Synthesis and Properties of Alkyl Bis-Guanidinium Acetates Surfactants
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Yongbo Song , Senior engineer, Taiyuan Institute of Technology, China. He received Ph.D. from Shanxi University, China. His research interests are focused on the synthesis, physicochemical property and theoretical research of cationic surfactants.
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Hongyan Zheng , Senior engineer of Taiyuan Institute of Technology. Her research field is focused on the application investigation of surfactants.Yulan Niu , Dean of department of chemistry and chemical engineering, Taiyuan Institute of Technology, China. His research interests are focused on the engineering development related to manufactures of fine chemical.Ying Yao , Lecturer, Taiyuan Institute of Technology, China. Her research field is focused on the theoretical investigation of surfactants.Rongqian Meng , Lecturer, Taiyuan Institute of Technology, China. Her research field is focused on the analysis and detection of surfactants.
Abstract
Novel surfactants with double hydrophilic groups (cocopropane and tallowpropane bis-guanidinium acetates), were synthesized and tested to evaluate both the basic surfactant properties and the unique application performance. Surface tension, conductivity and contact angle measurements were used to study the self-aggregation behavior in aqueous solution. Aggregation parameters were calculated such as adsorption efficiency and effectiveness (pC20 and CAC/C20), the maximum surface excess concentration (Гmax) and minimum surface area permolecule (Amin). The thermodynamic parameters of aggregation based conductivity measurements revealed that the aggregation process was spontaneous and entropy-driven. Compared to DTAC and CTAC, the alkyl bis-guanidinium acetates showed a higher emulsification capacity with both liquid kerosene and soybean oil. The evaluation of antimicrobial activity showed that the alkyl bisguanidinium acetates exhibited strong antibacterial activity against the tested strains at a concentration of 50 ppm.
Abstract
Synthese und Eigenschaften von Alkylbiguanidinacetat-Tensiden. Es wurden neuartige Tenside mit doppelten hydrophilen Gruppen (Kokospropan- und Rindertalgpropan-Biguanidinacetat) synthetisiert und getestet, um sowohl die grundlegenden oberflächenaktiven Eigenschaften als auch die einzigartige Anwendungsleistung zu bewerten. Oberflächenspannung, Leitfähigkeit und Kontaktwinkelmessungen wurden zur Untersuchung des Selbstaggregationsverhaltens in wässriger Lösung verwendet. Es wurden Aggregationsparameter wie die Adsorptionseffizienz und -effektivität (pC20 und CAC/C20), die maximale Oberflächen-Überschusskonzentration (Гmax) und der minimale Oberflächenbedarf pro Tensidmolekül (Amin) berechnet. Die thermodynamischen Parameter der Aggregation, die aus den Leitfähigkeitsmessungen berechnet wurden, zeigten, dass der Aggregationsprozess spontan und entropiegetrieben war. Im Vergleich zu DTAC und CTAC wiesen die Alkylbiguanidinacetate ein stärkeres Emulgiervermögen sowohl mit Flüssigparaffin als auch mit Sojaöl auf. Die Bewertung der antimikrobiellen Aktivität ergab, dass die Alkylbiguanidinacetate bei einer Konzentration von 50 ppm eine starke antibakterielle Aktivität gegen die getesteten Stämme aufwiesen.
About the authors
Yongbo Song, Senior engineer, Taiyuan Institute of Technology, China. He received Ph.D. from Shanxi University, China. His research interests are focused on the synthesis, physicochemical property and theoretical research of cationic surfactants.
Hongyan Zheng, Senior engineer of Taiyuan Institute of Technology. Her research field is focused on the application investigation of surfactants.
Yulan Niu, Dean of department of chemistry and chemical engineering, Taiyuan Institute of Technology, China. His research interests are focused on the engineering development related to manufactures of fine chemical.
Ying Yao, Lecturer, Taiyuan Institute of Technology, China. Her research field is focused on the theoretical investigation of surfactants.
Rongqian Meng, Lecturer, Taiyuan Institute of Technology, China. Her research field is focused on the analysis and detection of surfactants.
Acknowledgements
The authors acknowledge the financial supports by Science and Technology Innovation Project of Higher Education Institutions in Shanxi (No. 2019L0930).
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Articles in the same Issue
- Contents
- Environmental Chemistry
- Biodegradability of Polyvinyl Alcohol Based Film Used for Liquid Detergent Capsules
- Application
- Effects of Laundering on Moisture Management and Air Permeability of Different Chitosan Treated Nylon 6,6 Elastane Fabrics Using EDTA and Triton X-100
- Application of Newly Synthesized Sulfobetaine Based on Sweet Almond Oil in Bath Liquids for Sensitive Skin
- Preparation of Silicone Emulsion Defoamer with Easy Separation of Magnetic Hydrophobic Nanoparticles
- Bentonite Suspension Filtration and its Electro-Kinetics in the Presence of Additives
- Novel surfactants
- Synthesis and Properties of Alkyl Bis-Guanidinium Acetates Surfactants
- Synthesis and Characterization of a Novel Class of Zwitterionic Fluorocarbon Surfactants Based on Perfluorobutyl
- Physical Chemistry
- Interfacial Behaviour of Saponin Based Surfactant for Potential Application in Cleaning
- Synthesis
- Preparation and the Foaming Activity Study of Hydroxymethyl Cetyltrimethyl Ammonium Chloride
Articles in the same Issue
- Contents
- Environmental Chemistry
- Biodegradability of Polyvinyl Alcohol Based Film Used for Liquid Detergent Capsules
- Application
- Effects of Laundering on Moisture Management and Air Permeability of Different Chitosan Treated Nylon 6,6 Elastane Fabrics Using EDTA and Triton X-100
- Application of Newly Synthesized Sulfobetaine Based on Sweet Almond Oil in Bath Liquids for Sensitive Skin
- Preparation of Silicone Emulsion Defoamer with Easy Separation of Magnetic Hydrophobic Nanoparticles
- Bentonite Suspension Filtration and its Electro-Kinetics in the Presence of Additives
- Novel surfactants
- Synthesis and Properties of Alkyl Bis-Guanidinium Acetates Surfactants
- Synthesis and Characterization of a Novel Class of Zwitterionic Fluorocarbon Surfactants Based on Perfluorobutyl
- Physical Chemistry
- Interfacial Behaviour of Saponin Based Surfactant for Potential Application in Cleaning
- Synthesis
- Preparation and the Foaming Activity Study of Hydroxymethyl Cetyltrimethyl Ammonium Chloride
