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Preparation and characterization of poly (amide-ester-imide)/Na+-MMT nanocomposite via ultrasonic method

  • Razieh Mirsafaei and Majid Kolahdoozan EMAIL logo
Published/Copyright: September 27, 2016
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Journal of Polymer Engineering
From the journal Journal of Polymer Engineering Volume 37 Issue 5

Abstract

The novel poly (amide-ester-imide) (PAEI)/Na+-MMT (montmorillonite) nanocomposites were synthesized by ultrasound-assisted technique successfully. PAEI/Na+-MMT nanocomposites with various content of Na+-MMT were applied to enhance the dispersion of the clay layers with polymer matrix. Water-soluble PAEI containing poly (ethylene glycol) (PEG-6000) was prepared, and nanocomposites with various content of Na+-MMT (5, 10, 15, and 20 mass %) were fabricated by ultrasonic method to produce nano-scale composites. The effects of Na+-MMT on the nanocomposites were investigated by Fourier transform infrared, X-ray diffraction (XRD), transmission electron microscopy (TEM), and scanning electron microscopy (SEM) and for thermal properties. XRD approved the structure information of the synthesized nanomaterials, and it was shown that the interlayer spacing increased with clay loading. The magnitude of dispersion of the clay in the nanocomposite matrix was investigated by TEM and SEM images. The results indicated that the lateral dimension of Na+-MMT particles in composites was approximately 100 nm, and the nanomaterials are well dispersed in the polymer matrix to produce exfoliated structure in polymer/nanocomposite. Thermogravimetric analysis confirms that PAEI/Na+-MMT nanocomposites show superior thermal stability with respect to the pure PAEIs.

Keywords: nanocomposite; poly (amide-ester-imide); poly ethylene glycol (PEG); sodium montmorillonite (Na+-MMT); ultrasonic

Acknowledgments

We are grateful to the Iran National Science Foundation (INSF) for partial financial support. We also wish to express our gratitude to the Research Affairs Division of Shahreza University for financial support.

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Received: 2016-5-14
Accepted: 2016-8-3
Published Online: 2016-9-27
Published in Print: 2017-5-24

©2017 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. Original articles
  3. Preparation of epoxy/acrylonitrile-butadiene-styrene copolymer/short carbon fiber composites with a self-made conical mixer
  4. Preparation and characterization of poly (amide-ester-imide)/Na+-MMT nanocomposite via ultrasonic method
  5. Polyurethane membrane with a cyclodextrin-modified carbon nanotube for pervaporation of phenol/water mixture
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  7. Effect of cooling induced crystallization upon the properties of segmented thermoplastic polyurethanes
  8. Conductivity and dielectric analysis of nanocolloidal polypyrrole particles functionalized with higher weight percentage of poly(styrene sulfonate) using the dispersion polymerization method
  9. Mechanism and solutions of appearance defects on microfluidic chips manufactured by UV-curing assisted injection molding
  10. Effect of gas counter pressure on shrinkage and residual stress for injection molding process
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https://doi.org/10.1515/polyeng-2016-0178
Keywords for this article
nanocomposite; poly (amide-ester-imide); poly ethylene glycol (PEG); sodium montmorillonite (Na+-MMT); ultrasonic

Articles in the same Issue

  1. Frontmatter
  2. Original articles
  3. Preparation of epoxy/acrylonitrile-butadiene-styrene copolymer/short carbon fiber composites with a self-made conical mixer
  4. Preparation and characterization of poly (amide-ester-imide)/Na+-MMT nanocomposite via ultrasonic method
  5. Polyurethane membrane with a cyclodextrin-modified carbon nanotube for pervaporation of phenol/water mixture
  6. Fabrication of chitosan/PEO nanofiber mats with mica by electrospinning
  7. Effect of cooling induced crystallization upon the properties of segmented thermoplastic polyurethanes
  8. Conductivity and dielectric analysis of nanocolloidal polypyrrole particles functionalized with higher weight percentage of poly(styrene sulfonate) using the dispersion polymerization method
  9. Mechanism and solutions of appearance defects on microfluidic chips manufactured by UV-curing assisted injection molding
  10. Effect of gas counter pressure on shrinkage and residual stress for injection molding process
  11. Ablation and mechanical investigation of heat vulcanizing silicone rubber (HVSR) composite containing carbon fibers
  12. Cavitation desulfurization in vulcanized rubber recycling under ultra-high pressure water jet
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