Startseite Bis(phosphane)copper(I) and silver(I) dithiocarbamates: crystallography and anti-microbial assay
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Bis(phosphane)copper(I) and silver(I) dithiocarbamates: crystallography and anti-microbial assay

  • Nazzatush Shimar Jamaludin , Siti Nadiah Abdul Halim , Chai-Hoon Khoo , Bao-Jing Chen , Tian-Hong See , Jiun-Horng Sim , Yoke-Kqueen Cheah EMAIL logo , Hoi-Ling Seng und Edward R.T. Tiekink EMAIL logo
Veröffentlicht/Copyright: 26. April 2016
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Zeitschrift für Kristallographie - Crystalline Materials
Aus der Zeitschrift Zeitschrift für Kristallographie - Crystalline Materials Band 231 Heft 6

Abstract

The crystal and molecular structures of (Ph3P)2M[S2CN(Me)CH2CH2OH], M=Cu, isolated as a 1:1 dichloromethane solvate (1·CH2Cl2), and M=Ag (4) show the central metal atom to be coordinated by a symmetrically (1·CH2Cl2) and asymmetrically chelating (4) dithiocarbamate ligand. The distorted tetrahedral geometries are completed by two PPh3 ligands. The presence of hydroxyl-O–H···S(dithiocarbamate) hydrogen bonds leads to centrosymmetric dimeric aggregates in each crystal structure. In the molecular packing of 1·CH2Cl2, channels comprising 1 are formed via aryl-C–H···O interactions with the solvent molecules associated with the walls of the channels via methylene-C–H···S, π(aryl) interactions. For 4, the dimeric aggregates are connected via a network of aryl-C–H···π(aryl) interactions. Preliminary screening for anti-microbial activity was conducted. The compounds were only potent against Gram-positive bacteria. Some further selectivity in activity was noted. Most notably, all compounds were active against methicillin resistant Staphylococcus aureus.

Keywords: copper(I); crystal structure analysis; dithiocarbamate; silver(I); X-ray diffraction

Funding source: Ministry of Higher Education, Malaysia

Award Identifier / Grant number: UM.C/HIR-MOHE/SC/12

Funding statement: The support from the University of Malaya and the Ministry of Higher Education, Malaysia, High-Impact Research scheme (UM.C/HIR-MOHE/SC/12) is gratefully acknowledged.

Acknowledgments:

The support from the University of Malaya and the Ministry of Higher Education, Malaysia, High-Impact Research scheme (UM.C/HIR-MOHE/SC/12) is gratefully acknowledged.

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Supplemental Material:

The online version of this article (DOI: 10.1515/zkri-2016-0003) offers supplementary material, available to authorized users.

Received: 2015-11-25
Accepted: 2016-3-21
Published Online: 2016-4-26
Published in Print: 2016-6-1

©2016 by De Gruyter

Artikel in diesem Heft

  1. Frontmatter
  2. Graphical Synopsis
  3. Inorganic Crystal Structures
  4. Ni4 and Ni3Ga clusters as building units in Ca3Ni4Ga4 and Sr3Ni3□Ga4
  5. Crystallographic, DFT and docking (cathepsin B) studies on an organotellurium(IV) compound
  6. Organic and Metalorganic Crystal Structures
  7. Structural systematics of aryl-1,3-dithiane derivatives: crystal and energy-minimised structures, and Hirshfeld surface analysis
  8. Bis(phosphane)copper(I) and silver(I) dithiocarbamates: crystallography and anti-microbial assay
  9. Nanoscratching meets nanoindentation
  10. Hydrogen bonding in 2,6-bis(4-fluorophenyl)-3,5-dimethylpiperidin-4-one methanol solvate
  11. Investigation of the crystal structures and Hirshfeld surfaces of three closely related N-(2-fluorobenzoyl)-arylsulfonamides
https://doi.org/10.1515/zkri-2016-0003
Schlagwörter für diesen Artikel
copper(I); crystal structure analysis; dithiocarbamate; silver(I); X-ray diffraction

Artikel in diesem Heft

  1. Frontmatter
  2. Graphical Synopsis
  3. Inorganic Crystal Structures
  4. Ni4 and Ni3Ga clusters as building units in Ca3Ni4Ga4 and Sr3Ni3□Ga4
  5. Crystallographic, DFT and docking (cathepsin B) studies on an organotellurium(IV) compound
  6. Organic and Metalorganic Crystal Structures
  7. Structural systematics of aryl-1,3-dithiane derivatives: crystal and energy-minimised structures, and Hirshfeld surface analysis
  8. Bis(phosphane)copper(I) and silver(I) dithiocarbamates: crystallography and anti-microbial assay
  9. Nanoscratching meets nanoindentation
  10. Hydrogen bonding in 2,6-bis(4-fluorophenyl)-3,5-dimethylpiperidin-4-one methanol solvate
  11. Investigation of the crystal structures and Hirshfeld surfaces of three closely related N-(2-fluorobenzoyl)-arylsulfonamides
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