Startseite Effect of surface modification on the compressive properties of silica fume/polyurethane composites
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Effect of surface modification on the compressive properties of silica fume/polyurethane composites

  • Di Shao , Jianzhi Diao EMAIL logo , Lijie Wang und Long Li
Veröffentlicht/Copyright: 14. Januar 2016
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Abstract

Silica fume was modified by a silane coupling agent (KH-550). The modified silica fume was further investigated to reinforce polyurethane (PU) composites. Unmodified and modified silica fume reinforced PU composites were prepared. Through the comparisons of Fourier transform infrared (FT-IR) spectroscopy, transmission electron microscopy (TEM) and scanning electron microscopy (SEM) of unmodified and modified silica fume, the agglomerations of silica fume particles were effectively prevented as KH-550 was grafted. The compressive strength of the modified silica fume/PU composites was largely improved, because KH-550 could react with both silica fume and PU. Meanwhile, modified silica fume turned from hydrophilic to hydrophobic; a better dispersion was realized in the PU elastomers compared to the unmodified silica fume. The reinforcement effects were evaluated based on the results of a universal test machine in comparison with unmodified silica fume/PU composites.


Corresponding author: Jianzhi Diao, School of Material Science and Engineering, Shijiazhuang Tiedao University, Shijiazhuang, Hebei, P. R. China; and Hebei Provincial Key Laboratory of Traffic Engineering Materials, Shijiazhuang, Hebei, P. R. China, e-mail:

Acknowledgments

The authors gratefully acknowledge Professor Diao Jianzhi for advice on their paper. This work was financially supported by Hebei Provincial Key Laboratory of Traffic Engineering Materials.

References

[1] Huang JB, Ma G, Li XG, Jian SW, Tan HB. J. Wuhan Univ. Technol. 2012, 27, 886–891.10.1007/s11595-012-0568-2Suche in Google Scholar

[2] Hou X, Ding H, Liang Y, Zheng YX, Yang ZD, Luo HN. Mater. Res. Innov. 2013, 17, 260–266.10.1179/1432891713Z.000000000227Suche in Google Scholar

[3] Siddique R. Resour. Conserv. Recy. 2011, 55, 923–932.10.1016/j.resconrec.2011.06.012Suche in Google Scholar

[4] Sezre GI. Constr. Build. Mater. 2012, 26, 613–618.10.1016/j.conbuildmat.2011.06.064Suche in Google Scholar

[5] Cahyadi JH. Cement Concrete Res. 2003, 33, 1543–1548.10.1016/S0008-8846(03)00100-5Suche in Google Scholar

[6] Wu WR, Pan ZL. Acta Miner. Sin. 2000, 20, 397–400.Suche in Google Scholar

[7] Wu WR, Pan ZL, Zhao H, Guo ZB. Miner. Petrol. Geochem. 1999, 18, 274–276.Suche in Google Scholar

[8] Zhao YL, Shen SY, Su F. Conserv. Utilization Min. Resour. 2003, 2, 17–20.Suche in Google Scholar

[9] Ding H, Lu SC, Du GX. Int. J. Min. Met. Mater. 2011, 18, 83–88.10.1007/s12613-011-0404-2Suche in Google Scholar

[10] Yuan XW, Easteal AJ, Bhattacharyya D. J. Mater. Sci. 2008, 43, 6057–6063.10.1007/s10853-008-2957-7Suche in Google Scholar

[11] Zhang DD, Wang JH, Wen SG, Wang PZ, Yin CL, Du ZY. Adv. Mater. Phys. Chem. 2015, 5, 60–66.10.4236/ampc.2015.52009Suche in Google Scholar

[12] Obi Reddy K, Uma Maheswari C, Ramakrishna Reddy K, Shukla M, Muzenda E, Varada Rajulu A. Int. J. Polym. Anal. Ch. 2015, 20, 612–626.10.1080/1023666X.2015.1054084Suche in Google Scholar

[13] Liu W, Xie ZP, Jia C. J. Eur. Ceram. Soc. 2012, 32, 1001–1006.10.1016/j.jeurceramsoc.2011.11.017Suche in Google Scholar

[14] Wei B, Song SH, Cao H. Mater. Design 2011, 32, 4180–4186.10.1016/j.matdes.2011.04.041Suche in Google Scholar

[15] Gauvin F, Cousin P, Robert M. Fibres Polym. 2015, 16, 434–442.10.1007/s12221-015-0434-xSuche in Google Scholar

[16] Balazs AC, Emrick T, Russell TP. Science 2006, 314, 1107–1110.10.1126/science.1130557Suche in Google Scholar PubMed

Received: 2015-11-4
Accepted: 2015-11-16
Published Online: 2016-1-14
Published in Print: 2016-10-1

©2016 Walter de Gruyter GmbH, Berlin/Boston

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