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Application of Newly Synthesized Sulfobetaine Based on Sweet Almond Oil in Bath Liquids for Sensitive Skin

Anwendung eines neu synthetisierten Sulfobetains auf der Basis von Süßmandelöl in Badeflüssigkeiten für empfindliche Haut.
  • Emilia Klimaszewska

    Prof. Dr. Emilia Klimaszewska is a lecturer at the Department of Cosmetology at the Faculty of Medical Sciences and Health Sciences, Kazimierz Pulaski University of Technology and Humanities in Radom. The area of scientific interest includes industrial research and development of innovative formulations of cosmetics, pharmaceutical products (in particular products for children and cosmetics for sensitive skin), household chemistry products in the context of quality control.

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    , Daria Wieczorek

    Prof. Daria Wieczorek is a lecturer at the Department of Technology and Instrumental Analysis at the Institute of Quality Science, Poznan University of Economics and Business. Her scientific interest includes essential oils, adjuvants, ingredient of household and personal care products, surface and antimicrobial properties of surfactants.

    , Artur Seweryn

    Dr. Artur Seweryn is a lecture at the Department of Commodity Sciences and Quality Science at the Faculty of Chemical Engineering and Commodity Science, Kazimierz Pulaski University of Technology and Humanities in Radom. Main research topics are manufacturing of household products and cosmetics, quality assessment, aspects related to the safety of use of cosmetics and household chemicals, functional and physicochemical testing.

    and Marta Ogorzałek

    Dr. Marta Ogorzałek is a lecturer at the Commodity Science and Quality Sciences at the Faculty of Chemical Engineering and Commodity Science, Kazimierz Pulaski University of Technology and Humanities in Radom. The area of scientific interest concentrates on industrial research and development of innovative formulations of household products (especially fabric softener products) and cosmetics products, in the context of quality control.

Published/Copyright: March 13, 2021
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Abstract

Three formulations for bath liquids were developed, differing in the type of amphoteric surfactant applied. The formulations used Cocamidopropyl Betaine, Cocamidpropyl Hydroxide and newly synthesized sulfobetaine based on sweet almond oil (Oleicamidopropyl Sultaine). The molecular structure of the surfactant used in the manufactured formulations has a negatively charged sulfonate group and a positively charged quaternary nitrogen atom. Such molecular structures suggest that the functional properties of this substance are mild. Based on the research, it was found that the bath fluid containing the newly synthesized sulfobetaine based on sweet almond oil had the lowest zein number, the lowest pH increase of bovine albumin solution and the lowest ability to emulsify fatty dirt. This indicates a very low irritant effect of the tested bath liquid.

Abstract

Es wurden drei Formulierungen für flüssige Badeprodukte entwickelt, die sich durch die Art des verwendeten amphoteren Tensids unterscheiden: Cocamidopropylbetain, Cocamidpropylhydroxid und das neu synthetisierte Sulfobetain auf der Basis von Süßmandelöl (Oleicamidopropyl Sultain). Die Molekülstruktur des in den hergestellten Formulierungen verwendeten Tensids weist eine negativ geladene Sulfonatgruppe und ein positiv geladenes quaternäres Stickstoffatom auf. Solche Molekularstrukturen lassen vermuten, dass die Gebrauchseigenschaften dieser Substanz mild sind. Auf der Grundlage der Forschung wurde festgestellt, dass die Badeflüssigkeit, die das neu synthetisierte Sulfobetain auf der Basis von Süßmandelöl enthielt, die niedrigste Zeinzahl, den geringsten pH-Wert-Anstieg der Rinderalbuminlösung und die geringste Fähigkeit zur Emulgierung von Fettschmutz aufwies. Dies deutet auf eine sehr geringe Reizwirkung der getesteten Badeflüssigkeit hin.


Prof. Dr. Emilia Klimaszewska Department of Cosmetology Faculty of Medical Sciences and Health Sciences Kazimierz Pulaski University of Technology and Humanities in Radom 27 Boleslawa Chrobrego Street Radom 26-600, Poland Tel.: +48483617574

About the authors

Prof. Dr. Emilia Klimaszewska

Prof. Dr. Emilia Klimaszewska is a lecturer at the Department of Cosmetology at the Faculty of Medical Sciences and Health Sciences, Kazimierz Pulaski University of Technology and Humanities in Radom. The area of scientific interest includes industrial research and development of innovative formulations of cosmetics, pharmaceutical products (in particular products for children and cosmetics for sensitive skin), household chemistry products in the context of quality control.

Prof. Daria Wieczorek

Prof. Daria Wieczorek is a lecturer at the Department of Technology and Instrumental Analysis at the Institute of Quality Science, Poznan University of Economics and Business. Her scientific interest includes essential oils, adjuvants, ingredient of household and personal care products, surface and antimicrobial properties of surfactants.

Dr. Artur Seweryn

Dr. Artur Seweryn is a lecture at the Department of Commodity Sciences and Quality Science at the Faculty of Chemical Engineering and Commodity Science, Kazimierz Pulaski University of Technology and Humanities in Radom. Main research topics are manufacturing of household products and cosmetics, quality assessment, aspects related to the safety of use of cosmetics and household chemicals, functional and physicochemical testing.

Dr. Marta Ogorzałek

Dr. Marta Ogorzałek is a lecturer at the Commodity Science and Quality Sciences at the Faculty of Chemical Engineering and Commodity Science, Kazimierz Pulaski University of Technology and Humanities in Radom. The area of scientific interest concentrates on industrial research and development of innovative formulations of household products (especially fabric softener products) and cosmetics products, in the context of quality control.

Acknowledgements

Funded with the assistance of the Ministry of Science and Higher Education from subsidies for statutory activity. Project no. 3086/ 35/P entitled \Development of formulations and technologies for the manufacture of innovative cosmetics, pharmacy supplies, household and industrial chemicals" and project no. 3501/188/P entitled \Application of innovative raw materials of natural and synthetic origin in the care and support of treatment of skin diseases in various clinical conditions"..

References

1 Walters, R. M., Fevola, M. J., LiBrizzi, J. J. and Martin, K.: Designing cleansers for the unique needs of baby skin, Cosmet. Toil. 123 (2008) 53–60.Search in Google Scholar

2 Klimaszewska, E., Seweryn, A., Ogorzałek, M., Nizioł-Łukaszewska, Z., and Wasilewski, T.: Reduction of irritation potential caused by anionic surfactants in the use of various forms of collagen derived from marine sources in cosmetics for children, Tenside Surfact Det. 56 (2019) 180 – 187. DOI:10.3139/113.11061610.3139/113.110616Search in Google Scholar

3 Hall-Manning, T. J., Holland, G. H., Rennie, G., Revell, P., Hines, J., Barratt, M. D. and Basketter, D. A.: Skin irritation potential of mixed surfactant systems, Food Chem. Toxicol. 36 (1998) 233–238. DOI:10.1016/S0278-6915(97)00144-010.1016/S0278-6915(97)00144-0Search in Google Scholar

4 Seweryn, A.: Interactions between surfactants and the skin–theory and practice, Adv. Colloid Interface Sci., 256 (2018) 242–255. PMid:29685575; DOI:10.1016/j.cis.2018.04.00210.1016/j.cis.2018.04.002Search in Google Scholar PubMed

5 Klimaszewska, E., Seweryn, A., Czerwonka, D., Piotrowska, U. and Ogorzałek, M.: Improvement of the safety in use of babies cosmetics through appropriate selection of surfactants Przem. Chem. 96 (2017) 2509 – 2513. DOI:10.15199/62.2017.12.2310.15199/62.2017.12.23Search in Google Scholar

6 Mukherjee, S., Yang, L., Vincent, C., Lei, X., Ottaviani, M. F. and Ananthapadmanabhan, K. P.: A comparison between interactions of triglyceride oil and mineral oil with proteins and their ability to reduce cleanser surfactant induced irritation, Int. J. Cosmet. Sci. 37 (2015) 371–378. PMid:25656133; DOI:10.1111/ics.1220510.1111/ics.12205Search in Google Scholar PubMed

7 Bujak, T., Wasilewski, T. and Nizioł-Łukaszewska, Z.: Role of macromolecules in the safety of use of body wash cosmetics, Colloids Surf. B: Biointerfaces. 135 (2015) 497–503. PMid:26291586; 10.1016/j.colsurfb.2015.07.051Search in Google Scholar PubMed

8 Wasilewski, T. and Seweryn, A.: Effect of the hydrophobic plant extract and sodium chloride content on the rheological properties of hand dishwashing liquids, Przem. Chem. 95 (2016) 778–783. DOI:10.15199/62.2016.4.1310.15199/62.2016.4.13Search in Google Scholar

9 Falbe, J.: Surfactants in consumer products, Theory, Technology and Application, Springer Science & Business Media, Berlin (2012):. DOI:10.1007/978-3-642-71545-710.1007/978-3-642-71545-7Search in Google Scholar

10 Rosen, M. J. and Kunjappu, J. T.: Surfactants and interfacial phenomena, John Wiley & Sons, New Jersey (2012). DOI:10.1002/978111822892010.1002/9781118228920Search in Google Scholar

11 Ogorzałek, M., Wasilewski, T., Klimaszewska, E. and Zięba, M.: Effect of Hydrophobic Plant Extract on the Physicochemical Properties of a Transparent Fabric Softener, J Surfactants Deterg. 23 (2020) 405–413. DOI:10.1002/jsde.1237010.1002/jsde.12370Search in Google Scholar

12 Clendennen, S. K. and Boaz, N. W.: Betaine Amphoteric Surfactants, Synthesis, Properties, and Applications, In: Hayes, D. G., Solaiman D. K. Y. and Ashby R. D. (Eds.), Biobased Surfactants, AOCS Press, (2019) 447. DOI:10.1016/B978-0-12-812705-6.00014-910.1016/B978-0-12-812705-6.00014-9Search in Google Scholar

13 Schnuch, A., Lessmann, H., Geier, J. and Uter, W.: Is cocamidopropyl betaine a contact allergen? Analysis of network data and short review of the literature, Contact Dermatitis. 64 (2011) 203–211. PMid:21392028; DOI:10.1111/j.1600-0536.2010.01863.x10.1111/j.1600-0536.2010.01863.xSearch in Google Scholar PubMed

14 Staszak, K., Wieczorek, D. and Michocka, K.: Effect of sodium chloride on the surface and wetting properties of aqueous solutions of cocamidopropyl betaine, J Surfactants Deterg. 18 (2015) 321–328. PMid:25705107; DOI:10.1007/s11743-014-1644-810.1007/s11743-014-1644-8Search in Google Scholar PubMed PubMed Central

15 Dominguez, J. G., Balaguer, F., Parra, J. L. and Pelejero, C. M.: The inhibitory effect of some amphoteric surfactants on the irritation potential of alkylsulphates, Int. J. Cosmet. Sci. 3 (1981) 57–68. PMid:19469927; DOI:10.1111/j.1467-2494.1981.tb00268.x10.1111/j.1467-2494.1981.tb00268.xSearch in Google Scholar PubMed

16 Hunter, J. E. and Fowler Jr, J. F.: Safety to human skin of cocamidopropyl betaine: A mild surfactant for personal – care products, J Surfactants Deterg. 1 (1998) 235–239. DOI:10.1007/s11743-998-0025-310.1007/s11743-998-0025-3Search in Google Scholar

17 Fowler, J. J., Zug, K. M., Taylor, J. S., Storrs, F. J., Sherertz, E. A., Sasseville, D. A. and Maibach, H. I.: Allergy to cocamidopropyl betaine and amidoamine in North America, Dermatitis, 15 (2004) 5–6. PMid:15573641; DOI:10.2310/6620.2004.2041010.2310/6620.2004.20410Search in Google Scholar PubMed

18 Foti, C., Bonamonte, D., Mascolo, G., Corcelli, A., Lobasso, S., Rigano, L. and Angelini, G.: The role of 3- dimethylaminopropylamine and amidoamine in contact allergy to cocamidopropylbetaine, Contact Dermatitis. 48 (2003) 194–198. PMid:12786723; DOI:10.1034/j.1600-0536.2003.00078.x10.1034/j.1600-0536.2003.00078.xSearch in Google Scholar PubMed

19 Ananthapadmanabhan, K. P., Yang, L., Vincent, C., Tsaur, L., Vetro, K., Foy, V., Zhang, S., Ashkenazi, A., Pashkovski, E. and Subramanian, V.: A novel technology in mild and moisturizing cleansing liquids, Cosmetic Dermatology. 22 (2009) 307–316.Search in Google Scholar

20 Tomar, J., Jain, V. K., Aggarwal, K., Dayal, S. and Gupta, S.: Contact allergies to cosmetics: testing with 52 cosmetic ingredients and personal products, J Dermatol. 32 (2005) 951–955. PMid:16471456; DOI:10.1111/j.1346-8138.2005.tb00880.x10.1111/j.1346-8138.2005.tb00880.xSearch in Google Scholar PubMed

21 Alani, J. I., Davis, M. D. P. and Yiannias, J. A.: Allergy to cosmetics: a literature review, Dermatitis 24, 6 (2013) 283–290. PMid:24201464; DOI:10.1097/DER.0b013e3182a5d8bc10.1097/DER.0b013e3182a5d8bcSearch in Google Scholar PubMed

22 Götte, E. (Eds.): Skin compatibility of tensides measured by their capacity for dissolving zein protein, The fourth international congress on surface active substances, Brussels, Belgium (1964), 83.Search in Google Scholar

23 Pezron, I., Galet, L. and Clausse, D.: Surface interaction between a protein monolayer and surfactants and its correlation with skin irritation by surfactants, J. Colloid Interf. Sci. 180 (1996) 285–289. DOI:10.1006/jcis.1996.030110.1006/jcis.1996.0301Search in Google Scholar

24 Nizioł-Łukaszewska, Z., Osika, P., Wasilewski, T. and Bujak, T.: Hydrophilic dogwood extracts as materials for reducing the skin irritation potential of body wash cosmetics, Molecules 22, 2 (2017) 320–335. PMid:28218732; DOI:10.3390/molecules2202032010.3390/molecules22020320Search in Google Scholar PubMed PubMed Central

25 Seweryn, A. and Bujak, T.: Application of anionic phosphorus derivatives of alkyl polyglucosides for the production of sustainable and mild body wash cosmetics, ACS Sustain. Chem. Eng. 6, 12 (2018) 17294–17301. DOI:10.1021/acssuschemeng.8b0471110.1021/acssuschemeng.8b04711Search in Google Scholar

26 Ahmad, Z.: The uses and properties of almond oil, Complement. Ther. Clin. Pract. 16, 1 (2010) 10–12. PMid:20129403; DOI:10.1016/j.ctcp.2009.06.01510.1016/j.ctcp.2009.06.015Search in Google Scholar PubMed

27 Moayedi, A., Rezaei, K., Moini, S. and Keshavarz, B.: Chemical compositions of oils from several wild almond species, J. Am. Oil Chem.’ Soc. 88, 4 (2011) 503–508. DOI:10.1007/s11746-010-1701-z10.1007/s11746-010-1701-zSearch in Google Scholar

28 Özcan, M. M., Ünver, A., Erkan, E. and Arslan, D.: Characteristics of some almond kernel and oils, Sci. Hortic. 127, 3 (2011) 330–333. DOI:10.1016/j.scienta.2010.10.02710.1016/j.scienta.2010.10.027Search in Google Scholar

29 Kodad, O., Estopan?aín, G., Juan, T., Mamouni, A. and Socias Company, R.: Tocopherol concentration in almond oil: Genetic variation and environmental effects under warm conditions, J. Agric. Food Chem. 59, 11 (2011) 6137–6141. DOI:10.1021/jf200323c10.1021/jf200323cSearch in Google Scholar PubMed

30 Chen, C. Y., Lapsley, K. and Blumberg, J.: A nutrition and health perspective on almonds, J. Sci. Food Agric. 86, 14 (2006) 2245–2250. DOI:10.1002/jsfa.265910.1002/jsfa.2659Search in Google Scholar

31 Wasilewski, T., Seweryn, A. and Bujak, T.: Supercritical carbon dioxide blackcurrant seed extract as an anti-irritant additive for hand dishwashing liquids, Green Chem Lett Rev 9, 2 (2016) 114–121. DOI:10.1080/17518253.2016.118043210.1080/17518253.2016.1180432Search in Google Scholar

32 Imokawa, G., Sumura, K. and Katsumi, M.: Study on skin roughness caused by surfactants: II. Correlation between protein denaturation and skin roughness, J Am Oil Chem Soc 52, 12, (1975) 484–489. PMid:172549; DOI:10.1007/BF0264073710.1007/BF02640737Search in Google Scholar PubMed

33 Tavss, E. A., Eigen, E. and Kligman, A. M.: Anionic detergent-induced skin irritation and anionic detergent-induced pH rise of bovine serum albumin, J Soc Cosmet Chem 39, 4 (1988) 267–272.Search in Google Scholar

34 Klimaszewska, E., Ogorzałek, M., Seweryn, A. and Wasilewski, T.: Application properties of bath liquids for children based on Sodium Laureth Sulfate with addition of different molecular weight collagens derived from marine sources, J Surfactants Deterg. 22, 6, (2019), 1469–1475. DOI:10.1002/jsde.1234310.1002/jsde.12343Search in Google Scholar

35 Burnett, C. L., Bergfeld, W. F., Belsito, D. V., Hill, R. A., Klaassen, C. D., Liebler, D. and Andersen, F. A.: Final report of the Cosmetic Ingredient Review Expert Panel on the safety assessment of cocamidopropyl betaine (CAPB), Int. J. Toxicol. 31, 4 (2012) 77–111. PMid:22869896; DOI:10.1177/109158181244720210.1177/1091581812447202Search in Google Scholar PubMed

36 Block, C.: Human and Environmental Risk Assessment on ingredients of household cleaning products, Jorn. Com. Esp. Deterg. 33 (2003) 39–44.Search in Google Scholar

37 Suuronen, K., Pesonen, M. and Aalto-Korte, K.: Occupational contact allergy to cocamidopropyl betaine and its impurities, Contact Derm. 66, 5 (2012) 286–292. PMid:22364510; DOI:10.1111/j.1600-0536.2011.02036.x10.1111/j.1600-0536.2011.02036.xSearch in Google Scholar PubMed

38 Foti, C., Bonamonte, D., Mascolo, G., Corcelli, A., Lobasso, S., Rigano, L. and Angelini, G.: The role of 3-dimethylaminopropylamine and amidoamine in contact allergy to cocamidopropylbetaine, Contact Derm. 48, 4 (2003) 194–198. PMid:12786723; DOI:10.1034/j.1600-0536.2003.00078.x10.1034/j.1600-0536.2003.00078.xSearch in Google Scholar PubMed

39 Belsito, D. V., Hill, R. A., Klaassen, C. D., Liebler, D. C., Marks Jr, J. G., Shank, R. C., Slaga, T. J. and Snyder, P. W.: Safety Assessment of Alkyl Sultaines as Used in Cosmetics, Washington (2017).Search in Google Scholar

40 Guin, J. D.: Reaction to cocamidopropylhydroxysultaine, an amphoteric surfactant and conditioner, Contact Derm., 42, 5 (2000) 284.Search in Google Scholar

Received: 2020-07-06
Accepted: 2020-11-16
Published Online: 2021-03-13

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