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Oxidation of l-tyrosine by diperiodatocuprate(III) in CPC micellar medium, facilitated by Ru(III)

  • Abhishek Srivastava

    Abhishek Srivastava has completed his M.Sc. and Ph.D. form University of Lucknow, Lucknow, U.P. India. He has expertise in Chemical Kinetics and Nanochemistry. Till now he has published more than 80 research articles in various Journals of international repute.

     EMAIL logo     , Neetu Srivastava

    Neetu Srivastava has completed her M.Sc. and Ph.D. form University of Gorakhpur, Gorakhpur, U.P. India. He has expertise in inorganic Nanochemistry and Chemical Kinetics. Till now she has published around 30 research articles in various Journals of international repute.

         and Vinay Kumar Singh

    Vinay Kumar Singh has completed her Ph.D. form University of Lucknow, Lucknow, U.P. India. Till now he has published 40 research articles in various Journals of international repute
Published/Copyright: April 8, 2025
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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 62 Issue 3

Abstract

The oxidation of amino acids is interesting due to the different molecules generated by different oxidants. This research is crucial to understand the role of amino acids in redox processes and to identify the active species of Ru(III) and diperiodatocuprate(III) (DPC). The purpose of the present research is to analyze the effect of cationic surfactant on the Ru(III) catalysed oxidation of l-tyrosine (l-Tyr) by DPC. The progression of the reaction was evaluated using the pseudo-first-order scenario as a metric for [OH−], [DPC], ionic strength, [l-Tyr], [Ru(III)], [IO4−], [surfactant], and temperature. Over the range of concentrations studied, the observed reaction exhibits a kinetic order less than one with respect to both [OH−] and [l-Tyr], a negative fractional order with respect to [IO4−], and a first-order dependence on [Ru(III)] and [DPC]. The observed constancy of the oxidation rate with electrolyte addition suggests a zero salt effect. The oxidation rate is markedly increased by Ru(III) solution acting as a catalyst at ppm concentration. The micellar media of cetylpyridinium chloride (CPC) significantly accelerates the rate of the desired reaction, achieving a fourfold increase. The compatibility of CPC with Ru(III) for the oxidation of l-Tyr using DPC is particularly noteworthy.

Keywords: diperiodatocuprate(III); l-tyrosine; micellar medium; Ru(III) catalyzed; oxidation
Corresponding author: Abhishek Srivastava, Department of Chemistry, GLA University, Mathura, 281406, UP, India, E-mail:

About the authors

Abhishek Srivastava

Abhishek Srivastava has completed his M.Sc. and Ph.D. form University of Lucknow, Lucknow, U.P. India. He has expertise in Chemical Kinetics and Nanochemistry. Till now he has published more than 80 research articles in various Journals of international repute.

Neetu Srivastava

Neetu Srivastava has completed her M.Sc. and Ph.D. form University of Gorakhpur, Gorakhpur, U.P. India. He has expertise in inorganic Nanochemistry and Chemical Kinetics. Till now she has published around 30 research articles in various Journals of international repute.

Vinay Kumar Singh

Vinay Kumar Singh has completed her Ph.D. form University of Lucknow, Lucknow, U.P. India. Till now he has published 40 research articles in various Journals of international repute

  1. Research ethics: Not applicable.

  2. Informed consent: Not applicable.

  3. Author contributions: A.S.: Supervision, Conceptualization, Statistical analysis, Writing original draft. N. S.: Methodology, Investigation, Experimental, Graphical Work. V. K. S.: Investigation, Formal Analysis, Writing original draft.

  4. Use of Large Language Models, AI and Machine Learning Tools: None declared.

  5. Conflict of interest: The authors state no conflict of interest.

  6. Research funding: None declared.

  7. Data availability: Not applicable.

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Received: 2025-02-04
Accepted: 2025-02-24
Published Online: 2025-04-08
Published in Print: 2025-05-26

© 2025 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. Review Article
  3. Precision-engineered nanomaterials: unlocking the potential of water-in-oil microemulsions for the controlled synthesis, morphology design, and future innovations
  4. Micellar Catalysis
  5. Oxidation of l-tyrosine by diperiodatocuprate(III) in CPC micellar medium, facilitated by Ru(III)
  6. A comprehensive spectral study of dye-surfactant complex formation by Xylenol Orange with selective aqueous micellar media of CPC, rhamnolipids and saponin
  7. Physical Chemistry
  8. Preparation of polyoxyethylene(n) monodehydroabietates and their physicochemical properties
  9. Surface modification of synthetic montmorillonite as thickener: rheological behavior and tribological properties at high load and high temperature
  10. Drug Delivery System
  11. Exploring fatty acid-amino acid conjugate for the development of self-assembling, pH-sensitive vesicles for targeted anticancer drug delivery
  12. Novel Sufactants
  13. Double headed alkyl triazole glycosides – alternatives for APGs with increased hydrophilicity part 1: synthesis and physicochemical properties
  14. Synthesis and defoaming properties of two sulfonate surfactants from trisiloxane
  15. Application
  16. Criteria for a surfactant to be used sequentially as a grinding aid and collector
  17. Chitosan/hydroxyapatite biomimetic material loaded with Curcuma longa L. essential oil
https://doi.org/10.1515/tsd-2025-2662
Keywords for this article
diperiodatocuprate(III); l-tyrosine; micellar medium; Ru(III) catalyzed; oxidation

Articles in the same Issue

  1. Frontmatter
  2. Review Article
  3. Precision-engineered nanomaterials: unlocking the potential of water-in-oil microemulsions for the controlled synthesis, morphology design, and future innovations
  4. Micellar Catalysis
  5. Oxidation of l-tyrosine by diperiodatocuprate(III) in CPC micellar medium, facilitated by Ru(III)
  6. A comprehensive spectral study of dye-surfactant complex formation by Xylenol Orange with selective aqueous micellar media of CPC, rhamnolipids and saponin
  7. Physical Chemistry
  8. Preparation of polyoxyethylene(n) monodehydroabietates and their physicochemical properties
  9. Surface modification of synthetic montmorillonite as thickener: rheological behavior and tribological properties at high load and high temperature
  10. Drug Delivery System
  11. Exploring fatty acid-amino acid conjugate for the development of self-assembling, pH-sensitive vesicles for targeted anticancer drug delivery
  12. Novel Sufactants
  13. Double headed alkyl triazole glycosides – alternatives for APGs with increased hydrophilicity part 1: synthesis and physicochemical properties
  14. Synthesis and defoaming properties of two sulfonate surfactants from trisiloxane
  15. Application
  16. Criteria for a surfactant to be used sequentially as a grinding aid and collector
  17. Chitosan/hydroxyapatite biomimetic material loaded with Curcuma longa L. essential oil
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