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Research and application advances in rubber flame retardant technology

  • Junbo Che , Xueqing Liu , Qihan Cui , Beizhi Chu , Yumin Xia und Yuwei Chen ORCID logo EMAIL logo
Veröffentlicht/Copyright: 1. Mai 2025
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Journal of Polymer Engineering
Aus der Zeitschrift Journal of Polymer Engineering Band 45 Heft 6

Abstract

Rubber materials, known for their excellent physical and mechanical properties, are widely used in products such as tires, shock absorbers, and conveyor belts. However, most rubbers have a low limiting oxygen index (LOI) and are considered flammable materials, which limit their application in certain fields. Preparing rubber materials with good flame retardancy has become a key research topic. This paper mainly discusses the intrinsic flame retardancy, inorganic filler flame retardancy, nano-technology flame retardancy, and polymer flame retardancy from the aspects of chemical grafting and physical blending. It summarizes the research progress in the field of flame-retardant rubber over the past five years and predicts the research trends of flame-retardant rubber materials.

Keywords: flame retardancy of rubber; chemical modification; physical blending; intrinsic flame retardancy
Corresponding author: Yuwei Chen, Key Laboratory of Advanced Rubber Material, Ministry of Education, Qingdao University of Science and Technology, Qingdao, 266042, China, E-mail:

Funding source: Opening Project of Key Laboratory of Advanced Rubber Material, Ministry of Education

Award Identifier / Grant number: XJCL2025002

Funding source: Shandong Provincial Natural Science Foundation for Youth Scholars

Award Identifier / Grant number: ZR2024ME159

Funding source: Program of National Key Research and Development of China

Award Identifier / Grant number: 2021YFB3700105

Award Identifier / Grant number: 2022YFB3603702

  1. Research ethics: Not applicable.

  2. Informed consent: Not applicable.

  3. Author contributions: B. C. and X. L. conceptualized the study and wrote the manuscript; Q. C. and B. C. analyzed the data; Y. X. and Y. C. guided and reviewed the manuscript. The authors have accepted responsibility for the entire content of this manuscript and approved its submission.

  4. Use of Large Language Models, AI and Machine Learning Tools: None declared.

  5. Conflict of interest: The authors declare that they have no conflict of interest.

  6. Research funding: This work was supported by the Shandong Provincial Natural Science Foundation for Youth Scholars (Project no. ZR2024ME159). and the Program of National Key Research and Development of China (2021YFB3700105, 2022YFB3603702). This work was also supported by the Opening Project of Key Laboratory of Advanced Rubber Material, Ministry of Education (XJCL2025002).

  7. Data availability: Not applicable.

References

1. Zhang, D. R.; Xin, Z. X. Modern Rubber Formula Design; Chemical Industry Press: Beijing, 2002.Suche in Google Scholar

2. Liao, X. X.; Tan, H. S. Research Progress on Flame-Retardant Rubber. Chin. J. Trop. Agric. 2004, 24 (3), 70–75. https://doi.org/10.3969/j.issn.1009-2196.2004.03.014.Suche in Google Scholar

3. Huang, L.; Hu, H.; Wang, B.; Huang, J. F.; Cheng, G. S.; Zheng, K. H. Advance in the Research of Low-Smoke and Non-halogen Flame-Retardants. Guangdong Chem. Ind. 2011, 38 (8), 68–69.Suche in Google Scholar

4. Yang, H. Y.; Xiao, P.; Hu, B. H. Research Progress on Halogen-free Flame Retardants. Plast. Ind. 2006, 34 (33), 69–72.Suche in Google Scholar

5. Ye, X.; Wang, Y.; Zhao, Z.; Yan, H. A Novel Hyperbranched Poly (Phosphorodiamidate) with High Expansion Degree and Carbonization Efficiency Used for Improving Flame Retardancy of APP/PP Composites. Polym. Degrad. Stab. 2017, 142, 29–41. https://doi.org/10.1016/j.polymdegradstab.2017.05.023.Suche in Google Scholar

6. Yang, Y. J. Design of Wastewater Treatment Engineering for Chloroprene Rubber Production; Shanxi University: Xi’an, 2018.Suche in Google Scholar

7. Bao, Y. Preparation Methods and Research Progress of Fluororubber. Liaoning Chem. Ind. 2024, 53, 458–460; https://doi.org/10.14029/j.cnki.issn1004-0935.2024.03.032.Suche in Google Scholar

8. Jones, K. P.; Allen, P. W. Historical Development of the World Rubber Industry. In Natural Rubber: Biology, Cultivation and Technology; Sethuraj, M. R.; Mathew, N. M., Eds.; Elsevier: Amsterdam, 1992; pp. 1–25.10.1016/B978-0-444-88329-2.50007-6Suche in Google Scholar

9. Cornish, K. Similarities and Differences in Rubber Biochemistry among Plant Species. Phytochemistry 2001, 57 (7), 1123–1134. https://doi.org/10.1016/S0031-9422(01)00097-8.Suche in Google Scholar PubMed

10. Han, H. H. CHEN Yun and the Rubber Production of New China. Contemp. China History Stud. 2005 (4), 69–74. https://doi.org/10.3969/j.issn.1005-4952.2005.04.016.Suche in Google Scholar

11. Bsantley, H. L.; Fang, H. B. Prospects of Natural Rubber and Synthetic Rubber in Tire Industry. Rubber Transl. 1982, 4, 3–6.Suche in Google Scholar

12. Fukahori, Y. Mechanism of the Self-Reinforcement of Cross-Linked NR Generated through the Strain-Induced Crystallization. Polymer 2010, 51 (7), 1621–1631. https://doi.org/10.1016/j.polymer.2010.01.059.Suche in Google Scholar

13. Xu, J. Study on the Influence of Fillers on the Thermal Properties of Silicone Rubber. MA Thesis; Hangzhou Normal University: Hangzhou, 2016.Suche in Google Scholar

14. Zhuo, J.; Dong, J.; Jiao, C.; Chen, X. Synergistic Effects between Red Phosphorus and Alumina Trihydrate in Flame Retardant Silicone Rubber Composites. Plast. Rubber Compos. 2013, 42 (6), 239–243. https://doi.org/10.1179/146580113X13650753142022.Suche in Google Scholar

15. Qi, J.; Wen, Q.; Zhu, J.; He, T. Synthesis of a Novel Intumescent Flame Retardant Based on Phosphorus, Nitrogen, and Silicone, and Application in VMQ. J. Therm. Anal. Calorim. 2019, 137, 1549–1557. https://doi.org/10.1007/s10973-019-08049-3.Suche in Google Scholar

16. Pan, Y.; Liu, C.; Wang, J.; Song, S. Preparation of a Novel Synergistic Flame Retardant and its Application in Silicone Rubber Composites. Fire Mater. 2020, 44 (8), 1135–1148. https://doi.org/10.1002/fam.2924.Suche in Google Scholar

17. Fang, S.; Hu, Y.; Song, L.; Zhan, J.; He, Q. Mechanical Properties, Fire Performance and Thermal Stability of Magnesium Hydroxide Sulfate Hydrate Whiskers Flame Retardant Silicone Rubber. J. Mater. Sci. 2008, 43, 1057–1062. https://doi.org/10.1007/s10853-007-2241-2.Suche in Google Scholar

18. Liang, S.; Wang, F.; Liang, J.; Chen, S.; Jiang, M. Synergistic Effect between Flame Retardant Viscose and Nitrogen-Containing Intrinsic Flame-Retardant Fibers. Cellulose 2020, 27, 6083–6092. https://doi.org/10.1007/s10570-020-03203-9.Suche in Google Scholar

19. Zhang, X. W.; Jiang, H. W. Research on Halogen-free Flame-Retardant Silicone Rubber with High-Temperature Resistance. Rubber Ind. 2010, 57 (5), 286–290. https://doi.org/10.3969/j.issn.1000-890X.2010.05.005.Suche in Google Scholar

20. Adner, D.; Helmy, M.; Otto, T.; Schellenberg, J.; Schadewald, A. A Macromolecular Halogen-free Flame Retardant and its Effect on the Properties of Thermoplastic Polyesters. Fire Mater. 2019, 43 (2), 169–174. https://doi.org/10.1002/fam.2682.Suche in Google Scholar

21. Vini, R.; Thenmozhi, S.; Murugavel, S. Synthesis, Characterization and Thermal Degradation Kinetics of Azomethine-Based Halogen-free Flame-Retardant Polyphosphonates. High Perform. Polym. 2019, 31 (1), 86–96. https://doi.org/10.1177/0954008317752073.Suche in Google Scholar

22. Ou, Y. X.; Li, J. J. Flame Retardants: Performance, Manufacturing, and Applications; Ordnance Industry Press: Beijing, 1997.Suche in Google Scholar

23. Yu, Y. Z.; Wu, Q. H.; Ge, S. C. Flame Retardant Materials Handbook; Mass Publishing House: Beijing, 1997.Suche in Google Scholar

24. Xu, Y. L.; Wang, Y. H. Practical Flame Retardant Technology for Polymer Materials; Chemical Industry Press: Beijing, 1994.Suche in Google Scholar

25. Marosi, G.; Marton, A.; Anna, P.; Bertalan, G.; Marosföi, B.; Szép, A. Ceramic Precursor in Flame Retardant Systems. Polym. Degrad. Stab. 2002, 77 (2), 259–265. https://doi.org/10.1016/S0141-3910(02)00057-5.Suche in Google Scholar

26. Marosi, G.; Anna, P.; Marton, A.; Bertalan, G.; Bota, A.; Toth, A.; Mohai, M.; Racz, I. Flame-retarded Polyolefin Systems of Controlled Interphase. Polym. Adv. Technol. 2002, 13 (10-12), 1103–1111. https://doi.org/10.1002/pat.284.Suche in Google Scholar

27. Nontasak, W.; Thongnuanchan, B.; Ninjan, R.; Lopattananon, N.; Wannavilai, P.; Nakason, C. Fire-retardant Wood Coating Based on Natural Rubber Bearing Methacrylic Functionality. J. Polym. Eng. 2021, 41 (1), 44–53. https://doi.org/10.1515/polyeng-2020-0092.Suche in Google Scholar

28. Zhou, M.; Liu, Y.; Yao, D.; Jiang, Y.; Zhang, X.; Wang, D. Y.; Wang, N. Promotion of the Flame Retardancy of 9, 10-Dihydro-9-Oxa-10-Phosphaphenanthrene-10-Oxide Grafted Natural Rubber Using Expandable Graphite. Arab. J. Chem. 2021, 14 (3), 102980. https://doi.org/10.1016/j.arabjc.2020.102980.Suche in Google Scholar

29. Wang, F. Y. Research on Flame retardant Modification and Mechanism of EPDM Rubber Flame Retardant Material. MA Thesis; Qingdao University of Science and Technology: Qingdao, 2023.Suche in Google Scholar

30. Li, L.; Liu, X.; Shao, X.; Jiang, L.; Huang, K.; Zhao, S. Synergistic Effects of a Highly Effective Intumescent Flame Retardant Based on Tannic Acid Functionalized Graphene on the Flame Retardancy and Smoke Suppression Properties of Natural Rubber. Compos. Part A Appl. Sci. Manuf. 2020, 129, 105715. https://doi.org/10.1016/j.compositesa.2019.105715.Suche in Google Scholar

31. Wang, J.; Wang, X.; Zhou, Z.; Liu, X.; Xu, M.; Zhao, F.; Zhao, F.; Li, S.; Liu, Z.; Li, L.; Zhao, S. Flame-retardant Effect of Tannic Acid-Based Intumescent Fire-Retardant Applied on Flammable Natural Rubber. RSC Adv. 2022, 12 (46), 29928–29938. https://doi.org/10.1039/D2RA04682B.Suche in Google Scholar

32. Li, L.; Liu, X.; Huang, K.; Wang, Y.; Zheng, X.; Wang, J.; Du, Y.; Jiang, L.; Zhao, S. A Facile Strategy to Fabricate Intumescent Fire-Retardant and Smoke Suppression Protective Coatings for Natural Rubber. Polym. Test. 2020, 90, 106689. https://doi.org/10.1016/j.polymertesting.2020.106689.Suche in Google Scholar

33. Qu, Q.; Xu, J.; Wang, H.; Yu, Y.; Dong, Q.; Zhang, X.; He, Y. Carbon Nanotube-Based Intumescent Flame Retardants Achieve High-Efficiency Flame Retardancy and Simultaneously Avoid Mechanical Property Loss. Polymers 2023, 15 (6), 1406. https://doi.org/10.3390/polym15061406.Suche in Google Scholar PubMed PubMed Central

34. Wu, C.; Wang, X.; Zhang, J.; Cheng, J.; Shi, L. Microencapsulation and Surface Functionalization of Ammonium Polyphosphate via In-Situ Polymerization and Thiol-Ene Photograted Reaction for Application in Flame-Retardant Natural Rubber. Ind. Eng. Chem. Res. 2019, 58 (37), 17346–17358. https://doi.org/10.1021/acs.iecr.9b02464.Suche in Google Scholar

35. Cheng, J.; Niu, S.; Zhao, Y.; Liu, Y.; Kang, M.; Guan, Y.; Zhang, F. The Flame Retardant and Thermal Conductivity Properties of High Thermal Conductivity Expandable Graphite Microcapsule Filled Natural Rubber Composites. Constr. Build. Mater. 2022, 318, 125998. https://doi.org/10.1016/j.conbuildmat.2021.125998.Suche in Google Scholar

36. Wang, N.; Zhou, M.; Zhang, J.; Fang, Q. Modified Boron Nitride as an Efficient Synergist to Flame Retardant Natural Rubber: Preparation and Properties. Polym. Adv. Technol. 2020, 31 (9), 1887–1895. https://doi.org/10.1002/pat.4833.Suche in Google Scholar

37. Su, X.; Chai, W.; Xia, Y.; Gao, M.; Li, Y.; Tang, Z.; Zhang, Z.; Han, Z.; Zheng, Z. Bio-inspired Construction of Hydrophobic, Bio-Based and Halogen-free Flame-Retardant Strategy for Silicone Rubber. J. Therm. Anal. Calorim. 2023, 148 (19), 9857–9874. https://doi.org/10.1007/s10973-023-12371-2.Suche in Google Scholar

38. Peng, H.; Yang, Q. Investigation on the Effect of Supported Synergistic Catalyst with Intumescent Flame Retardant in Polypropylene. J. Polym. Eng. 2021, 41, 281–288. https://doi.org/10.1515/polyeng-2020-0225.Suche in Google Scholar

39. Wu, P.; Peng, Y.; Zhang, X.; Zhang, G.; Ran, J.; Xu, M. Unsaturated Polyester Resin Modified with a Novel Reactive Flame Retardant: Effects on Thermal Stability and Flammability. J. Polym. Eng. 2022, 42, 818–826. https://doi.org/10.1515/polyeng-2021-0317.Suche in Google Scholar

40. Zhou, C.; Wang, J.; Li, J.; Shi, J. Thermal Aging Properties of Flame Retardant Silicone Rubber Based on Melamine Cyanurate. J. Appl. Polym. Sci. 2021, 138 (9), 49919. https://doi.org/10.1002/app.49919.Suche in Google Scholar

41. Lv, X.; Wu, X.; Cheng, P.; Wang, H. Flame-Retardant Natural Rubber. CN, 201910940222; 2019.Suche in Google Scholar

42. Mao, C. H.; Chen, S. X.; Zhou, C. Q.; Jin, Q.; Zhang, S. Flame-Retardant and Anti-static Rubber for Shoe Edges and its Preparation Method. CN, 202011202747 (7), 2021.Suche in Google Scholar

43. Wang, N.; Liu, H.; Zhang, J.; Zhang, M.; Fang, Q.; Wang, D. Synergistic Effect of Graphene Oxide and Boron-Nitrogen Structure on Flame Retardancy of Natural Rubber/IFR Composites. Arab. J. Chem. 2020, 13 (8), 6274–6284. https://doi.org/10.1016/j.arabjc.2020.05.016.Suche in Google Scholar

44. Xu, W.; Wu, X.; Wen, Q.; Li, S.; Song, Y.; Shi, B. Effects of Collagen Fiber Addition on the Combustion and Thermal Stability of Natural Rubber. J. Leather Sci. Eng. 2020, 2, 1–10. https://doi.org/10.1186/s42825-020-00040-1.Suche in Google Scholar

45. Yang, J.; Ma, W.; Hu, D.; Zhang, D.; Wu, L.; Yang, B.; Zhang, S. Facile Preparation and Flame Retardancy Mechanism of Cyclophosphazene Derivatives for Highly Flame-Retardant Silicone Rubber Composites. J. Appl. Polym. Sci. 2021, 138 (17), 50297. https://doi.org/10.1002/app.50297.Suche in Google Scholar

46. Jiang, G.; Zhou, H.; Liao, K. Effect of B Enzotriazole-Protected Platinum Catalyst on Flame Retardancy and Ceramic-Forming Property of Ceramifiable Silicone Rubber. Polym. Adv. Technol. 2020, 31 (11), 2687–2700. https://doi.org/10.1002/pat.4995.Suche in Google Scholar

47. Battig, A.; Fadul, N. A. R.; Frasca, D.; Schulze, D.; Schartel, B. Multifunctional Graphene Nanofiller in Flame Retarded Polybutadiene/chloroprene/carbon Black Composites. e-Polymers 2021, 21 (1), 244–262. https://doi.org/10.1515/epoly-2021-0026.Suche in Google Scholar

48. Xu, W. C.; Zheng, W. C.; Zhao, L.; Wu, H. T.; Wu, Y. X.; Li, H. L.; Zhang, H.; Long, H. M. Preparation and Properties of Flame-Retardant Rubber Composites Based on Steel Slag Filler. J. Iron Steel Res. Int. 2023, 30 (7), 1334–1341. https://doi.org/10.1007/s42243-022-00901-5.Suche in Google Scholar

49. Yu, J.; Hong, L.; Qu, L. Study on Char Reinforcing of Different Inorganic Fillers for Expandable Fire Resistance Silicone Rubber. J. Appl. Polym. Sci. 2021, 138 (28), 50675. https://doi.org/10.1002/app.50675.Suche in Google Scholar

50. Du, W.; Yin, C.; Huang, H.; Ge, X. Vinyl-functionalized Polyborosiloxane for Improving Mechanical and Flame-Retardancy Performances of Silicone Rubber Foam Composites. Polym. Int. 2022, 71 (1), 124–131. https://doi.org/10.1002/pi.6292.Suche in Google Scholar

51. Parvathi, K.; Ramesan, M. High Performance Chlorinated Natural Rubber/zinc Ferrite Nanocomposite Prepared through Industrial Compounding Technique. Polym. Bull. 2023, 80 (3), 3165–3182. https://doi.org/10.1007/s00289-022-04201-6.Suche in Google Scholar

52. Younis, A.; El-Wakil, A. Improvement of Mechanical and Flame Retardant Properties of Natural Rubber by Eco-Friendly Watermelon Peel and Crumb Rubber. Fibers Polym. 2021, 22 (5), 1237–1246. https://doi.org/10.1007/s12221-021-0497-9.Suche in Google Scholar

53. Wang, Y.; Liu, T.; Zhang, H.; Luo, N.; Chen, F.; Fu, Q. Effect of Spherical Alumina Crystalline Phase Content and Particle Size Distribution Polydispersity on the Properties of Silicone Rubber Composites. Compos. Sci. Technol. 2023, 243, 110273. https://doi.org/10.1016/j.compscitech.2023.110273.Suche in Google Scholar

54. Kang, F.; Tu, J.; Zhao, H.; Bai, Z.; Zhang, T. Flame Retardancy and Smoke Suppression of Silicone Rubber Foam with Microencapsulated Sepiolite and Zinc Borate. Polymers 2023, 15 (13), 2927. https://doi.org/10.3390/polym15132927.Suche in Google Scholar PubMed PubMed Central

55. Song, W.; Lan, Y.; Wang, J.; Zhang, C. Synergistic Effect of Diatomite and Intumescent Flame Retardant on Flame Retardant Properties of Silicone Rubber Composites. J. Rubber Res. 2021, 24, 489–499. https://doi.org/10.1007/s42464-021-00116-5.Suche in Google Scholar

56. Du, W.; Zhang, Z.; Huang, H.; Yin, C. Flame Retardancy and Mechanical Properties of Silicone Rubber Foam Composite Reinforced with ZnNiAl Layered Double Hydroxides. J. Polym. Res. 2023, 30 (10), 384. https://doi.org/10.1007/s10965-023-03768-6.Suche in Google Scholar

57. Abdelkhalik, A.; Makhlouf, G.; Abdel-Hakim, A. Fire Behavior of Natural Rubber Filled with Intumescent Flame Retardant Containing Graphite. J. Vinyl Addit. Technol. 2020, 26 (2), 155–164. https://doi.org/10.1002/vnl.21728.Suche in Google Scholar

58. Liu, C.; Wang, J.; Zhao, W.; Song, S. Application Properties of a Cyclophosphamide-Core Polyamidoamine Dendritic Montmorillonite in Natural Rubber Composites. Polym. Polym. Compos. 2020, 28 (5), 356–366. https://doi.org/10.1177/0967391119879289.Suche in Google Scholar

59. Chen, X.; Qiu, T. Natural Rubber Composites Reinforced with Basic Magnesium Oxysulfate Whiskers: Processing and Ultraviolet Resistance/flame Retardant Properties. Polym. Test. 2020, 81, 106271. https://doi.org/10.1016/j.polymertesting.2019.106271.Suche in Google Scholar

60. Pang, Q.; Kang, F.; Deng, J.; Lei, L.; Lu, J.; Shao, S. Flame Retardancy Effects between Expandable Graphite and Halloysite Nanotubes in Silicone Rubber Foam. RSC Adv. 2021, 11 (23), 13821–13831. https://doi.org/10.1039/D1RA01409A.Suche in Google Scholar PubMed PubMed Central

61. Pang, Q.; Deng, J.; Kang, F.; Shao, S. Effect of Expandable Graphite/Hexaphenoxycyclotriphosphazene Beads on the Flame Retardancy of Silicone Rubber Foam. Mater. Res. Express 2020, 7 (5), 055308. https://doi.org/10.1088/2053-1591/ab9250.Suche in Google Scholar

62. Li, Z.; Cheng, X.; Liu, Y.; Liu, H.; Jiang, Y.; Wang, N. Intumescent Flame Retardancy and Smoke Suppression of Eucommia Ulmoides Gum/natural Rubber Blends Based on Synergistic G-C3n4@ Fe3O4 Nanocomposites. RSC Adv. 2022, 12 (34), 21704–21712. https://doi.org/10.1039/D2RA03377A.Suche in Google Scholar

63. Wang, C.; Shen, J.; Hao, Z.; Luo, Z.; Shen, Z.; Li, X.; Yang, L.; Zhou, Q. Flexible Silicone Rubber/carbon Fiber/nano-Diamond Composites with Enhanced Thermal Conductivity via Reducing the Interface Thermal Resistance. J. Polym. Eng. 2022, 42, 544–553. https://doi.org/10.1515/polyeng-2021-0301.Suche in Google Scholar

64. Muralidharan, N. D.; Subramanian, J.; Rajamanickam, S. K.; Gopalan, V. An Experimental Investigation of Flame Retardancy and Thermal Stability of Treated and Untreated Kenaf Fiber Reinforced Epoxy Composites. J. Polym. Eng. 2023, 43, 865–874. https://doi.org/10.1515/polyeng-2023-0128.Suche in Google Scholar

65. Song, J.; Zhang, X.; Wang, J.; Sun, J.; Shi, A. Ceramifiable Flame-Retarded Silicone Rubber Composites Based on Novel Phosphorus/Nitrogen/Silicon-Containing Flame Retardants. Silicon 2023, 15 (11), 5001–5011. https://doi.org/10.1007/s12633-023-02416-4.Suche in Google Scholar

66. Hu, S.; Tan, Z. W.; Chen, F.; Li, J. G.; Shen, Q.; Huang, Z. X.; Zhang, L. M. Flame-retardant Properties and Synergistic Effect of Ammonium Polyphosphate/aluminum Hydroxide/mica/silicone Rubber Composites. Fire Mater. 2020, 44 (5), 673–682. https://doi.org/10.1002/fam.2831.Suche in Google Scholar

67. Li, J.; Yan, Z.; Liu, M.; Han, X.; Lu, T.; Liu, R.; Zhao, S.; Lv, Q.; Li, B.; Zhao, S.; Wang, H. Triple Silicon, Phosphorous, and Nitrogen-Grafted Lignin-Based Flame Retardant and its Vulcanization Promotion for Styrene Butadiene Rubber. ACS Omega 2023, 8 (24), 21549–21558. https://doi.org/10.1021/acsomega.3c00714.Suche in Google Scholar PubMed PubMed Central

68. Yao, L.; Xu, W.; Ding, D.; Zhou, Y.; Zhang, Y. Core-shell Carbon Nanotubes/cobalt Copper Hydroxide Hybrid/silicone Rubber Composite: Flame Retardancy and Antistatic Properties. Iran. Polym. J. 2023, 32 (5), 557–570. https://doi.org/10.1007/s13726-023-01145-0.Suche in Google Scholar

69. Sajith, T.; Praveen, K.; Thomas, S.; Ahmad, Z.; Kalarikkal, N.; Dhanani, C.; Maria, H. J. Effect of HAF Carbon Black on Curing, Mechanical, Thermal and Neutron Shielding Properties of Natural Rubber-Low-Density Polyethylene Composites. Prog. Nucl. Energy 2021, 141, 103940. https://doi.org/10.1016/j.pnucene.2021.103940.Suche in Google Scholar

70. Abdulrahman, S. T.; Ahmad, Z.; Thomas, S.; Maria, H. J.; Rahman, A. A. Viscoelastic and Thermal Properties of Natural Rubber Low-Density Polyethylene Composites with Boric Acid and Borax. J. Appl. Polym. Sci. 2020, 137 (44), 49372. https://doi.org/10.1002/app.49372.Suche in Google Scholar

71. Walong, A.; Thongnuanchan, B.; Sakai, T.; Lopattananon, N. Influence of Silicon Dioxide Addition and Processing Methods on Structure, Thermal Stability and Flame Retardancy of EVA/NR Blend Nanocomposite Foams. Prog. Rubber Plast. Recy. Technol. 2021, 37 (1), 49–65. https://doi.org/10.1177/1477760620953437.Suche in Google Scholar

72. Walong, A.; Thongnuanchan, B.; Uthaipan, N.; Sakai, T.; Lopattananon, N. Enhancing Cellular Structure, Mechanical Properties, Thermal Stability and Flame Retardation of EVA/NR Blend Nanocomposite Foams by Silicon Dioxide-Based Flame Retardant. Prog. Rubber Plast. Recy. Technol. 2022, 38 (1), 70–88. https://doi.org/10.1177/14777606211042028.Suche in Google Scholar

73. Sawangpet, K.; Walong, A.; Thongnuanchan, B.; Kaesaman, A.; Sakai, T.; Lopattananon, N. Foaming and Physical Properties, Flame Retardancy, and Combustibility of Polyethylene Octene Foams Modified by Natural Rubber and Expandable Graphite. J. Vinyl Addit. Technol. 2020, 26 (4), 423–433. https://doi.org/10.1002/vnl.21757.Suche in Google Scholar

74. Lu, Y.; Wang, J.; Zhang, C. Preparation of a Novel Flame Retardant Based on Diatomite/polyethyleneimine Modified MWCNT for Applications in Silicone Rubber Composites. J. Rubber Res. 2021, 24, 137–146. https://doi.org/10.1007/s42464-020-00079-z.Suche in Google Scholar

75. Chai, W.; Su, X.; Xia, Y.; Liao, C.; Gao, M.; Li, Y.; Zheng, Z. Fabrication of Ni-Doped Synergistic Intumescent Flame-Retarding Silicone Rubber System with Superior Flame Retardancy and Water Resistance. J. Therm. Anal. Calorim. 2023, 148 (5), 1827–1839. https://doi.org/10.1007/s10973-022-11865-9.Suche in Google Scholar

76. Zirnstein, B.; Schulze, D.; Schartel, B. The Impact of Polyaniline in Phosphorus Flame Retardant Ethylene-Propylene-Diene-Rubber (EPDM). Thermochim. Acta 2019, 673, 92–104. https://doi.org/10.1016/j.tca.2019.01.019.Suche in Google Scholar
Received: 2025-01-15
Accepted: 2025-03-25
Published Online: 2025-05-01
Published in Print: 2025-07-28

© 2025 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. Material Properties
  3. Impact behavior of shear thickening fluid treated CFRP by using SHPB technique
  4. Soft materials containing dynamic C–N bonds for fluorescence visualization
  5. Preparation and Assembly
  6. Advanced polymer nanocomposites in packaging applications
  7. Research and application advances in rubber flame retardant technology
  8. Silicone- and ester-containing polyurethanes with improved thermal stability
  9. Engineering and Processing
  10. Experimental study on the usage of biopolymer sodium alginate as drainage barrier in liners
https://doi.org/10.1515/polyeng-2025-0004
Schlagwörter für diesen Artikel
flame retardancy of rubber; chemical modification; physical blending; intrinsic flame retardancy

Artikel in diesem Heft

  1. Frontmatter
  2. Material Properties
  3. Impact behavior of shear thickening fluid treated CFRP by using SHPB technique
  4. Soft materials containing dynamic C–N bonds for fluorescence visualization
  5. Preparation and Assembly
  6. Advanced polymer nanocomposites in packaging applications
  7. Research and application advances in rubber flame retardant technology
  8. Silicone- and ester-containing polyurethanes with improved thermal stability
  9. Engineering and Processing
  10. Experimental study on the usage of biopolymer sodium alginate as drainage barrier in liners
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Heruntergeladen am 28.11.2025 von https://www.degruyterbrill.com/document/doi/10.1515/polyeng-2025-0004/html?lang=de
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