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Model for the hydrodynamic dispersion of agglomerates incorporating thermoresponsive additives

  • Luciana Bava , Donald L. Feke , Ica Manas-Zloczower EMAIL logo und Stuart J. Rowan
Veröffentlicht/Copyright: 20. April 2011
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Journal of Polymer Engineering
Aus der Zeitschrift Band 31 Heft 1

Abstract

A phenomenological model for the hydrodynamic dispersion of silica agglomerates modified with a thermoresponsive hydrogel (poly-N-isopropylacrylamide, PNIPAM) is presented. The model well describes experimental observations of the dependence of the dispersion behavior on the presence of additives (water and PNIPAM hydrogels) and applied hydrodynamic stress. Most importantly, the thermosensitivity of the dispersion process is captured by characterizing the agglomerate structure and cohesive force at two different temperatures (above and below the hydrogel transition temperature). The transition in dispersion mechanism between rupture-like and erosion-like regimes with system temperature can also be accommodated within the model.

Published Online: 2011-04-20
Published in Print: 2011-04-01

©2011 by Walter de Gruyter Berlin New York

Heruntergeladen am 9.9.2025 von https://www.degruyterbrill.com/document/doi/10.1515/polyeng.2011.006/pdf
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