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Molecularly imprinted polymer for the selective removal of direct violet 51 from wastewater: synthesis, characterization, and environmental applications

  • Maaz Khan , Ilyas Ahmad , Shahab Khan ORCID logo EMAIL logo , Alam Zeb , Mohamed F. Elsadek , Sanjaykumar Patel , Khalid S. Al-Numair , Ankur Kulshreshta and Hameed U. Rahman
Published/Copyright: October 15, 2024
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Journal of Polymer Engineering
From the journal Journal of Polymer Engineering Volume 44 Issue 10

Abstract

Molecularly imprinted polymers (MIPs) are a diverse class of materials designed for selective molecular recognition. These polymers are synthesized with particular binding sites that are suited to a target molecule or a collection of structurally similar molecules through the use of a process called molecular imprinting. MIPs were synthesized in this work to specifically remove direct violet 51 from occupational leachates and aqueous solutions. Methacrylic acid functioned as the functional monomer, ethylene glycol dimethacrylate (EGDMA) as the cross-linker, 2,2-azobisisobutyronitrile (AIBN) as the initiator, and alcohol as a porogenic solvent. To improve the dye removal effectiveness, a number of factors were optimized, including time, pH, analyte concentrations, and MIP/NIP dosages. The findings showed that MIPs had a much greater capacity for direct violet 51 adsorption than nonimprinted polymers (NIPs), with MIP adsorption capacity reaching 42.553 mg g−1 and NIP adsorption capacity reaching 7 mg g−1. The pseudo 2nd-order model described the adsorption kinetics, and the rate constant (K 2) for MIPs was found to be 0.00251 mg g−1 min. Furthermore, a high rebinding efficiency of 94 % was observed when the selectivity of MIPs for direct violet 51 was assessed against structurally similar templates.

Keywords: MIP; NIP; direct violet 51; UV visible spectrometer; FTIR; SEM
Corresponding author: Shahab Khan, Department of Chemistry, University of Malakand, 18800 Chakdara, Dir Lower, Khyber Pakhtunkhwa, Pakistan, E-mail:

Funding source: Researchers Supporting Project, King Saud University

Award Identifier / Grant number: RSP2024R349

  1. Research ethics: Not applicable.

  2. Informed consent: Not applicable.

  3. Author contributions: Maaz Khan and Ilyas Ahmad wrote the initial draft of the manuscript. Alamzeb performed the SEM and FTIR characterization. Figure modifications, graphics, and quality enhancements were made by Ankur Kulshreshta. The scheme of the study was designed and supervised by Shahab Khan. Sanjaykumar Patel helped with the revision of the manuscript, answered criticisms by reviewers and editors, verified the integrity and scope of the work, and improved language proficiency. References, Tables sitting, and validation were done by Hameed Ur Rahman. Mohamed Farouk Elsadek and Khalid S. Al-Numair helped with providing research instruments and chemicals, finalized the manuscript, corrected the grammar, and approved the final manuscript version along with financial support. The authors have accepted responsibility for the entire content of this manuscript and approved its submission.

  4. Use of Large Language Models, AI and Machine Learning Tools: None declared.

  5. Conflict of interest: Not applicable.

  6. Research funding: The authors would like to extend their sincere appreciation for funding this work through the Researchers Supporting Project number (RSP2024R349), King Saud University, Riyadh, Saudi Arabia.

  7. Data availability: Not applicable.

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Received: 2024-06-03
Accepted: 2024-08-11
Published Online: 2024-10-15
Published in Print: 2024-11-26

© 2024 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. Material Properties
  3. Effect of epoxidized soybean oil on melting behavior of poly(l-lactic acid) and poly(d-lactic acid) blends after isothermal crystallization
  4. An experimental investigation on the influence of pore foaming agent particle size on cell morphology, hydrophobicity, and acoustic performance of open cell poly (vinylidene fluoride) polymeric foams
  5. Reinforcement of recycled polypropylene by nano lanthana with improved thermal, mechanical and antimicrobial properties
  6. Microstructure-mechanical property relationships of polymer nanocomposite reinforced with lyophilized montmorillonite/carbon nanotubes hybrid particles
  7. Preparation and Assembly
  8. Preparation and dynamic simulation of a hemin reversible associated copolymer with self-healing properties
  9. Molecularly imprinted polymer for the selective removal of direct violet 51 from wastewater: synthesis, characterization, and environmental applications
  10. Engineering and Processing
  11. Comparative analysis of 3D-printed and freeze-dried biodegradable gelatin methacrylate/ poly‐ε‐caprolactone- polyethylene glycol-poly‐ε‐caprolactone (GelMA/PCL-PEG-PCL) hydrogels for bone applications
  12. Thermally conductive and electrically insulated DGEBA-epoxy nano-composite fabricated by integrating GO/h-BN and rGO/h-BN hybrid for thermal management applications: a comparative analysis
https://doi.org/10.1515/polyeng-2024-0116
Keywords for this article
MIP; NIP; direct violet 51; UV visible spectrometer; FTIR; SEM

Articles in the same Issue

  1. Frontmatter
  2. Material Properties
  3. Effect of epoxidized soybean oil on melting behavior of poly(l-lactic acid) and poly(d-lactic acid) blends after isothermal crystallization
  4. An experimental investigation on the influence of pore foaming agent particle size on cell morphology, hydrophobicity, and acoustic performance of open cell poly (vinylidene fluoride) polymeric foams
  5. Reinforcement of recycled polypropylene by nano lanthana with improved thermal, mechanical and antimicrobial properties
  6. Microstructure-mechanical property relationships of polymer nanocomposite reinforced with lyophilized montmorillonite/carbon nanotubes hybrid particles
  7. Preparation and Assembly
  8. Preparation and dynamic simulation of a hemin reversible associated copolymer with self-healing properties
  9. Molecularly imprinted polymer for the selective removal of direct violet 51 from wastewater: synthesis, characterization, and environmental applications
  10. Engineering and Processing
  11. Comparative analysis of 3D-printed and freeze-dried biodegradable gelatin methacrylate/ poly‐ε‐caprolactone- polyethylene glycol-poly‐ε‐caprolactone (GelMA/PCL-PEG-PCL) hydrogels for bone applications
  12. Thermally conductive and electrically insulated DGEBA-epoxy nano-composite fabricated by integrating GO/h-BN and rGO/h-BN hybrid for thermal management applications: a comparative analysis
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