formulate stable polyvinyl alcohol (PVA)-based CdS nanofluids at room temperature. Thermal conductivities of nanofluids at different temperatures have been measured using Hot Disc Thermal Constants Analyzer. Significant enhancement in thermal conductivity is noted at very low nanoparticle loading. Ultrasonic velocity and ultrasonic attenuation in the prepared nanofluids have been investigated using ultrasonic interferometer and Acoustic Particle Sizer (APS-100), respectively. APS-100 has been also used for the analysis of particle size distribution (PSD) of CdS nanoparticles in the prepared nanofluids. The PSD result of APS-100 is in good agreement with that of HRTEM. The characteristic behavior of CdS nanofluid is illustrated on the basis of its ultrasonic and thermal properties. The thermal conductivity enhancement increases with the temperature and reaches up to 61.6% for 1.0 wt% particle loadings at 80 °C. Our analysis shows that CdS nanofluids have potential application for effective heat transfer management in various cooling industries.


Corresponding authors: Shakti Pratap Singh, Department of Physics, University of Allahabad, Allahabad211002, India; and Department of Physics, Prof. Rajendra Singh (Rajju Bhaiya) Institute of Physical Sciences for Study and Research, V. B. S. Purvanchal University, Jaunpur222003, India, E-mail: ; and Upendra Mani Tripathi, Department of Physics, University of Allahabad, Allahabad211002, India, E-mail:

Acknowledgments

Authors are grateful to Prof. Devraj Singh, Director, Prof. Rajendra Singh (Rajju Bhaiya) Institute of Physical Sciences for Study and Research, V. B. S. Purvanchal University, Jaunpur, India for his kind permission for the TPS-500S and APS-100 measurements. We are also deeply indebted to Prof. Ram Kripal, Department of Physics, University of Allahabad for providing UV–Visible facility. Authors are thankful to Dr. Giridhar Mishra and Mr. Ramanshu Prabhakar Singh for fruitful discussion and suggestions during the preparation of the manuscript.

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: On behalf of all the authors, the corresponding authors states that there is no conflict of interest.

References

[1] J. Shah, M. Ranjan, K. P. Sooraj, Y. Sonvane, and S. K. Gupta, “Surfactant prevented growth and enhanced thermophysical properties of CuO nanofluid,” J. Mol. Liq., vol. 283, pp. 550–557, 2019. https://doi.org/10.1016/j.molliq.2019.03.127.Search in Google Scholar

[2] M. Wan, R. R. Yadav, K. L. Yadav, and S. B. Yadaw, “Synthesis and experimental investigation on thermal conductivity of nanofluids containing functionalized polyaniline nanofibers,” Exp. Therm. Fluid Sci., vol. 41, pp. 158–164, 2012. https://doi.org/10.1016/j.expthermflusci.2012.03.030.Search in Google Scholar

[3] P. K. Nagarajan, J. Subramani, S. Suyambazhahan, and R. Sathyamurthy, “Nanofluids for solar collector applications: a review,” Energy Procedia, vol. 61, pp. 2416–2434, 2014. https://doi.org/10.1016/j.egypro.2014.12.017.Search in Google Scholar

[4] M. Zhao, W. Lv, Y. Li, et al.., “A study on preparation and stabilizing mechanism of hydrophobic silica nanofluids,” Materials, vol. 11, p. 1385, 2018. https://doi.org/10.3390/ma11081385.Search in Google Scholar PubMed PubMed Central

[5] H. Masuda, A. Ebata, K. Teramae, and N. Hishinuma, “Alteration of thermal conductivity and viscosity of liquid by dispersing ultra-fine particles,” Netsu Bussei, vol. 7, pp. 227–233, 1993. https://doi.org/10.2963/jjtp.7.227.Search in Google Scholar

[6] S. Lee, S. U. S. Choi, S. Li, and J. A. Eastman, “Measuring thermal conductivity of fluids containing oxide nanoparticles,” ASME, J. Heat Transfer, vol. 121, pp. 280–288, 1999. https://doi.org/10.1115/1.2825978.Search in Google Scholar

[7] X. Wang, X. Xu, and S. U. S. Choi, “Thermal conductivity of nanoparticle–fluid mixture,” J. Thermophys. Heat Transf., vol. 13, pp. 474–480, 1999. https://doi.org/10.2514/2.6486.Search in Google Scholar

[8] J. Shah, M. Ranjan, V. Davariya, S. K. Gupta, and Y. Sonvane, “Temperature-dependent thermal conductivity and viscosity of synthesized α-alumina nanofluids,” Appl. Nanosci., vol. 7, pp. 803–813, 2017. https://doi.org/10.1007/s13204-017-0594-7.Search in Google Scholar

[9] M. Thambidurai, N. Muthukumarasamy, S. Agilan, et al.., “Strong quantum confinement effect in nanocrystalline CdS,” J. Mater. Sci., vol. 45, pp. 3254–3258, 2010. https://doi.org/10.1007/s10853-010-4333-7.Search in Google Scholar

[10] S. K. Verma, D. K. Singh, D. K. Pandey, and R. R. Yadav, “Study of nanostructured silver sulfide and its nanofluid,” Natl. Acad. Sci. Lett., vol. 36, pp. 535–540, 2013. https://doi.org/10.1007/s40009-013-0157-8.Search in Google Scholar

[11] C. Burda, T. Green, C. Landes, et al.., Optical Spectroscopy of Nanophase Materials, Weinheim, Germany, Wiley-VCH Verlag GmbH & Co. KGaA, 1999, pp. 197–241.10.1002/3527600094.ch7Search in Google Scholar

[12] A. Nezamzadeh-Ejhieh and Z. Banan, “Comparison between the efficiency of CdS nanoparticles/zeolite A and CdO/zeolite A as catalysts in photodecolorization of crystal violet,” Desalination, vol. 279, pp. 146–151, 2011. https://doi.org/10.1016/j.desal.2011.06.006.Search in Google Scholar

[13] A. Nezamzadeh-Ejhieh and K. Shirvani, “CdS loaded an Iranian clinoptilolite as a heterogeneous catalyst in photodegradation of p-aminophenol,” J. Chem., vol. 2013, p. 541736, 2013. https://doi.org/10.1155/2013/541736.Search in Google Scholar

[14] A. Nezamzadeh-Ejhieh and Z. Banan, “Photodegradation of dimethyldisulfide by heterogeneous catalysis using nanoCdS and nanoCdO embedded on the zeolite A synthesized from waste porcelain,” Desalin. Water Treat., vol. 52, pp. 3328–3337, 2014. https://doi.org/10.1080/19443994.2013.797627.Search in Google Scholar

[15] S. Azimi and A. Nezamzadeh-Ejhieh, “Enhanced activity of clinoptilolite-supported hybridized PbS-CdS semiconductors for the photocatalytic degradation of a mixture of tetracycline and cephalexin aqueous solution,” J. Mol. Catal. Chem., vol. 408, pp. 152–160, 2015. https://doi.org/10.1016/j.molcata.2015.07.017.Search in Google Scholar

[16] P. Devendran, T. Alagesan, T. R. Ravindran, and K. Pandian, “Synthesis of spherical CdS quantum dots using cadmium diethyldithiocarbamate as single source precursor in olive oil medium,” Curr. Nanosci., vol. 10, pp. 302–307, 2014.10.2174/15734137113096660117Search in Google Scholar

[17] P. Devendrana, T. Alagesanb, N. Nallamuthua, S. Asath Bahadura, and K. Pandianc, “Single-precursor synthesis of sub-10 nm CdS nanoparticles embedded on graphene sheets nanocatalyst for active photodegradation under visible light,” Appl. Surf. Sci., vol. 534, p. 147614, 2020. https://doi.org/10.1016/j.apsusc.2020.147614.Search in Google Scholar

[18] A. N. Ejhieh and Z. Banan, “Sunlight assisted photodecolorization of crystal violet catalyzed by CdS nanoparticles embedded on zeolite A,” Desalination, vol. 284, pp. 157–166, 2012. https://doi.org/10.1016/j.desal.2011.08.050.Search in Google Scholar

[19] J. Zhao, J. A. Bardecker, A. M. Munro, et al.., “Efficient CdSe/CdS quantum dot light-emitting diodes using a thermally polymerized hole transport layer,” Nano Lett., vol. 6, pp. 463–467, 2006. https://doi.org/10.1021/nl052417e.Search in Google Scholar PubMed

[20] J. Han, H. Su, D. Zhang, J. Chen, and Z. Chen, “Butterfly wings as natural photonic crystal scaffolds for controllable assembly of CdS NPs,” J. Mater. Chem., vol. 19, pp. 8741–8746, 2009. https://doi.org/10.1039/B911101H.Search in Google Scholar

[21] K. Deng and L. Li, “CdS nanoscale photodetectors,” Adv. Mater., vol. 26, pp. 2619–2635, 2014. https://doi.org/10.1002/adma.201304621.Search in Google Scholar PubMed

[22] T. Gao, Q. H. Li, and T. H. Wang, “CdS nanobelts as photoconductors,” Appl. Phys. Lett., vol. 86, p. 173105, 2005. https://doi.org/10.1063/1.1915514.Search in Google Scholar

[23] Y. Li, V. P. Kotzeva, and D. J. Fray, “Electrochemical performance of CdS nanomaterials synthesized by microemulsion techniques,” Mater. Lett., vol. 60, pp. 2743–2746, 2006. https://doi.org/10.1016/j.matlet.2006.01.082.Search in Google Scholar

[24] M. Hodos, E. Horváth, H. Haspel, Á. Kukovecz, Z. Kónya, and I. Kiricsi, “Photosensitization of ion-exchangeable titanate nanotubes by CdS nanoparticles,” Chem. Phys. Lett., vol. 399, pp. 512–515, 2004. https://doi.org/10.1016/j.cplett.2004.10.064.Search in Google Scholar

[25] H. L. Lee, I. A. M. Belmahi, M. B. Assouar, H. Rinnert, and M. Alnot, “Thermal and optical properties of CdS nanoparticles in thermotropic liquid crystal monomers,” Materials, vol. 3, pp. 2069–2086, 2010. https://doi.org/10.3390/ma3032069.Search in Google Scholar

[26] J. Gangwar, A. K. Srivastava, S. K. Tripathi, M. Wan, and R. R. Yadav, “Strong enhancement in thermal conductivity of ethylene glycol-based nanofluids by amorphous and crystalline Al2O3 nanoparticles,” Appl. Phys. Lett., vol. 105, p. 063108, 2014. https://doi.org/10.1063/1.4893026.Search in Google Scholar

[27] M. Wan, R. Parashar, N. Kumar, et al.., “Heat transfer biofluids: a novel approach towards weed management,” Ecol. Eng., vol. 84, pp. 492–495, 2015. https://doi.org/10.1016/j.ecoleng.2015.09.020.Search in Google Scholar

[28] R. Parashar, M. Wan, R. R. Yadav, A. C. Pandey, and V. Parashar, “Surfactant free synthesis of metal oxide (Co and Ni) nanoparticles and applications to heat propagation in nanofluids,” Mater. Lett., vol. 132, pp. 440–443, 2014. https://doi.org/10.1016/j.matlet.2014.06.126.Search in Google Scholar

[29] P. D. More, “Role of substrate temperatures on structural, optical, wetting and electrical transport properties of CdS thin films,” J. Surf. Eng. Mater. Adv. Technol., vol. 3, pp. 43–47, 2013. https://doi.org/10.4236/jsemat.2013.31006.Search in Google Scholar

[30] T. Tamiji and A. Nezamzadeh-Ejhieh, “Study of kinetics aspects of the electrocatalytic oxidation of benzyl alcohol in aqueous solution on AgBr modified carbon paste electrode,” Mater. Chem. Phys., vol. 237, p. 121813, 2019. https://doi.org/10.1016/j.matchemphys.2019.121813.Search in Google Scholar

[31] A. Noruozi and A. Nezamzadeh-Ejhieh, “Preparation, characterization, and investigation of the catalytic property of α-Fe2O3-ZnO nanoparticles in the photodegradation and mineralization of methylene blue,” Chem. Phys. Lett., vol. 752, p. 137587, 2020. https://doi.org/10.1016/j.cplett.2020.137587.Search in Google Scholar

[32] R. Kripal and U. M. Tripathi, “A comprehensive spectroscopic study of Mn2+ doped PbS nanocrystals,” J. Mater. Sci. Mater. Electron., vol. 29, pp. 12195–12205, 2018. https://doi.org/10.1007/s10854-018-9328-1.Search in Google Scholar

[33] C. Han, F. Wang, C. Gao, et al.., “Transparent epoxy–ZnO/CdS nanocomposites with tunable UV and blue light-shielding capabilities,” J. Mater. Chem. C., vol. 3, pp. 5065–5072, 2015. https://doi.org/10.1039/C4TC02880E.Search in Google Scholar

[34] C. Wang, H. M. Wang, and Z. Y. Fang, “Influence of Mn doping on the microstructure and optical properties of CdS,” J. Alloys Compd., vol. 486, pp. 702–705, 2009. https://doi.org/10.1016/j.jallcom.2009.07.043.Search in Google Scholar

[35] S. B. Aziz, M. A. Rasheed, S. R. Saeed, and O. Gh. Abdullah, “Synthesis and characterization of CdS nanoparticles grown in a polymer solution using in-situ chemical reduction technique,” Int. J. Electrochem. Sci., vol. 12, pp. 3263–3274, 2017. https://doi.org/10.20964/2017.04.10.Search in Google Scholar

[36] S. Kannan, “FT-IR and EDS analysis of the seaweeds Sargassum wightii (brown algae) and Gracilaria corticata (red algae),” Int. J. Curr. Microbiol. Appl. Sci., vol. 3, pp. 341–351, 2014.Search in Google Scholar

[37] J. Yang, J.-H. Zeng, S.-H. Yu, L. Yang, G.-e. Zhou, and Y.-t. Qian, “Formation process of CdS nanorods via solvothermal route,” Chem. Mater., vol. 12, pp. 3259–3263, 2000. https://doi.org/10.1021/cm0000144.Search in Google Scholar

[38] A. A. Gadalla, A. N. Aboelkhir, M. G. Mahesha, and A. Rao, “Synthesis and characterization of Mn doped CdS diluted magnetic semiconductor nanoparticles,” J. Mater. Sci. Mater. Electron., vol. 31, p. 10941, 2020. https://doi.org/10.1007/s10854-020-03240-x.Search in Google Scholar

[39] D. H. Kumar, H. E. Patel, V. R. R. Kumar, T. Sundararajan, T. Pradeep, and S. K. Das, “Model for heat conduction in nanofluids,” Phys. Rev. Lett., vol. 93, p. 144301, 2004. https://doi.org/10.1103/PhysRevLett.93.144301.Search in Google Scholar PubMed

[40] R. Prasher, P. Bhattacharya, and P. E. Phelan, “Thermal conductivity of nanoscale colloidal solutions (nanofluids),” Phys. Rev. Lett., vol. 94, p. 025901, 2005. https://doi.org/10.1103/PhysRevLett.94.025901.Search in Google Scholar PubMed

[41] P. W. Bridgman, “The effect of pressure on the viscosity of forty-three pure liquids,” Proc. Am. Acad. Arts Sci., vol. 61, pp. 57–99, 1926. https://doi.org/10.2307/20026138.Search in Google Scholar

[42] R. S. Khedkar, S. S. Sonawane, and K. L. Wasewar, “Influence of CuO nanoparticles in enhancing the thermal conductivity of water and monoethylene glycol based nanofluids,” Int. Commun. Heat Mass Transfer, vol. 39, pp. 665–669, 2012. https://doi.org/10.1016/j.icheatmasstransfer.2012.03.012.Search in Google Scholar

[43] P. S. Epstein and R. R. Carhart, “The absorption of sound in suspensions and emulsions. I. Water fog in air,” J. Acoust. Soc. Am., vol. 25, pp. 553–565, 1953. https://doi.org/10.1121/1.1907107.Search in Google Scholar

[44] Y. Wang and E. Forssberg, “Production of carbonate and silica nano-particles in stirred bead milling,” Int. J. Miner. Process., vol. 81, pp. 1–14, 2006. https://doi.org/10.1016/j.minpro.2006.05.007.Search in Google Scholar

[45] A. Skumiel, “The effect of temperature on the anisotropy of ultrasound attenuation in a ferrofluid,” J. Phys. D Appl. Phys., vol. 37, pp. 3073–3079, 2004. https://doi.org/10.1088/0022-3727/37/22/003.Search in Google Scholar

[46] T. E. Gómez Álvarez-Arenas, L. E. Segura, and E. R. Franco de Sarabia, “Characterization of suspensions of particles in water by an ultrasonic resonant cell,” Ultrasonics, vol. 39, pp. 715–727, 2002. https://doi.org/10.1016/S0041-624X(02)00375-X.Search in Google Scholar

[47] R. J. Urick, “The absorption of sound in suspensions of irregular particles,” J. Acoust. Soc. Am., vol. 20, pp. 283–289, 1948. https://doi.org/10.1121/1.1906373.Search in Google Scholar

[48] S. Temkin, “Sound propagation in dilute suspensions of rigid particles,” J. Acoust. Soc. Am., vol. 103, pp. 0838–849, 1998. https://doi.org/10.1121/1.421244.Search in Google Scholar

[49] S. Biwa, Y. Watanabe, S. Motogi, and N. Ohno, “Analysis of ultrasonic attenuation in particle-reinforced plastics by a differential scheme,” Ultrasonics, vol. 43, pp. 5–12, 2004. https://doi.org/10.1016/j.ultras.2004.03.002.Search in Google Scholar PubMed

[50] D. K. Singh, D. K. Pandey, and R. R. Yadav, “An ultrasonic characterization of ferrofluid,” Ultrasonics, vol. 49, pp. 634–637, 2009. https://doi.org/10.1016/j.ultras.2009.03.005.Search in Google Scholar PubMed

[51] D. K. Singh, D. K. Pandey, R. R. Yadav, and D. Singh, “A study of nanosized zinc oxide and its nanofluid,” Pramana - J. Phys., vol. 78, pp. 759–766, 2012. https://doi.org/10.1007/s12043-012-0275-8.Search in Google Scholar


Supplementary Material

The online version of this article offerssupplementary material (https://doi.org/10.1515/zna-2020-0334).


Received: 2020-12-05
Revised: 2021-04-12
Accepted: 2021-04-14
Published Online: 2021-05-06
Published in Print: 2021-07-27

© 2021 Walter de Gruyter GmbH, Berlin/Boston

Downloaded on 3.12.2025 from https://www.degruyterbrill.com/document/doi/10.1515/zna-2020-0334/html?lang=en
Scroll to top button