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Iterative evaluation of micellar and thermodynamic properties of 12-2-12 in 1 % BSA aqueous solution in the presence of organic solvents and temperature

  • Ashwani Kumar Sood

    Ashwani Kumar Sood is Associate Professor in the Department of Chemistry, Guru Nanak Dev University, Amritsar. He received his M. Tech. degree in Material Science from National Institute of Technology, Jalandhar. He has published more than 40 papers in journals of international reputation. Presently he is working on physicochemical properties of surfactant and their mixtures.

     EMAIL logo     , Sachin Kumar Godara

    Sachin Kumar Godara is an Assistant Professor in the Department of Apparel and Textile Technology, Guru Nanak Dev University, Amritsar. He received his M. Tech. degree in Textile from Indian Institute of technology Delhi. He has published more than 60 papers in journals of international reputation. Presently he is working on physicochemical properties of surfactant and ferrites.

         and Meenu Aggarwal

    Meenu Aggarwal is Associate Professor in the Department of Mathematics DAV College Amritsar. She did her M. Sc. degree in Mathematics from Guru Nanak Dev University, Amritsar. She has more than 26 years of teaching experience and published 5 papers in journals of international reputation.
Published/Copyright: November 30, 2023
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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 61 Issue 1

Abstract

The interactions between a gemini surfactant 12-2-12 and bovine serum albumin (BSA) have been studied in aqueous and mixed aqueous media by conductance measurements using the iterative method at different temperatures ranging from 298.15 K to 313.15 K with step size 5. The critical micellar concentration (CMC) as well as the degree of ionization for the micelles (α) have been evaluated and their variation with solvent type and temperature has been discussed. The error for conductivity measurements was calculated and found to be much smaller than for surface tension measurements using the platinum ring method. The CMC values for the mixture of 12-2-12 and BSA in aqueous solvent solutions follow the sequence: DMF > AN > DMSO > water. These values were further confirmed by surface tension studies. From the thermodynamic parameters, hydrophobic interactions were found to be the driving force for micellization. The existence of enthalpy-entropy compensation was established from the linear plot of ΔH° m and ΔS° m .

Keywords: 12-2-12 Gemini surfactant; bovine serum albumin (BSA); CMC; conductivity; thermodynamics
Corresponding author: Ashwani Kumar Sood, Department of Chemistry, UGC Centre for Advanced Studies II, Guru Nanak Dev University, Amritsar, 143 005, Punjab, India, E-mail:

About the authors

Ashwani Kumar Sood

Ashwani Kumar Sood is Associate Professor in the Department of Chemistry, Guru Nanak Dev University, Amritsar. He received his M. Tech. degree in Material Science from National Institute of Technology, Jalandhar. He has published more than 40 papers in journals of international reputation. Presently he is working on physicochemical properties of surfactant and their mixtures.

Sachin Kumar Godara

Sachin Kumar Godara is an Assistant Professor in the Department of Apparel and Textile Technology, Guru Nanak Dev University, Amritsar. He received his M. Tech. degree in Textile from Indian Institute of technology Delhi. He has published more than 60 papers in journals of international reputation. Presently he is working on physicochemical properties of surfactant and ferrites.

Meenu Aggarwal

Meenu Aggarwal is Associate Professor in the Department of Mathematics DAV College Amritsar. She did her M. Sc. degree in Mathematics from Guru Nanak Dev University, Amritsar. She has more than 26 years of teaching experience and published 5 papers in journals of international reputation.

Acknowledgments

The authors are grateful to UGC, India, for their UGC-CAS program and DST, India, for the FIST program awarded to the Department of Chemistry, Guru Nanak Dev University, Amritsar.

  1. Research funding: The authors declare that no financial assistance has been received

  2. Author contributions: All authors have accepted responsibility for the entire content of this manuscript and approved its submission.

  3. Competing interests: Authors state no conflict of interest.

  4. Informed consent: Informed consent was obtained from all individuals included in this study.

  5. Ethical approval: The local Institutional Review Board deemed the study exempt from review.

  6. Data Availability: All the data is available with the corresponding author and can be provided on request.

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Received: 2023-06-13
Accepted: 2023-10-11
Published Online: 2023-11-30
Published in Print: 2024-01-29

© 2023 Walter de Gruyter GmbH, Berlin/Boston

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  3. A novel approach to mixed micelles formation: study the interactions between bis-quaternary ammonium salts and nonionic surfactant Triton X-100
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  10. Iterative evaluation of micellar and thermodynamic properties of 12-2-12 in 1 % BSA aqueous solution in the presence of organic solvents and temperature
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https://doi.org/10.1515/tsd-2023-2540
Keywords for this article
12-2-12 Gemini surfactant; bovine serum albumin (BSA); CMC; conductivity; thermodynamics

Articles in the same Issue

  1. Frontmatter
  2. Bis-Quaternary Ammonium Salts
  3. A novel approach to mixed micelles formation: study the interactions between bis-quaternary ammonium salts and nonionic surfactant Triton X-100
  4. Applications
  5. Brevity is the soul of wit – how time, temperature and detergent choice impact the cleaning performance in domestic dishwashers
  6. The preparation of a novel modified chitosan: application to the removal of lead and cephalexin
  7. Removal of acid dye from wastewater by cloud point extraction and regeneration of surfactant by pH regulation
  8. Effect of glauconite and SLS surfactant on phosphate and calcite rheology
  9. Physical Chemistry
  10. Iterative evaluation of micellar and thermodynamic properties of 12-2-12 in 1 % BSA aqueous solution in the presence of organic solvents and temperature
  11. Novel Surfactants
  12. Corrosion inhibition of pure iron by Eurohypnum leptothallum extract in 0.5 mol L−1 H2SO4: an experimental and GC-MS based study
  13. Study on rheology of a novel UV-light sensitive trimeric anionic–cationic surfactant/trans-o-methoxycinnamic acid micellar system
  14. Biosurfactants
  15. An overview on trehalolipids: a promising eco-friendly bio-surfactant
  16. A mini review on synthetic and biosurfactants: origin and structure, physicochemical properties, applications, cost of production, toxicity, biodegradability and environmental effects
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