Startseite [NaCl][Cu(HSeO3)2], NaCl-intercalated Cu(HSeO3)2: synthesis, crystal structure and comparison with related compounds
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[NaCl][Cu(HSeO3)2], NaCl-intercalated Cu(HSeO3)2: synthesis, crystal structure and comparison with related compounds

  • Vadim M. Kovrugin , Sergey V. Krivovichev EMAIL logo , Olivier Mentré und Marie Colmont
Veröffentlicht/Copyright: 7. August 2015
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Zeitschrift für Kristallographie - Crystalline Materials
Aus der Zeitschrift Zeitschrift für Kristallographie - Crystalline Materials Band 230 Heft 9-10

Abstract

Single crystals of [NaCl][Cu(HSeO3)2] have been prepared by the chemical vapor transport reactions. Its crystal structure (monoclinic, C2/c, a = 13.9874(7), b = 7.2594(4), c = 9.0421(5) Å, β = 127.046(2)°, V = 732.81(7) Å3) is based upon electroneutral [Cu(HSeO3)2] sheets formed by corner sharing between the [CuO4] squares and (HSeO3) groups that are parallel to the (100) plane. Each (SeO2OH)– group forms the Oh1...O2 hydrogen bond to an adjacent hydroselenite group to constitute a [(SeO2OH)2]2– dimer that provides additional stabilization of the copper diselenite sheet. The [Cu(HSeO3)2] sheets alternate with the sheets consisting of zigzag–Na–Cl–Na–Cl–chains formed by Cl atoms and disordered Na sites. The chains are parallel to the c axis. The linkage between the alternating electroneutral [Cu(HSeO3)2] and [NaCl] sheets is provided by the Cu–Cl and Na–O bonds. The coordination of Na is fivefold and consists of three O and two Cl atoms. [NaCl][Cu(HSeO3)2] is a new member of the group of compounds based upon the M(HSeO3)2 layers (M2+ = Cu, Co, Cd). The prototype structure for this group is [Cu(HSeO3)2] that does not have any chemical species separating the copper hydroselenite layers. In other compounds, the interlayer space between the [Cu(HSeO3)2]0 layers is occupied by structural units of different complexity. [NaCl][Cu(HSeO3)2] can be considered as [Cu(HSeO3)2] intercalated with the NaCl layers consisting of one-dimensional–Na–Cl–Na–Cl–chains.

Keywords: copper; crystal structure; intercalated structures; layered compounds; selenite
Corresponding author: Sergey V. Krivovichev, Department of Crystallography, St. Petersburg State University, Universitetskaya nab. 7/9, 199034 St. Petersburg, Russia; and Institute of Silicate Chemistry, Russian Academy of Sciences, Makarova Emb. 6, 199034 St. Petersburg, Russia, E-mail:

Acknowledgments

VMK and SVK have been supported in this work by the Russian Science Foundation (grant 14-17-00071). This work was carried out under the framework of the Multi-InMaDe project supported by the ANR (Grant ANR 2011-JS-0800301). The Fonds Européen de Développement Régional (FEDER), CNRS, Région Nord Pas-de-Calais, and Ministére de l’Education Nationale de l’Enseignement Supérieur et de la Recherche are acknowledged for funding the X-ray diffractometers. VMK also thanks l’Ambassade de France en Russie and l’Agence Campus France (Contract Nos. 768231K, 779116K, 794852B, 808399A, and 808400J) for the partial support of this work.

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Received: 2015-3-2
Accepted: 2015-5-29
Published Online: 2015-8-7
Published in Print: 2015-9-1

©2015 by De Gruyter

Artikel in diesem Heft

  1. Frontmatter
  2. Graphical Synopsis
  3. Review Article
  4. Visualization and analysis of crystal structures using CrystalMaker software
  5. Inorganic Crystal Structures
  6. [NaCl][Cu(HSeO3)2], NaCl-intercalated Cu(HSeO3)2: synthesis, crystal structure and comparison with related compounds
  7. Intermediate-valent CeCoAl – a commensurate modulated structure with short Ce–Co distances
  8. Pressure-induced transformation processes in ferroelastic Pb3(P1–xAsxO4)2, x = 0 and 0.80
  9. Disorder, pseudo symmetry and photoluminescence properties of a new diphosphate K2Ba3(P2O7)2
  10. Organic and Metalorganic Crystal Structures
  11. Determination of crystal structures and tautomeric states of 2-ammoniobenzenesulfonates by laboratory X-ray powder diffraction
  12. [Fe(PNN-iPr)Br2]·xDCM: the first example of merotype-epitaxy of a molecular structure and its solvatomorph
https://doi.org/10.1515/zkri-2015-1849
Schlagwörter für diesen Artikel
copper; crystal structure; intercalated structures; layered compounds; selenite

Artikel in diesem Heft

  1. Frontmatter
  2. Graphical Synopsis
  3. Review Article
  4. Visualization and analysis of crystal structures using CrystalMaker software
  5. Inorganic Crystal Structures
  6. [NaCl][Cu(HSeO3)2], NaCl-intercalated Cu(HSeO3)2: synthesis, crystal structure and comparison with related compounds
  7. Intermediate-valent CeCoAl – a commensurate modulated structure with short Ce–Co distances
  8. Pressure-induced transformation processes in ferroelastic Pb3(P1–xAsxO4)2, x = 0 and 0.80
  9. Disorder, pseudo symmetry and photoluminescence properties of a new diphosphate K2Ba3(P2O7)2
  10. Organic and Metalorganic Crystal Structures
  11. Determination of crystal structures and tautomeric states of 2-ammoniobenzenesulfonates by laboratory X-ray powder diffraction
  12. [Fe(PNN-iPr)Br2]·xDCM: the first example of merotype-epitaxy of a molecular structure and its solvatomorph
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