Startseite Elastic, thermoelastic and piezoelectric properties of 11 new bis(alkylammonium) and bis(polyalkylammonium) zirconium bis(nitrilotriacetates)
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Elastic, thermoelastic and piezoelectric properties of 11 new bis(alkylammonium) and bis(polyalkylammonium) zirconium bis(nitrilotriacetates)

  • Eiken Haussühl EMAIL logo , Siegfried Haussühl und Ekkehart Tillmanns
Veröffentlicht/Copyright: 15. Juli 2015
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Zeitschrift für Kristallographie - Crystalline Materials
Aus der Zeitschrift Zeitschrift für Kristallographie - Crystalline Materials Band 230 Heft 11

Abstract

Single crystals with dimensions up to 20 × 20 × 20 mm3 of 11 new bis(alkylammonium) zirconium bis(nitrilotriacetates) have been grown from aqueous solutions. Their elastic and thermoelastic properties were derived from ultrasonic resonant frequencies of plane-parallel plates and their shift upon variation of temperature, respectively. All of these crystal species belong to the monoclinic or orthorhombic crystal systems. The majority possesses an acentric crystal structure giving rise to piezoelectric effects, which surmount the maximum longitudinal piezoelectric effect d111 of α-quartz by a factor of two. The pyroelectric effect of two of these specimens is about three to four times larger than π3σ of tourmaline. In addition, the tensors of thermal expansion were determined. Owing to the dominating large size of the anion most physical properties of the salts with different cations behave quite similar. Branched or more globular alkylammonium cations generate a slightly larger mean elastic stiffness than unbranched cations.

Keywords: bis(alkylammonium) zirconium bis(nitrilotriacetates); elasticity; piezoelectricity; thermal expansion; thermoelastic constants

Dedicated to the memory of Siegfried Haussühl who passed away on January 7th, 2014.

Corresponding author: Eiken Haussühl, Institut für Geowissenschaften, Abteilung Kristallographie, Goethe-Universität Frankfurt, Altenhöferallee 1, D-60438, Germany, E-mail:
†Deceased.

Acknowledgments

The authors wish to thank the Austrian Fonds zur Förderung der wissenschaftlichen Forschung FWF (P11684-GEO and P14125-GEO) and the Deutsche Forschungsgemeinschaft DFG (HA5137/1, HA5137/3) for financial support.

References

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Received: 2015-3-3
Accepted: 2015-5-13
Published Online: 2015-7-15
Published in Print: 2015-11-1

©2015 by De Gruyter

Artikel in diesem Heft

  1. Frontmatter
  2. Graphical Synopsis
  3. Preface
  4. Crystal physics in Germany – The lifework of Siegfried Haussühl (*25th November 1927, †07th January 2014)
  5. Original Articles
  6. Pyroelectric properties of the monoclinic rare earth nitrates A2Ln(NO3)5·4H2O (A = NH4, Rb; Ln = La, Ce)
  7. Single crystals of guanidinium zinc sulfate, [C(NH2)3]2Zn(SO4)2 – growth, structure, vibrational spectroscopy and stimulated Raman scattering
  8. 3D printing of representation surfaces from tensor data of KH2PO4 and low-quartz utilizing the WinTensor software
  9. Elastic, thermoelastic and piezoelectric properties of 11 new bis(alkylammonium) and bis(polyalkylammonium) zirconium bis(nitrilotriacetates)
  10. Influence of the Bi 6s2 lone electron pair on elastic properties of monoclinic Bi4B2O9
  11. X-ray topographic study of the antiferroelectric phase transition and antiphase boundaries in copper formate tetrahydrate
https://doi.org/10.1515/zkri-2015-1850
Schlagwörter für diesen Artikel
bis(alkylammonium) zirconium bis(nitrilotriacetates); elasticity; piezoelectricity; thermal expansion; thermoelastic constants

Artikel in diesem Heft

  1. Frontmatter
  2. Graphical Synopsis
  3. Preface
  4. Crystal physics in Germany – The lifework of Siegfried Haussühl (*25th November 1927, †07th January 2014)
  5. Original Articles
  6. Pyroelectric properties of the monoclinic rare earth nitrates A2Ln(NO3)5·4H2O (A = NH4, Rb; Ln = La, Ce)
  7. Single crystals of guanidinium zinc sulfate, [C(NH2)3]2Zn(SO4)2 – growth, structure, vibrational spectroscopy and stimulated Raman scattering
  8. 3D printing of representation surfaces from tensor data of KH2PO4 and low-quartz utilizing the WinTensor software
  9. Elastic, thermoelastic and piezoelectric properties of 11 new bis(alkylammonium) and bis(polyalkylammonium) zirconium bis(nitrilotriacetates)
  10. Influence of the Bi 6s2 lone electron pair on elastic properties of monoclinic Bi4B2O9
  11. X-ray topographic study of the antiferroelectric phase transition and antiphase boundaries in copper formate tetrahydrate
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