Crystal structures with infinite chains based on antimony tartrate dimers
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Xiqu Wang
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Allan J. Jacobson
Abstract
Seven complex metal antimony tartrates have been synthesized in single crystal form by slowly evaporating aqueous solutions of potassium antimony tartrate (tartar emetic) and divalent metal nitrates or perchlorates. Crystal structures of these compounds all contain infinite chains formed by linking antimony tartrate dimers with divalent metal ions. While infinite chains of antimony tartrate dimers bridged by single Zn2+ ions or by double Mg2+ ions were reported previously, new types of chains with alternating single and double bridging cations are observed in this work.
Funding source: Robert A. Welch Foundation
Award Identifier / Grant number: E-0024
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Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Research funding: This work was financially supported by Robert A. Welch Foundation (Grant No. E-0024).
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Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
Supplementary materials
Crystallographic data have been deposited with the Cambridge Crystallographic Data Center, CCDC No. 2101177 – 2101183. Copies of this information may be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (Fax: 44 1223 336 033; deposit@ccdc.cam.ac.uk).
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© 2021 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- In this issue
- Inorganic Crystal Structures (Original Paper)
- EuTMg2 (T = Pd, Ag, Ir, Pt, Au), EuTCd2 (T = Pd, Pt, Au) and CaRhMg2 – intermetallic compounds with orthorhombically distorted tetrahedral magnesium (cadmium) substructures
- A europium kagome lattice in the solid solution Eu3−х Sr х Pt4Zn12 – first zinc representatives of the Gd3Ru4Al12 type
- CoSO4·H2O and its continuous transition compared to the compression properties of isostructural kieserite-type polymorphs
- TiO2 nanofibers fabricated by electrospinning technique and degradation of MO dye under UV light
- Organic and Metalorganic Crystal Structures (Original Paper)
- A (4,4)-connected zinc(II) coordination polymer constructed with the flexible 2-carboxy phenoxyacetate ligand: synthesis, conformation alteration and fluorescent properties
- Structural, surface, and computational analysis of two vitamin-B1 crystals with sulfonimide-based anions
- Crystal structures with infinite chains based on antimony tartrate dimers
Artikel in diesem Heft
- Frontmatter
- In this issue
- Inorganic Crystal Structures (Original Paper)
- EuTMg2 (T = Pd, Ag, Ir, Pt, Au), EuTCd2 (T = Pd, Pt, Au) and CaRhMg2 – intermetallic compounds with orthorhombically distorted tetrahedral magnesium (cadmium) substructures
- A europium kagome lattice in the solid solution Eu3−х Sr х Pt4Zn12 – first zinc representatives of the Gd3Ru4Al12 type
- CoSO4·H2O and its continuous transition compared to the compression properties of isostructural kieserite-type polymorphs
- TiO2 nanofibers fabricated by electrospinning technique and degradation of MO dye under UV light
- Organic and Metalorganic Crystal Structures (Original Paper)
- A (4,4)-connected zinc(II) coordination polymer constructed with the flexible 2-carboxy phenoxyacetate ligand: synthesis, conformation alteration and fluorescent properties
- Structural, surface, and computational analysis of two vitamin-B1 crystals with sulfonimide-based anions
- Crystal structures with infinite chains based on antimony tartrate dimers
