Abstract
Electromagnetic cooperative strategy has been proved to be an effective approach that can significantly decrease the matching thickness required for reflection loss. However, improving the electromagnetic wave (EMW) absorbing effectiveness with low matching thickness remains challenging for current single-phase absorbing materials. A layer-by-layer construction design is used in our study via a combination with iso-butyl isoprene rubber (IIR) and mixed polyurethane (MPU) as the matrix, with the single-wall carbon nanotubes (SWCNTs) and magnetic powder as fillers. This bilayer composite design resulted in a decrease in matching thickness and a shift in absorption bandwidth to higher frequencies by 40 %–50 %. Furthermore, the trilayer structure of MPU/IIR/MPU was found to stabilize permeability, enhance the thermal stability of the magnetism and improve the shielding effectiveness significantly. The thickness corresponding minimum absorption loss of the trilayer composites decreased and the absorption bandwidth of −10 dB widened by 50 % from 8.2 GHz–9.5 GHz to 10.2 GHz–12.4 GHz.
Acknowledgments
Thanks to Dr. Xin Guo for her guidance on the paper writing.
-
Research ethics: Not applicable.
-
Author contributions: The author has accepted responsibility for the entire content of this manuscript and approved its submission.
-
Competing interests: The author states no conflict of interest.
-
Research funding: None declared.
-
Data availability: Not applicable.
References
1. Liu, P.; Chen, S.; Yao, M.; Yao, Z.; Ng, V. M. H.; Zhou, J.; Lei, Y.; Yang, Z.; Kong, L. B. Double-Layer Absorbers Based on Hierarchical MXene Composites for Microwave Absorption through Optimal Combination. J. Mater. Res. 2020, 35 (11), 1481–1491; https://doi.org/10.1557/jmr.2020.122.Search in Google Scholar
2. Shen, Y.; Zhang, T. T.; Yang, J. H.; Zhang, N.; Huang, T.; Wang, Y. Selective Localization of Reduced Graphene Oxides at the Interface of PLA/EVA Blend and its Resultant Electrical Resistivity. Polym. Compos. 2017, 38 (9), 1982–1991; https://doi.org/10.1002/pc.23769.Search in Google Scholar
3. Song, P.; Liu, B.; Liang, C.; Ruan, K.; Qiu, H.; Ma, Z.; Guo, Y.; Gu, J. Lightweight, Flexible Cellulose-Derived Carbon Aerogel@Reduced Graphene Oxide/PDMS Composites with Outstanding EMI Shielding Performances and Excellent Thermal Conductivities. Nano. Micro. Lett. 2021, 13 (1), 91; https://doi.org/10.1007/s40820-021-00624-4.Search in Google Scholar PubMed PubMed Central
4. Moonlek, B.; Wimolmala, E.; Markpin, T.; Sombatsompop, N.; Saenboonruang, K. Enhancing Electromagnetic Interference Shielding Effectiveness for Radiation Vulcanized Natural Rubber Latex Composites Containing Multiwalled Carbon Nanotubes and Silk Textile. Polym. Compos. 2020, 41 (10), 3996–4009; https://doi.org/10.1002/pc.25687.Search in Google Scholar
5. Zhang, X.; Fan, C.; Ma, Y.; Zhao, H.; Sui, J.; Liu, J.; Sun, C. Elastic Composites Fabricating for Electromagnetic Interference Shielding Based on MWCNTs and Fe3O4 Unique Distribution in Immiscible NR/NBR Blends. Polym. Eng. Sci. 2022, 62 (6), 2019–2030; https://doi.org/10.1002/pen.25985.Search in Google Scholar
6. Wen, M.; Sun, X.; Su, L.; Shen, J.; Li, J.; Guo, S. The Electrical Conductivity of Carbon Nanotube/Carbon Black/Polypropylene Composites Prepared through Multistage Stretching Extrusion. Polymer 2012, 53 (7), 1602–1610; https://doi.org/10.1016/j.polymer.2012.02.003.Search in Google Scholar
7. Kim, I. T.; Lee, J. H.; Shofner, M. L.; Jacob, K.; Tannenbaum, R. Crystallization Kinetics and Anisotropic Properties of Polyethylene Oxide/Magnetic Carbon Nanotubes Composite Films. Polymer 2012, 53 (12), 2402–2411; https://doi.org/10.1016/j.polymer.2012.03.065.Search in Google Scholar
8. Liang, L.; Yang, R.; Han, G.; Feng, Y.; Zhao, B.; Zhang, R.; Wang, Y.; Liu, C. Enhanced Electromagnetic Wave-Absorbing Performance of Magnetic Nanoparticles-Anchored 2D Ti(3)C(2)T(x) MXene. ACS Appl. Mater. Interfaces 2020, 12 (2), 2644–2654; https://doi.org/10.1021/acsami.9b18504.Search in Google Scholar PubMed
9. Pang, H.; Chen, C.; Zhang, Y. C.; Ren, P. G.; Yan, D. X.; Li, Z. M. The Effect of Electric Field, Annealing Temperature and Filler Loading on the Percolation Threshold of Polystyrene Containing Carbon Nanotubes and Graphene Nanosheets. Carbon 2011, 49 (6), 1980–1988; https://doi.org/10.1016/j.carbon.2011.01.023.Search in Google Scholar
10. Pan, F.; Rao, Y.; Batalu, D.; Cai, L.; Dong, Y.; Zhu, X.; Shi, Y.; Shi, Z.; Liu, Y.; Lu, W. Macroscopic Electromagnetic Cooperative Network-Enhanced MXene/Ni Chains Aerogel-Based Microwave Absorber with Ultra-low Matching Thickness. Nano. Micro Lett. 2022, 14 (1), 140; https://doi.org/10.1007/s40820-022-00869-7.Search in Google Scholar PubMed PubMed Central
© 2024 Walter de Gruyter GmbH, Berlin/Boston
Articles in the same Issue
- Frontmatter
- Material Properties
- Synthesis and properties of AM/AMPS/MMA and cationic monomer copolymer flooding agent
- Synthesis and properties of reed-based polyurethane (PU) coating
- Synthesis, rheology, cytotoxicity and antibacterial studies of N-acrolylglycine-acrylamide copolymer soft nano hydrogel
- Preparation and Assembly
- Hydrogel for slow-release drug delivery in wound treatment
- Low thickness electromagnetic wave absorbing polyurethane and IIR composites by interfacial polarization of multi-layer structure
- Development of MXene-based flexible piezoresistive sensors
- Engineering and Processing
- ScCO2-processed thermoplastic starch/chitosan oligosaccharide blown films and their oxygen barrier or antibacterial applications
- Influence of plasticisation during foam injection moulding on the melt viscosity and fibre length of long glass fibre-reinforced polypropylene
Articles in the same Issue
- Frontmatter
- Material Properties
- Synthesis and properties of AM/AMPS/MMA and cationic monomer copolymer flooding agent
- Synthesis and properties of reed-based polyurethane (PU) coating
- Synthesis, rheology, cytotoxicity and antibacterial studies of N-acrolylglycine-acrylamide copolymer soft nano hydrogel
- Preparation and Assembly
- Hydrogel for slow-release drug delivery in wound treatment
- Low thickness electromagnetic wave absorbing polyurethane and IIR composites by interfacial polarization of multi-layer structure
- Development of MXene-based flexible piezoresistive sensors
- Engineering and Processing
- ScCO2-processed thermoplastic starch/chitosan oligosaccharide blown films and their oxygen barrier or antibacterial applications
- Influence of plasticisation during foam injection moulding on the melt viscosity and fibre length of long glass fibre-reinforced polypropylene