Startseite Sorption of cesium on Tamusu clay in synthetic groundwater with high ionic strength
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Sorption of cesium on Tamusu clay in synthetic groundwater with high ionic strength

  • Han Zhang , Yang Dong , Hanyi He , Honghui Li , Shuaiwei Zhao , Jun Liu , Meilan Jia , Jijun Yang , Yuanyou Yang EMAIL logo , Ning Liu und Jiali Liao EMAIL logo
Veröffentlicht/Copyright: 25. Juli 2019
Radiochimica Acta
Aus der Zeitschrift Radiochimica Acta Band 108 Heft 4

Abstract

The sorption behaviour of cesium on Tamusu clay was first investigated by batch experiments under synthetic groundwater and deionized water conditions. The results showed that the sorption could be well described by the pseud-second-order kinetic model or by the Freundlich isotherm model, and the Kd values decreased rapidly when temperature was greater than 328 K. However, the influence of initial cesium concentration, initial pH and Humic acid (HA) on the sorption behaviour in the synthetic groundwater exhibited a significant difference from those in the deionized water. In particular, the Kd value in the synthetic groundwater (5.47 mL/g) was much lower than that in the deionized water (58.97 mL/g). The SEM/EDS, effect of ion strength and pH-independent results in the synthetic groundwater indicated the cesium sorption on Tamusu clay was mainly involved in an ion exchange process. Additionally, the research reported in this work implies that the retardation of cesium on Tamusu clay was significantly lower than that on other clay rock in the world. The results suggest that the sorption behaviour of cesium or other nuclides on Tamusu clay should be evaluated in synthetic or actual groundwater but not in deionized water.

Keywords: High ionic strength; Tamusu clay; cesium; sorption; ion exchange

Funding source: National Natural Science Foundation of China

Award Identifier / Grant number: 21876123

Funding source: National Fund of China for Fostering Talents in Basic Science

Award Identifier / Grant number: J1210004

Funding statement: This work was supported by the National Natural Science Foundation of China, Funder Id: http://dx.doi.org/10.13039/501100001809 (Grant No. 21876123) and the National Fund of China for Fostering Talents in Basic Science (J1210004).

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Supplementary Material

The online version of this article offers supplementary material (https://doi.org/10.1515/ract-2019-3161).

Received: 2019-04-24
Accepted: 2019-06-22
Published Online: 2019-07-25
Published in Print: 2020-03-26

© 2020 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. Effect of ionic liquid on the extraction of uranium with pillar[5]arene-based phosphine oxide from nitric acid solutions
  3. Topological analysis of the layered uranyl compounds bearing slabs with UO2:TO4 ratio of 2:3
  4. Adsorption of uranium from its aqueous solutions using activated cellulose and silica grafted cellulose
  5. Uranium biosorption by immobilized active yeast cells entrapped in calcium-alginate-PVA- GO-crosslinked gel beads
  6. Sorption of cesium on Tamusu clay in synthetic groundwater with high ionic strength
  7. Optimization of 14C LSC measurement using CO2 absorption technique
  8. Targeting 5α-reductase with 99mTc labeled dutasteride derivatives for prostate imaging
  9. Changes in structural and optical properties due to γ-irradiation of MgO nanoparticles
  10. Radiation-induced free radicals from different milk powders and its possible use as radiation dosimeters
https://doi.org/10.1515/ract-2019-3161
Schlagwörter für diesen Artikel
High ionic strength; Tamusu clay; cesium; sorption; ion exchange

Artikel in diesem Heft

  1. Frontmatter
  2. Effect of ionic liquid on the extraction of uranium with pillar[5]arene-based phosphine oxide from nitric acid solutions
  3. Topological analysis of the layered uranyl compounds bearing slabs with UO2:TO4 ratio of 2:3
  4. Adsorption of uranium from its aqueous solutions using activated cellulose and silica grafted cellulose
  5. Uranium biosorption by immobilized active yeast cells entrapped in calcium-alginate-PVA- GO-crosslinked gel beads
  6. Sorption of cesium on Tamusu clay in synthetic groundwater with high ionic strength
  7. Optimization of 14C LSC measurement using CO2 absorption technique
  8. Targeting 5α-reductase with 99mTc labeled dutasteride derivatives for prostate imaging
  9. Changes in structural and optical properties due to γ-irradiation of MgO nanoparticles
  10. Radiation-induced free radicals from different milk powders and its possible use as radiation dosimeters
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