Startseite Production and separation of no-carrier-added 181−184Re radioisotopes from proton irradiated tungsten target
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Production and separation of no-carrier-added 181−184Re radioisotopes from proton irradiated tungsten target

  • Dibyasree Choudhury , Nabanita Naskar und Susanta Lahiri EMAIL logo
Veröffentlicht/Copyright: 19. April 2018

Abstract

Cross sections for the production of 181−184Re isotopes from proton irradiated thin natWO3 target at 20.9, 17.9, 14.9, 11.9 and 8.8 MeV projectile energies have been measured. An acceptable agreement between experimentally obtained data and available literature reports was found. The produced no-carrier-added (NCA) Re radionuclides have been separated from bulk tungsten target by liquid-liquid extraction (LLX) using trioctyl amine (TOA) and di-(2-ethylhexyl)phosphoric acid (HDEHP) dissolved in cyclohexane. A clear separation has been observed at 0.1 M and 1 M TOA with 0.1 M HNO3 concentration. However, by using HDEHP NCA Re radionuclides could not be separated from bulk W target without its contamination.

Acknowledgement

Authors are thankful to BARC-TIFR Pelletron staffs and TIFR target laboratory staffs for their cooperation during proton irradiation. We gratefully acknowledge the support through the research grants from SINP-DAE 12 Five year plan Trace, Ultratrace Analysis and Isotope Production (TULIP), Government of India. One of the authors, NN would like to thank University Grants Commission (UGC) for providing the necessary fellowship.

References

1. Hehrlein, C., Fehsenfeld, P.: Vascular Implant. U.S. Patent. Patent Number 5, 674, 177 (1997).Suche in Google Scholar

2. Dutta, B., Lahiri, S., Tomar, B.: Separation of no-carrier-added rhenium from bulk tantalum by precipitation technique. Sep. Sci. Technol. 48, 2468 (2013).10.1080/01496395.2013.807827Suche in Google Scholar

3. Tárkányi, F., Takács, S., Szelécsényi, F., Ditroi, F., Hermanne, A., Sonck, M.: Excitation functions of proton induced nuclear reactions on natural tungsten up to 34 MeV. Nucl. Instrum. Methods Phys. Res. Sect. B 252, 160 (2006).10.1016/j.nimb.2006.09.010Suche in Google Scholar

4. Zhang, X., Li, W., Fang, K., He, W., Sheng, R., Ying, D., Hu, W.: Excitation functions for natW(p,xn)181−186Re reactions and production of no-carrier-added 186Re via 186W(p,n)186Re reaction. Radiochim. Acta. 86, 11 (1999).10.1524/ract.1999.86.12.11Suche in Google Scholar

5. Khandaker, M. U., Uddin, M. S., Kim, K., Lee, M. W., Kim, K. S., Lee, Y. S., Kim, G. N., Cho, Y. S., Lee, Y. O.: Excitation functions of proton induced nuclear reactions on natW up to 40 MeV. Nucl. Instrum. Methods Phys. Res. B 266, 1021 (2008).10.1016/j.nimb.2008.02.037Suche in Google Scholar

6. Lapi, S., Mills, W. J., Wilson, J., McQuarrie, S., Publicover, J., Schueller, M., Schlyer, D., Ressler, J. J., Ruth, T. J.: Production cross sections of 181−186Re isotopes from proton bombardment of natural tungsten. Appl. Radiat. Isotopes 65, 345 (2007).10.1016/j.apradiso.2006.08.015Suche in Google Scholar

7. Scott, N. E., Cobble, J. W., Daly, P. J.: A comparison of reactions induced by medium-energy 3He and 4He ions in heavy target nuclei. Nucl. Phys. A 119, 131 (1968).10.1016/0375-9474(68)90810-5Suche in Google Scholar

8. Hermes, F., Jasper, E. W., Kurz, H. E., Mayer-Kuckuk, T.: Analysis of (particle,xn) reactions on tantalum and gold: (I) 181Ta (α,xn) excitation functions up to 104 MeV and equilibrium statistical model analysis. Nucl. Phys. A 228, 165 (1974).10.1016/0375-9474(74)90452-7Suche in Google Scholar

9. Dmitriev, P. P., Molin, G. A.: Yields of 181Re, 182mRe, 182Re 183Re 184mRe and 186Re in the bombardment of tungsten by protons and deuterons, and tantalum by α particles. At. Energ. 48, 122 (1980).10.1007/BF01121302Suche in Google Scholar

10. Ismail, M.: Measurements and analysis of the excitation function and isomeric cross-section ratios for α-induced reaction on Ir, Au, Re and Ta nuclei. Pranama-J. Phys. 50, 173 (1998).10.1007/BF02847528Suche in Google Scholar

11. Santos, W. M. S.; de Barros, S.; Suita, J. C.: Cross sections and thermonuclear reaction rates for 181Ta (α,n)184Re, 169Tm(α,n)172Lu, 191Ir(α,n)194Au and 197Au(α,n)200Tl. J. Phys. G 26, 301 (2000).10.1088/0954-3899/26/3/308Suche in Google Scholar

12. Tárkányi, F., Takács, S., Hermanne, A., Ditroi, F., Ando, L., Heselius, S-J., Bergman, J.: New experimental data on excitation functions for practical applications of alpha induced nuclear reactions on Ta up to 30 MeV. J. Nucl. Instrum. Methods Phys. Res. B 211, 22 (2003).10.1016/S0168-583X(03)01168-6Suche in Google Scholar

13. Dutta, B., Lahiri, S., Tomar, B.: Application of PEG based aqueous biphasic systems in extraction and separation of no-carrier-added 183Re from bulk tantalum. Radiochim. Acta. 101, 19 (2013).10.1524/ract.2013.1994Suche in Google Scholar

14. Dutta, B., Lahiri, S., Tomar, B.: Separation of no-carrier-added rhenium from bulk tantalum by the sodium malonate–PEG aqueous biphasic system. Appl. Radiat. Isotopes 84, 8 (2014).10.1016/j.apradiso.2013.10.014Suche in Google Scholar

15. Galan, P., Vejs, M.: Investigation of the decay 182Re +182W. Czech. J. Phys. B 22, 18 (1972).10.1007/BF01690942Suche in Google Scholar

16. Lahiri, S., Mukhopadhyay, K., Banerjee, K., Ramaswami, A., Manohar, S. B.: Separation of carrier-free 181Re production in 16O-irradiated thulium target. Appl. Radiat. Isotopes 55, 751 (2001).10.1016/S0969-8043(01)00131-2Suche in Google Scholar

17. Lahiri, S., Banerjee, K., Ramaswami, A., Manohar, S. B.: Production and separation of 183Os and 183Re from 7Li irradiated tantalum target. J. Nucl. Radiochem. Sci. 2, 50 (2001).Suche in Google Scholar

18. Maiti, M.: Probable nuclear reactions to produce proton rich rhenium radionuclides. J. Radioanal. Nucl. Chem. 290, 11 (2011).10.1007/s10967-011-1083-1Suche in Google Scholar

19. Richards, V., Rath, N., Lapi, S.: Production and separation of 186gRe from proton bombardment of 186WC. Nucl. Med. Biol. 42, 530 (2015).10.1016/j.nucmedbio.2015.03.001Suche in Google Scholar

20. Novgorodov, A. F., Bruchertseifer, F., Brockmann, J., Lebedev, N. A., Rösch, F.: Thermochromatographic separation of no-carrier-added 186Re or 188Re from tungsten targets relevant to nuclear medical applications. Radiochim. Acta 88, 163 (2000).10.1524/ract.2000.88.3-4.163Suche in Google Scholar

21. Kakavand, T., Mirzaii, M., Eslami, M., Kaleghi, M.: Production of 186gRe using low-energy protons. J. Radioanal. Nucl. Chem. 307, 253 (2016).10.1007/s10967-015-4146-xSuche in Google Scholar

22. Zhang, X., Li, Q., Li, W., Sheng, R., Shen, S.: Production of no-carrier-added 186Re via deuteron induced reactions on isotopically enriched 186W. Appl. Radiat. Isotopes 54, 92 (2001).10.1016/S0969-8043(00)00268-2Suche in Google Scholar

23. Brodskaya, G. A., Gureev, E. S., Gapurova, O. U.: Solvent extraction of tungsten with tri-n-octylamine from hydrogen peroxide solutions. Radiokhimiya 30, 769 (1988).Suche in Google Scholar

24. Gott, M. D., Ballard, B. D., Redman, L. N., Maassen, J. R., Taylor, W. A., Engle, J. W., Nortier, F. M., Birnbaum, E. R., John, K. D., Wilbur, D. S., Cutler, C. S., Ketring, A. R., Jurisson, S. S., Fassbender, M. E.: Radiochemical study of Re/W adsorption behavior on a strongly basic anion exchange resin. Radiochim. Acta 102, 325 (2014).10.1515/ract-2013-2144Suche in Google Scholar

25. Shigeta, N., Matsuoka, H., Osa, A., Koizumi, M., Izumo, M., Kobayashi, K., Hashimoto, K., Sekine, T., Lambrecht, R. M.: Production method of no-carrier-added 186Re. J. Radioanal. Nucl. Chem. 205, 85 (1996).10.1007/BF02040553Suche in Google Scholar

26. Fassbender, M., Ballard, B., Birnbaum, E., Engle, J., John, K., Maassen, J., Nortier, F., Lenz, J., Cutler, C., Ketring, A., Jurisson, S., Wilbur, D.: Proton irradiation parameters and chemical separation procedure for the bulk production of high-specific-activity 186gRe using WO3 targets. Radiochim. Acta 101, 339 (2013).10.1524/ract.2013.2031Suche in Google Scholar

27. Bidokhti, P., Sadeghi, M., Fateh, B., Matloobi, M., Aslani, G.: Nuclear data measurement of 186Re production via various reactions. Nucl. Eng. Technol. 42, 600 (2010).10.5516/NET.2010.42.5.600Suche in Google Scholar

28. Klofutar, C., Krasovec, F., Kodre, A.: Radiochemical separation of rhenium (VII) from tungsten (VI). J. Radioanal. Nucl. Chem. 5, 3 (1970).10.1007/BF02513694Suche in Google Scholar

29. Qaim, S. M.: Nuclear data relevant to cyclotron produced short-lived medical radioisotopes. Radiochim. Acta 30, 147 (1982).Suche in Google Scholar

30. Ziegler, J. F., Biersack, J. P., Littmark, U.: The Stopping and Ranges in Solids. Pergamon Press, New York (1985).Suche in Google Scholar

31. Sarri, S., Misaelides, P., Zamboulis, D., Gaona, X., Altmaier, M.: Rhenium(VII) and technetium(VII) separation from aqueous solutions using a polyethylene-epichlorohydrin resin. J. Radioanal. Nucl. Chem. 307, 681 (2016).10.1007/s10967-015-4213-3Suche in Google Scholar

32. Fang, D. W., Gu, X. J., Xiong, Y., Yue, S., Li, J., Zang, S. L.: Thermodynamics of solvent extraction of rhenium with trioctyl amine. J. Chem. Eng. Data 55, 424 (2010).10.1021/je900402wSuche in Google Scholar

33. Srivastava, R. R., Lee, J. C., Kim, M. S.: Complexation chemistry in liquid-liquid extraction of rhenium. J. Chem. Technol. Biotechnol. 90, 1752 (2015).10.1002/jctb.4707Suche in Google Scholar

34. Lassner, E., Schubert, W. D.: Tungsten: Properties, Chemistry, Technology of the Element, Alloys and Chemical Compounds. Kluwer Academic/Plenum Publishers, New York (1999).10.1007/978-1-4615-4907-9Suche in Google Scholar

Received: 2017-08-23
Accepted: 2018-03-16
Published Online: 2018-04-19
Published in Print: 2018-09-25

©2018 Walter de Gruyter GmbH, Berlin/Boston

Heruntergeladen am 21.10.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ract-2017-2869/html
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