Home Physical Sciences Properties of EPDM/PP thermoplastic vulcanizates produced by an intermeshing-type internal mixer comparing with a co-rotating twin-screw extruder
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Properties of EPDM/PP thermoplastic vulcanizates produced by an intermeshing-type internal mixer comparing with a co-rotating twin-screw extruder

  • Wattana Teppinta EMAIL logo , Banja Junhasavasdikul and Nattapong Nithi-Uthai
Published/Copyright: September 4, 2018
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Abstract

A unique technology for producing thermoplastic vulcanizate (TPV) has been developed using an intermeshing-type internal mixer (ITM). TPV produced by the ITM was compared with that produced using a co-rotating twin screw extruder (Co-TSE) to assess the former’s commercial possibilities. TPV, originating from ethylene-propylene-diene monomer (EPDM) and polypropylene (PP), was produced by both machines with equal filled volumes, same shear rate, and same specific mechanical energy. Results indicate that ITMs can be used to produce TPV with mechanical properties comparable to those of TPV produced by Co-TSE. TPV can be produced with a lower shear rate with ITM compared to Co-TSE. A long residence time can be maintained in the mixing chamber of the ITM, allowing high conversion of the cross-linking reaction and resulting in better elastic recovery properties due to the higher cross-linking density. However, this resulted in higher viscosity of TPV produced by ITM.

References

[1] Coran AY, Patel R. Rubber Chem. Technol. 1980, 53, 141–150.10.5254/1.3535023Search in Google Scholar

[2] Karger-Kocsis J. Thermoplastic rubbers via dynamic vulcanization. In Polymer Blends and Alloys, Shonaike GO, Simon GP, Eds., Marcel Dekker: New York, 1999, pp 125–153.10.1201/9780203742921-5Search in Google Scholar

[3] Coran AY, Patel RP. Thermoplastic elastomers based on elastomer/thermoplastic blends dynamically vulcanized. In Reactive Modifiers for Polymers, Al-Malaika S, Ed., Chapman & Hall: London, 1997, pp 349–394.10.1007/978-94-009-1449-0_9Search in Google Scholar

[4] Oderkerk J, Schaetzen G, Goderis B, Hellemans L, Groeninckx G. Macromolecules 2002, 35, 6623–6629.10.1021/ma0113475Search in Google Scholar

[5] Zhang J, Zhang K, Gao L, Wang Z. Polym. Plast. Technol. Eng. 2017, 56, 906–916.10.1080/03602559.2016.1247275Search in Google Scholar

[6] Yeetsorn R, Ungtrakul T, Jariyakun K, Prissanaroon-Ouajai W, Tzoganakis C. Key Eng. Mater. 2017, 757, 29–34.10.4028/www.scientific.net/KEM.757.29Search in Google Scholar

[7] Thakur V, Gohs U, Wagenknecht U, Heinrich G, Polym. J. 2012, 44, 439–448.10.1038/pj.2012.3Search in Google Scholar

[8] Mondal M, Gohs U, Wagenknecht U, Heinrich G, Radiat. Phys. Chem. 2013, 88, 74–81.10.1016/j.radphyschem.2013.03.021Search in Google Scholar

[9] Xiao H, Huang S, Jiang T. J. Appl. Polym. Sci. 2004, 92, 357–362.10.1002/app.20026Search in Google Scholar

[10] Goharpey F, Katbab AA, Nazockdast H. Rubber Chem. Technol. 2003, 76, 239–252.10.5254/1.3547737Search in Google Scholar

[11] Ellul MD, Tsou AH, Hu W. Polymer 2004, 45, 3351–3358.10.1016/j.polymer.2004.03.029Search in Google Scholar

[12] Goharpey F, Nazockdast H, Katbab AA. Polym. Eng. Sci. 2005, 45, 84–94.10.1002/pen.20232Search in Google Scholar

[13] Coran AY, Patel R. Rubber Chem. Technol. 1981, 54, 91–100.10.5254/1.3535800Search in Google Scholar

[14] Coran AY, Patel R, Williams D. Rubber Chem. Technol. 1982, 55, 116–136.10.5254/1.3535861Search in Google Scholar

[15] Coran AY, Patel R, Williams D. Rubber Chem. Technol. 1982, 55, 1063–1077.10.5254/1.3535914Search in Google Scholar

[16] Ning N, Zhang L, Tian M, Tian H, Hu GH. RSC Adv. 2016, 6, 91594–91602.10.1039/C6RA19335HSearch in Google Scholar

[17] Gao Y, Li Y, Hu X, Wu W, Wang Z, Wang R, Zhang L. Polymers 2017, 9, 694.10.3390/polym9120694Search in Google Scholar PubMed PubMed Central

[18] Matchawet S, Kaesaman A, Vennemann N, Kummerlowe C, Nakason C. Ind. Eng. Chem. Res. 2017, 56, 3629–3639.10.1021/acs.iecr.7b00252Search in Google Scholar

[19] Chen Y, Gong Z, Cao L, Wang Y, Yuan D, Xu C. Polym. Adv. Technol. 2018, 29, 1456–1468.10.1002/pat.4257Search in Google Scholar

[20] Kazemi Y, Kakroodi AR, Ameli A, Filleter T, Park CB. J. Mater. Chem. C 2018, 6, 350–359.10.1039/C7TC04501HSearch in Google Scholar

[21] Gámez JFH, Hernández EH, Céspedes RIN, Velázquez MGN, Rosales SGS, Corral FS, Morones PG, Tavizón SF, Leon RDD, Cepeda LF, Polym. Compos. 2018, 39, 229–237.10.1002/pc.23922Search in Google Scholar

[22] Duin MV, Macromol. Symp. 2006, 233, 11–16.10.1002/masy.200690006Search in Google Scholar

[23] Hamanaka T, Goto Y, Komine N, Oda N, Ishibashi I. US Patent 5847052, 1998.Search in Google Scholar

[24] Itoh Y, Uchiyama A. US Patent 0091198A1, 2002.Search in Google Scholar

[25] Nadella HP, Cheng J, Young RD, Shen K. US Patent 7655728B2, 2010.Search in Google Scholar

[26] Martin C. Modern extrusion for TPE-TPO-TPU-TPV production. In TPE 2010 Conference Proceedings, Cologne, 2010.Search in Google Scholar

[27] Limper A. Processing aspects of rubber mixing. In Mixing of Rubber Compounds, Limper A, Ed., Hanser Publishers: Munich, 2012, pp 47–69.10.3139/9783446428652.002Search in Google Scholar

[28] Yang H, Manas-Zloczower I. Analysis of mixing performance in a VIC mixer. In Int. Polym. Proc., Hanser Publishers: Munich, 1994, 9, 291–302.10.3139/217.940291Search in Google Scholar

[29] Yao C, Manas-Zloczower I. Rubber Chem. Technol. 1998, 71, 690–707.10.5254/1.3538498Search in Google Scholar

[30] Rauwendaal C. Liquid-liquid mixing. In Polymer Mixing, Carl Hanser Verlag: Munich, 1998, pp 74–87.Search in Google Scholar

[31] Goharpey F, Katbab AA, Nazockdast H. J. Appl. Polym. Sci. 2001, 81, 2531–2544.10.1002/app.1694Search in Google Scholar

[32] Teppinta W, Junhasavasdikul B, Nithi-Uthai N. Adv. Mater. Res. 2014, 844, 117–121.10.4028/www.scientific.net/AMR.844.117Search in Google Scholar

[33] Leblance JL, Lionnet R. Polym. Eng. Sci. 1992, 32, 989–997.10.1002/pen.760321503Search in Google Scholar

[34] Anderson PG. The werner and pfleiderer twin-screw corotating extruder system. In Plastics Compounding: Equipment and Processing, Todd DB, Ed., Hanser Publishers: Munich, 1988, pp 71–121.Search in Google Scholar

[35] Palmgren H. Rubber Chem. Technol. 1975, 48, 462–494.10.5254/1.3547462Search in Google Scholar

[36] Abdou-Sabet S, Shen K. US Patent 4594390, 1986.Search in Google Scholar

[37] Goharpey F, Foudazi R, Nazockdast H, Katbab AA. J. Appl. Polym. Sci. 2008, 107, 3840–3847.10.1002/app.27401Search in Google Scholar

[38] Prut EV. Processing and properties of thermoplastic vulcanizates (TPV). In TPE Conference 2001, Crown Plaza Hotel, Brussels, Belgium, 2001.Search in Google Scholar

[39] Gao J, Walsh GC, Bigio D. Polym. Eng. Sci. 2000, 40, 227–237.10.1002/pen.11155Search in Google Scholar

[40] Puaux JP, Bozga G, Ainser A. Chem. Eng. Sci. 2000, 55, 1641–1651.10.1016/S0009-2509(99)00430-3Search in Google Scholar

[41] Cassagnau P, Mijangos C, Michel A. Polym. Eng. Sci. 1991, 31, 772–778.10.1002/pen.760311103Search in Google Scholar

[42] Shearer G, Tzoganakis C. Polym. Eng. Sci. 1999, 39, 1584–1596.10.1002/pen.11552Search in Google Scholar

[43] Gasner GE, Bigio D, Marks C. Polym. Eng. Sci. 1999, 39, 286–298.10.1002/pen.11415Search in Google Scholar

[44] Meier R, Moll K, Krumme M, Kleinbudde P. Eur. J. Pharm. Biopharm. 2017, 115, 102–112.10.1016/j.ejpb.2017.02.010Search in Google Scholar

[45] Hinsken H, Moss S, Pauquet J, Zweifel H. Polym. Degrad. Stab. 1991, 34, 279–293.10.1016/0141-3910(91)90123-9Search in Google Scholar

[46] Huang J, Xu J. Int. J. Polym. Mater. 2003, 52, 203–209.10.1080/00914030304896Search in Google Scholar

[47] Qian S, Igarashi T, Nitta K. Polym. Bull. 2011, 67, 1661–1670.10.1007/s00289-011-0560-6Search in Google Scholar

[48] Antunes CF, Duin M, Machado AV. Mater. Chem. Phys. 2012, 133, 410–418.10.1016/j.matchemphys.2012.01.053Search in Google Scholar

[49] Lu K, Duin MV, With G. Polymer 2012, 53, 4171–4177.10.1016/j.polymer.2012.06.041Search in Google Scholar

[50] Shearer G, Tzoganakis C. Polym. Eng. Sci. 2000, 40, 1095–1106.10.1002/pen.11237Search in Google Scholar

[51] Gibala D, Hamed GR. Rubber Chem. Technol. 1994, 67, 636–648.10.5254/1.3538699Search in Google Scholar

[52] Gibala D, Laohapisitpanich K, Thomas D, Hamed GR. Rubber Chem. Technol. 1996, 69, 115–119.10.5254/1.3538351Search in Google Scholar

[53] Gibala D, Thomas D, Hamed GR. Rubber Chem. Technol. 1999, 72, 357–360.10.5254/1.3538807Search in Google Scholar

[54] Rondin J, Bouquey M, Muller R, Serra CA, Martin G, Sonntag P. Polym. Eng. Sci. 2014, 54, 1444–1457.10.1002/pen.23667Search in Google Scholar

[55] Yang HH, Manas-Zloczower I. Polym. Eng. Sci. 1992, 32, 1411–1417.10.1002/pen.760321903Search in Google Scholar

[56] Liang J, Zhong L. Polym. Eng. Sci. 2010, 50, 2190–2193.10.1002/pen.21754Search in Google Scholar

Received: 2018-05-30
Accepted: 2018-08-03
Published Online: 2018-09-04
Published in Print: 2019-02-25

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