Fabrication and characterization of microencapsulated dimethyl adipate phase change material with melamine-formaldehyde shell for cold thermal energy storage in coating
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Bhagyashree Vasantrao Waghmare
und
Prakash A. Mahanwar
Abstract
Microencapsulated phase change material (MPCM) was synthesized by using the in-situ polymerization technique. Dimethyl adipate (DMA) and melamine-formaldehyde were used as core and shell material for polymerization respectively. Sodium laureate sulphate (SLS) is used as a surfactant. The thermal properties were characterized by using a differential scanning calorimeter (DSC) and thermogravimetry analysis (TGA). Fourier transform infrared spectroscopy (FT-IR) was used to confirm the chemical structure. The morphology of microcapsules was studied by using, scanning electron microscopy. DSC result of MPCM has been observed to melt at 10.09 °C with melting latent enthalpy 88 J/g and crystallizes at 4.69 °C with crystallization latent heat 89.50 J/g. TGA analysis confirms increases in the thermal stability of MPCM. The decorative coating was prepared with 0, 5, 10, 15, and 20 % MPCM loading, and the prepared paint was tested for pencil hardness, gloss, and stain resistances. The thermal energy transfer rate was used to measure how much time coated panel took to reach the equilibrium temperature of 25 °C. Coating with 20 % MPCM loading revealed good thermal storage capacity but other general coating properties deteriorate.
Funding source: Dr. Babasaheb Ambedkar Research and Training Institute Pune
Award Identifier / Grant number: BANRF-2020/21-22/850
Acknowledgments
The authors thank the Institute of Chemical Technology, Mumbai, for availing all instrumental facilities required for the work.
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Author contributions: BVW: visualisation, data collection, investigation, writing original draft. PAM: supervision, review, and editing.
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Research funding: BVW significantly acknowledges BARTI, Pune, for a BANRF fellowship (BANRF-2020/21-22/850).
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Conflict of interest statement: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
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© 2023 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- Material Properties
- The degradation behaviors of optical cellulose triacetate films in alkali/acid solutions
- Exploration of dielectric spectra of variously synthesized epoxy/ZnO nanocomposites
- Preparation and Assembly
- Preparation and evaluation of polyvinyl alcohol hydrogels with zinc oxide nanoparticles as a drug controlled release agent for a hydrophilic drug
- PVA-borax/g-C3N4 nanocomposite hydrogel with excellent mechanical property and self-healing efficiency
- Fabrication and characterization of microencapsulated dimethyl adipate phase change material with melamine-formaldehyde shell for cold thermal energy storage in coating
- Preparation and performance of “three-layer sandwich” composite loose nanofiltration membrane based on mussel bionic technology
- Engineering and Processing
- Electrospinning and electrospun based polyvinyl alcohol nanofibers utilized as filters and sensors in the real world
- Synergistic effect of GMA and TMPTA as co-agent to adjust the branching structure of PLLA during UV-induced reactive extrusion
Artikel in diesem Heft
- Frontmatter
- Material Properties
- The degradation behaviors of optical cellulose triacetate films in alkali/acid solutions
- Exploration of dielectric spectra of variously synthesized epoxy/ZnO nanocomposites
- Preparation and Assembly
- Preparation and evaluation of polyvinyl alcohol hydrogels with zinc oxide nanoparticles as a drug controlled release agent for a hydrophilic drug
- PVA-borax/g-C3N4 nanocomposite hydrogel with excellent mechanical property and self-healing efficiency
- Fabrication and characterization of microencapsulated dimethyl adipate phase change material with melamine-formaldehyde shell for cold thermal energy storage in coating
- Preparation and performance of “three-layer sandwich” composite loose nanofiltration membrane based on mussel bionic technology
- Engineering and Processing
- Electrospinning and electrospun based polyvinyl alcohol nanofibers utilized as filters and sensors in the real world
- Synergistic effect of GMA and TMPTA as co-agent to adjust the branching structure of PLLA during UV-induced reactive extrusion
