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Applicability of different powder and polymer recipes in a new design powder injection molding system

  • Bunyamin Cicek ORCID logo EMAIL logo , Yavuz Sun ORCID logo , Yunus Turen ORCID logo und Hayrettin Ahlatci ORCID logo
Veröffentlicht/Copyright: 22. Februar 2021
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Abstract

Production methods are changing day by day with the developing technology. Based on this idea, a new production logic and machine have been developed owing to polymer-supported powder injection molding (PIM). The ability of this newly designed machine (newPIM) to mold metal or ceramic powders supported by polymer binders is discussed in this study. By taking advantage of the polymer properties such as fluidity and sticking, powders are molded with a specially developed machine with high gas pressure in certain sizes. In this study, in which many parameters are processed from feedstock (FS) production to molding; metals Mg/316L and ceramics SiC/SiO2 powders have been used in different powder sizes and structures. In the newPIM process, polymers were included in four different recipes. Paraffin wax (PW), polyethylene glycol (PEG), polypropylene (PP), ethylene-vinyl acetate (EVA), poly-methyl methacrylate (PMMA) and low-density polyethylene (LDPE) have been employed in the FS with different combinations. From FS production to the molding stage; pressure, microstructure examination, weight loss, and density change features were investigated. The result indicated that the best FS and molding was obtained by the PEG+PMMA polymer composition formed with a spherical powder with a diameter below 40 µm. The compression force of the FS in this composition was observed at approximately 3.4k N values.


Corresponding author: Bunyamin Cicek, Technical Sciences Vct. Sch., Hitit University, 19030Corum, Turkey, E-mail:

Funding source: Karabük Üniversitesi

Award Identifier / Grant number: FDK-2019-2106

Acknowledgments

We would like to thank the staff of the Iron and Steel Institute for their assistance.

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: We would like to thank the Karabuk University Scientific Research Project Unit (FDK-2019-2106) for financial support in the completion of this study.

  3. Conflict of interest statement: The authors declare that they have no conflict regarding this article.

References

1. Kryachek, V. M. Injection moulding. Powder Metall. Met. Ceram. 2004, 43(Suppl. 7–8), 336–348. https://doi.org/10.1023/b:pmmc.0000048127.24809.d3.10.1023/B:PMMC.0000048127.24809.d3Suche in Google Scholar

2. Levy, G. N., Schindel, R., Kruth, J.-P. Rapid manufacturing and rapid tooling with layer manufacturing (LM) technologies, state of the art and future perspectives. CIRP Ann. 2003, 52(Suppl. 2), 589–609. https://doi.org/10.1016/s0007-8506(07)60206-6.Suche in Google Scholar

3. German, R. M., Hens, K. F., Lin, S. T. P. Key issues in powder injection molding. Am. Ceram. Soc. Bull. 1991, 70(Suppl. 8), 1294–1302.Suche in Google Scholar

4. Kamal, M. R., Isayev, A., Liu, S.-J. Injection Molding; Hanser: München, Germany, 2009.10.3139/9783446433731Suche in Google Scholar

5. Rak, Z. New trends in powder injection moulding. Powder Metall. Met. Ceram. 1999, 38(Suppl. 3–4), 126–132. https://doi.org/10.1007/bf02676037.Suche in Google Scholar

6. Bleyan, D., Svoboda, P., Hausnerová, B. Specific interactions of low molecular weight analogues of carnauba wax and polyethylene glycol binders of ceramic injection moulding feedstocks. Ceram. Int. 2015, 41(Suppl. 3), 3975–3982. https://doi.org/10.1016/j.ceramint.2014.11.082.Suche in Google Scholar

7. Ibar, J. Control of polymer properties by melt vibration technology: a review. Polym. Eng. Sci. 1998, 38(Suppl. 1), 1–20. https://doi.org/10.1002/pen.10161.Suche in Google Scholar

8. Porter, M. A. Effects of Binder Systems for Metal Injection Moulding. M.Sc. Thesis, Lulea University of Technology, Sweden, 2003.Suche in Google Scholar

9. Senthilvelan, T., Raghukandan, K., Venkatraman, A. Testing and quality standards for powder metallurgy products. Mater. Manuf. Process. 2003, 18(Suppl. 1), 105–112. https://doi.org/10.1081/amp-120017592.Suche in Google Scholar

10. Kainer, K. U., Ebel, T., Ferri, O. M., Limberg, W., Pyczak, F., Schimansky, F. P., Wolff, M. From titanium to magnesium: processing by advanced metal injection moulding. Powder Metall. 2012, 55(Suppl. 4), 315–321. https://doi.org/10.1179/1743290112y.0000000020.Suche in Google Scholar

11. Menon, S. M., German, R. M., Rose, J. L., Hens, K. F. Green part characterization and in situ monitoring of powder injection molding using ultrasonic sensors. Adv. Powder Metall. Part. Mater. 1995, 2, 135–146.Suche in Google Scholar

12. Wang, Q., Wu, Z. Analysis on vibration characteristics of screw in filling process of dynamic injection molding machine. J. Polym. Eng. 2016, 36(Suppl. 8), 861–866.10.1515/polyeng-2015-0318Suche in Google Scholar

13. Hartwig, T., Veltl, G., Petzoldt, F., Kunze, H., Scholl, R., Kieback, B. Powders for metal injection molding. J. Eur. Ceram. Soc. 1998, 18(Suppl. 9), 1211–1216.10.1016/S0955-2219(98)00044-2Suche in Google Scholar

14. Heaney, D. Powders for Metal Injection Molding (MIM); Woodhead Publishing: United Kingdom, 2012.10.1533/9780857096234Suche in Google Scholar

15. Liu, Z. Y., Loh, N. H., Tor, S. B., Khor, K. A., Murakoshi, Y., Maeda, R. Binder system for micropowder injection molding. Mater. Lett. 2001, 48(Suppl. 1), 31–38. https://doi.org/10.1016/s0167-577x(00)00276-7.Suche in Google Scholar

16. Royer, A., Barrière, T., Gelin, J.-C., Hilliou, L. Development and characterisation of a biosourced feedstock of superalloy in metal injection moulding process. Powder Metall. 2017, 60(Suppl. 2), 105–111. https://doi.org/10.1080/00325899.2016.1269457.Suche in Google Scholar

17. Supriadi, S., Baek, E., Choi, C., Lee, B. Binder system for STS 316 nanopowder feedstocks in micro-metal injection molding. J. Mater. Process. Technol. 2007, 187, 270–273. https://doi.org/10.1016/j.jmatprotec.2006.11.157.Suche in Google Scholar

18. Wei, W. C. J., Wu, R. Y., Ho, S. J. Effects of pressure parameters on alumina made by powder injection moulding. J. Eur. Ceram. Soc. 2000, 20(Suppl. 9), 1301–1310. https://doi.org/10.1016/s0955-2219(99)00295-2.Suche in Google Scholar

19. Loh, N. H., Tor, S. B., Khor, K. A. Production of metal matrix composite part by powder injection molding. J. Mater. Process. Technol. 2001, 108(Suppl. 3), 398–407. https://doi.org/10.1016/s0924-0136(00)00855-4.Suche in Google Scholar

20. Setasuwon, P., Bunchavimonchet, A., Danchaivijit, S. The effects of binder components in wax/oil systems for metal injection molding. J. Mater. Process. Technol. 2008, 196(Suppl. 1–3), 94–100. https://doi.org/10.1016/j.jmatprotec.2007.05.009.Suche in Google Scholar

21. Hamidi, M., Harun, W., Samykano, M., Ghani, S., Ghazalli, Z., Ahmad, F., Sulong, A. B. A review of biocompatible metal injection moulding process parameters for biomedical applications. Mater. Sci. Eng. 2017, 78, 1263–1276. https://doi.org/10.1016/j.msec.2017.05.016.Suche in Google Scholar

22. Wolff, M., Schaper, J., Dahms, M., Ebel, T., Kainer, K., Klassen, T. Magnesium powder injection moulding for biomedical application. Powder Metall. 2014, 57(Suppl. 5), 331–340. https://doi.org/10.1179/1743290114y.0000000111.Suche in Google Scholar

23. Özgün, Ö., Gülsoy, H. Ö., Findik, F., Yilmaz, R. Microstructure and mechanical properties of injection moulded Nimonic-90 superalloy parts. Powder Metall. 2012, 55(Suppl. 5), 405–414. https://doi.org/10.1179/1743290112y.0000000010.Suche in Google Scholar

24. Özgün, Ö., Gülsoy, H. Ö., Yilmaz, R., Findik, F. Injection molding of nickel based 625 superalloy: sintering, heat treatment, microstructure and mechanical properties. J. Alloys Compd. 2013, 546, 192–207. https://doi.org/10.1016/j.jallcom.2012.08.069.Suche in Google Scholar

25. Özgün, Ö., Yılmaz, R., Gülsoy, H. Ö., Fındık, F. The effect of aging treatment on the fracture toughness and impact strength of injection molded Ni-625 superalloy parts. Mater. Char. 2015, 108, 8–15. https://doi.org/10.1016/j.matchar.2015.08.006.Suche in Google Scholar

26. Mark, J. E. Polymer Data Handbook; Oxford University Press: Oxford, UK, 2009.10.1093/oso/9780195181012.001.0001Suche in Google Scholar

27. Li, S., Zhao, G., Wang, J. A method to improve dimensional accuracy and mechanical properties of injection molded polypropylene parts. J. Polym. Eng. 2017, 37(Suppl. 4), 323–334. https://doi.org/10.1515/polyeng-2015-0526.Suche in Google Scholar

28. Thomas-Vielma, P., Cervera, A., Levenfeld, B., Várez, A. Production of alumina parts by powder injection molding with a binder system based on high density polyethylene. J. Eur. Ceram. Soc. 2008, 28(Suppl. 4), 763–771. https://doi.org/10.1016/j.jeurceramsoc.2007.08.004.Suche in Google Scholar

29. Mulser, M., Petzoldt, F. Standards for metal injection moulding: progress to-date and future challenges. Powder Inj. Mould. Int. 2017, 11(Suppl. 1), 59–66.Suche in Google Scholar

30. Bhosale, S. B., Bhowmik, S., Ray, A. Multi criteria decision making for selection of material composition for powder metallurgy process. Mater. Today: Proc. 2018, 5(Suppl. 2), 4615–4620. https://doi.org/10.1016/j.matpr.2017.12.032.Suche in Google Scholar

31. Poh, L., Della, C., Ying, S., Goh, C., Li, Y. Powder distribution on powder injection moulding of ceramic green compacts using thermogravimetric analysis and differential scanning calorimetry. Powder Technol. 2018, 328, 256–263. https://doi.org/10.1016/j.powtec.2017.12.078.Suche in Google Scholar

32. Negoro, T., Wongpajan, R., Thodsaratpreeyakul, W., Boonlertsamut, J., Thumsorn, S., Inoya, H., Hamada, H. Optimizing of vented injection molding on mechanical performance and miscibility of recycled poly (ethylene terephthalate) and polycarbonate blends. J. Polym. Eng. 2017, 37(Suppl. 3), 271–277. https://doi.org/10.1515/polyeng-2016-0034.Suche in Google Scholar

33. Lapointe, F., Turenne, S., Julien, B. Low viscosity feedstocks for powder injection moulding. Powder Metall. 2009, 52(Suppl. 4), 338–344. https://doi.org/10.1179/003258909x12518163544239.Suche in Google Scholar

34. Hausnerova, B., Kuritka, I., Bleyan, D. Polyolefin backbone substitution in binders for low temperature powder injection moulding feedstocks. Molecules 2014, 19(Suppl. 3), 2748–2760. https://doi.org/10.3390/molecules19032748.Suche in Google Scholar

35. Hayat, M. D., Goswami, A., Matthews, S., Li, T., Yuan, X., Cao, P. Modification of PEG/PMMA binder by PVP for titanium metal injection moulding. Powder Technol. 2017, 315, 243–249. https://doi.org/10.1016/j.powtec.2017.04.004.Suche in Google Scholar

36. Robinson, S. K., Paul, M. R. Debinding and sintering solutions for metals and ceramics. Met. Powder Rep. 2001, 56(Suppl. 6), 24–34. https://doi.org/10.1016/s0026-0657(01)80324-6.Suche in Google Scholar

37. Kim, D., Park, H., Lee, K., Cha, B., Choi, J., Rhee, B., Tovar, J. A. The effects of processing variables on gas penetration in gas-assisted powder injection molding (GAPIM). Trans. Mater. Process. 2012, 21(Suppl. 2), 107–112. https://doi.org/10.5228/kstp.2012.21.2.107.Suche in Google Scholar

38. Türen, Y. Influence of pressure type on powder injection moulding of stainless steel (316L) powder. Hit. J. Sci. Eng. 2017, 4(Suppl. 2), 85–90. https://doi.org/10.17350/hjse19030000053.Suche in Google Scholar

39. Arslan, M. Production of Stainless Steel (316L) Material through Powder Injection Moulding and Investigation of its Properties. M.Sc. Thesis, Zonguldak Karaelmas University, Karabuk, Turkey, 2007.Suche in Google Scholar

40. Shahbudin, S., Othman, M., Amin, S. Y. M., Ibrahim, M. A. Review of metal injection molding-process, optimization, defects and microwave sintering on WC-Co cemented carbide. In IOP Conference Series: Materials Science and Engineering, Melaka, Malaysia, 2017; https://doi.org/10.1088/1757-899X/226/1/01216210.1088/1757-899X/226/1/012162Suche in Google Scholar

41. Özgün, Ö., Gülsoy, H. Ö., Yılmaz, R., Fındık, F. Microstructural and mechanical characterization of injection molded 718 superalloy powders. J. Alloys Compd. 2013, 576, 140–153. https://doi.org/10.1016/j.jallcom.2013.04.042.Suche in Google Scholar

42. Zhao, D., Chang, K., Ebel, T., Qian, M., Willumeit, R., Yan, M., Pyczak, F. Microstructure and mechanical behavior of metal injection molded Ti–Nb binary alloys as biomedical material. J. Mech. Behav. Biomed. Mater. 2013, 28, 171–182. https://doi.org/10.1016/j.jmbbm.2013.08.013.Suche in Google Scholar

43. Zhao, D., Chang, K., Ebel, T., Qian, M., Willumeit, R., Yan, M., Pyczak, F. Titanium carbide precipitation in Ti–22Nb alloy fabricated by metal injection moulding. Powder Metall. 2014, 57(Suppl. 1), 2–4. https://doi.org/10.1179/0032589914z.000000000153.Suche in Google Scholar

44. Carreño-Morelli, E., Bidaux, J. E., Rodríguez-Arbaizar, M., Girard, H., Hamdan, H. Production of titanium grade 4 components by powder injection moulding of titanium hydride. Powder Metall. 2014, 57(Suppl. 2), 89–92. https://doi.org/10.1179/0032589914z.000000000165.Suche in Google Scholar

45. Bakan, H., Jumadi, Y., Messer, P., Davies, H., Ellis, B. Study of processing parameters for MIM feedstock based on composite PEG-PMMA binder. Powder Metall. 1998, 41(Suppl. 4), 289–291. https://doi.org/10.1179/pom.1998.41.4.289.Suche in Google Scholar

46. Omar, M., Davies, H., Messer, P., Ellis, B. The influence of PMMA content on the properties of 316L stainless steel MIM compact. J. Mater. Process. Technol. 2001, 113(Suppl. 1–3), 477–481. https://doi.org/10.1016/s0924-0136(01)00641-0.Suche in Google Scholar

47. Mukund, B. N., Hausnerova, B. Variation in particle size fraction to optimize metal injection molding of water atomized 17–4PH stainless steel feedstocks. Powder Technol. 2020, 368, 130–136. https://doi.org/10.1016/j.powtec.2020.04.058.Suche in Google Scholar

48. Waalkes, L., Längerich, J., Holbe, F., Emmelmann, C. Feasibility study on piston-based feedstock fabrication with Ti-6Al-4V metal injection molding feedstock. Addit. Manuf. 2020, 35, 101207. https://doi.org/10.1016/j.addma.2020.101207.Suche in Google Scholar

49. Turan, M. E., Sun, Y., Akgul, Y., Turen, Y., Ahlatci, H. The effect of GNPs on wear and corrosion behaviors of pure magnesium. J. Alloys Compd. 2017, 724, 14–23. https://doi.org/10.1016/j.jallcom.2017.07.022.Suche in Google Scholar

50. Chowdhury, S., Laugier, M., Henry, J. XRD stress analysis of CVD diamond coatings on SiC substrates. Int. J. Refract. Metals Hard Mater. 2007, 25(Suppl. 1), 39–45. https://doi.org/10.1016/j.ijrmhm.2005.11.012.Suche in Google Scholar

51. Yilmaz, G. Structural characterization of glass–ceramics made from fly ash containing SiO2–Al2O3–Fe2O3–CaO and analysis by FT-IR–XRD–SEM methods. J. Mol. Struct. 2012, 1019, 37–42. https://doi.org/10.1016/j.molstruc.2012.03.028.Suche in Google Scholar

52. Huang, S., Ma, D., Sheng, J., Agyenim-Boateng, E., Zhao, J., Zhou, J. Effects of laser peening on tensile properties and martensitic transformation of AISI 316L stainless steel in a hydrogen-rich environment. Mater. Sci. Eng. A-Struct. 2020, 788, 139543. https://doi.org/10.1016/j.msea.2020.139543.Suche in Google Scholar

53. Hausnerova, B., Kasparkova, V., Hnátková, E. Rheological and thermal performance of newly developed binder systems for ceramic injection molding. In AIP Conference Proceedings 1736, Naples, Italy, June 19–23, 2016.10.1063/1.4949695Suche in Google Scholar

54. Bleyan, D., Hausnerová, B., Svoboda, P. The development of powder injection moulding binders: a quantification of individual components’ interactions. Powder Technol. 2015, 286, 84–89. https://doi.org/10.1016/j.powtec.2015.07.046.Suche in Google Scholar

55. Xu, C., Zhao, J., Guo, A., Li, H., Dai, G., Zhang, X. Effects of injection velocity on microstructure, porosity and mechanical properties of a rheo-diecast Al-Zn-Mg-Cu aluminum alloy. J. Mater. Process. Technol. 2017, 249, 167–171. https://doi.org/10.1016/j.jmatprotec.2017.05.033.Suche in Google Scholar

Received: 2020-10-02
Accepted: 2021-01-19
Published Online: 2021-02-22
Published in Print: 2021-04-27

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